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Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺
Infrared and visible absorption spectra and laser-induced fluorescence (LIF) and excitation spectra are obtained for several simple cations deposited from a mass-selected ion beam. In the present preliminary study we demonstrate successful and clean mass selection by presenting spectra of samples ob...
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2000
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| Series: | Физика низких температур |
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| Online Access: | http://dspace.nbuv.gov.ua/handle/123456789/129227 |
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irk-123456789-1292272018-01-18T03:02:45Z Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ Lorenz, Martin Bondybey, Vladimir E. Low-Temperature Physics and Chemistry in Cryomatrice Infrared and visible absorption spectra and laser-induced fluorescence (LIF) and excitation spectra are obtained for several simple cations deposited from a mass-selected ion beam. In the present preliminary study we demonstrate successful and clean mass selection by presenting spectra of samples obtained by depositing the isotopic ³⁴S¹²C³²S⁺ ion in natural isotopic abundance, and analyzing its spectrum. Spectra of C₆F₆⁺ deposited from a 20 eV ion beam exhibit quite different inhomogeneous line profiles, suggesting that even the relatively low kinetic energy results in considerable damage to the solid. Analysis of the spectra indicates that the Jahn–Teller-distorted vibrational structure in the doubly degenerate ground state of C₆F₆⁺ is strongly perturbed in the newly formed sites, which are presumably of lower symmetry. A 33–46 cm−1 splitting of the origin and other totally symmetric bands in emission is tentatively attributed to the spin–orbit splitting in the ²E₁g ground state. 2000 Article Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ / Martin Lorenz, Vladimir E. Bondybey // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 1044-1052. — Бібліогр.: 51 назв. — англ. 0132-6414 PACS: 33.15.Ta, 33.20.Ea, 33.20.Kf, 33.50.-j, 39.10.+j, 71.70.-d http://dspace.nbuv.gov.ua/handle/123456789/129227 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
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DSpace DC |
| language |
English |
| topic |
Low-Temperature Physics and Chemistry in Cryomatrice Low-Temperature Physics and Chemistry in Cryomatrice |
| spellingShingle |
Low-Temperature Physics and Chemistry in Cryomatrice Low-Temperature Physics and Chemistry in Cryomatrice Lorenz, Martin Bondybey, Vladimir E. Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ Физика низких температур |
| description |
Infrared and visible absorption spectra and laser-induced fluorescence (LIF) and excitation spectra are obtained for several simple cations deposited from a mass-selected ion beam. In the present preliminary study we demonstrate successful and clean mass selection by presenting spectra of samples obtained by depositing the isotopic ³⁴S¹²C³²S⁺ ion in natural isotopic abundance, and analyzing its spectrum. Spectra of C₆F₆⁺ deposited from a 20 eV ion beam exhibit quite different inhomogeneous line profiles, suggesting that even the relatively low kinetic energy results in considerable damage to the solid. Analysis of the spectra indicates that the Jahn–Teller-distorted vibrational structure in the doubly degenerate ground state of C₆F₆⁺ is strongly perturbed in the newly formed sites, which are presumably of lower symmetry. A 33–46 cm−1 splitting of the origin and other totally symmetric bands in emission is tentatively attributed to the spin–orbit splitting in the ²E₁g ground state. |
| format |
Article |
| author |
Lorenz, Martin Bondybey, Vladimir E. |
| author_facet |
Lorenz, Martin Bondybey, Vladimir E. |
| author_sort |
Lorenz, Martin |
| title |
Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ |
| title_short |
Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ |
| title_full |
Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ |
| title_fullStr |
Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ |
| title_full_unstemmed |
Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ |
| title_sort |
deposition of mass-selected ions in neon matrices: cs₂⁺ and c₆f₆⁺ |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2000 |
| topic_facet |
Low-Temperature Physics and Chemistry in Cryomatrice |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/129227 |
| citation_txt |
Deposition of mass-selected ions in neon matrices: CS₂⁺ and C₆F₆⁺ / Martin Lorenz, Vladimir E. Bondybey // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 1044-1052. — Бібліогр.: 51 назв. — англ. |
| series |
Физика низких температур |
| work_keys_str_mv |
AT lorenzmartin depositionofmassselectedionsinneonmatricescs2andc6f6 AT bondybeyvladimire depositionofmassselectedionsinneonmatricescs2andc6f6 |
| first_indexed |
2023-10-18T20:57:12Z |
| last_indexed |
2023-10-18T20:57:12Z |
| _version_ |
1796151538839715840 |