The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide
The kinetics of the sorption and the subsequent desorption of ⁴He by the starting graphite oxide (GtO) and the thermally reduced graphene oxide samples (TRGO, T reduction = 200, 300, 500, 700 and 900 °C) have been investigated in the temperature interval 1.5–20 K. The effect of the annealing tempera...
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| Дата: | 2017 |
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| Автори: | , , , , , , , , , , |
| Формат: | Стаття |
| Мова: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2017
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| Назва видання: | Физика низких температур |
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| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/129422 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide / A.V. Dolbin, M.V. Khlistuck, V.B. Esel’son, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, A.I. Prokhvatilov, I.V. Legchenkova, V.V. Meleshko, W.K. Maser A.M. Benito // Физика низких температур. — 2017. — Т. 43, № 3. — С. 471-478. — Бібліогр.: 39 назв. — англ. |
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irk-123456789-1294222018-01-20T03:03:21Z The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide Dolbin, A.V. Khlistuck, M.V. Esel’son, V.B. Gavrilko, V.G. Vinnikov, N.A. Basnukaeva, R.M. Prokhvatilov, A.I. Legchenkova, I.V. Meleshko, V.V. Maser, A.M. Benito, W.K. Наноструктуры при низких температурах The kinetics of the sorption and the subsequent desorption of ⁴He by the starting graphite oxide (GtO) and the thermally reduced graphene oxide samples (TRGO, T reduction = 200, 300, 500, 700 and 900 °C) have been investigated in the temperature interval 1.5–20 K. The effect of the annealing temperature on the structural characteristics of the samples was examined by the x-ray diffraction (XRD) technique. On lowering the temperature from 20 to 11–12 K, the time of ⁴He sorption increased for all the samples, which is typically observed under the condition of thermally activated diffusion. Below 5 K the characteristic times of ⁴He sorption by the GtO and TRGO-200 samples were only weakly dependent on temperature, suggesting the dominance of the tunnel mechanism. In the same region (T < 5 K) the characteristic times of the TRGOs reduced at higher temperatures (300, 500, 700 and 900 °C) were growing with lowering temperature, presumably due to the defects generated in the carbon planes on removing the oxygen functional groups (oFGs). The estimates of the activation energy ( Ea) of ⁴He diffusion show that in the TRGO-200 sample the Ea value is 2.9 times lower as compared to the parent GtO, which is accounted for by GtO exfoliation due to evaporation of the water intercalated in the interlayer space of carbon. The nonmonotonic dependences Ea( T) for the GtO samples treated above 200 °C are determined by a competition between two processes—the recovery of the graphite carbon structure, which increases the activation energy, and the generation of defects, which decreases the activation energy by opening additional surface areas and ways for sorption. The dependence of the activation energy on T reduction correlates well with the contents of the crystalline phase in GtO varying with a rise of the annealing temperature. 2017 Article The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide / A.V. Dolbin, M.V. Khlistuck, V.B. Esel’son, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, A.I. Prokhvatilov, I.V. Legchenkova, V.V. Meleshko, W.K. Maser A.M. Benito // Физика низких температур. — 2017. — Т. 43, № 3. — С. 471-478. — Бібліогр.: 39 назв. — англ. 0132-6414 PACS: 68.43.Jk, 68.43.Mn http://dspace.nbuv.gov.ua/handle/123456789/129422 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Наноструктуры при низких температурах Наноструктуры при низких температурах |
| spellingShingle |
Наноструктуры при низких температурах Наноструктуры при низких температурах Dolbin, A.V. Khlistuck, M.V. Esel’son, V.B. Gavrilko, V.G. Vinnikov, N.A. Basnukaeva, R.M. Prokhvatilov, A.I. Legchenkova, I.V. Meleshko, V.V. Maser, A.M. Benito, W.K. The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide Физика низких температур |
| description |
The kinetics of the sorption and the subsequent desorption of ⁴He by the starting graphite oxide (GtO) and the thermally reduced graphene oxide samples (TRGO, T reduction = 200, 300, 500, 700 and 900 °C) have been investigated in the temperature interval 1.5–20 K. The effect of the annealing temperature on the structural characteristics of the samples was examined by the x-ray diffraction (XRD) technique. On lowering the temperature from 20 to 11–12 K, the time of ⁴He sorption increased for all the samples, which is typically observed under the condition of thermally activated diffusion. Below 5 K the characteristic times of ⁴He sorption by the GtO and TRGO-200 samples were only weakly dependent on temperature, suggesting the dominance of the tunnel mechanism. In the same region (T < 5 K) the characteristic times of the TRGOs reduced at higher temperatures (300, 500, 700 and 900 °C) were growing with lowering temperature, presumably due to the defects generated in the carbon planes on removing the oxygen functional groups (oFGs). The estimates of the activation energy ( Ea) of ⁴He diffusion show that in the TRGO-200 sample the Ea value is 2.9 times lower as compared to the parent GtO, which is accounted for by GtO exfoliation due to evaporation of the water intercalated in the interlayer space of carbon. The nonmonotonic dependences Ea( T) for the GtO samples treated above 200 °C are determined by a competition between two processes—the recovery of the graphite carbon structure, which increases the activation energy, and the generation of defects, which decreases the activation energy by opening additional surface areas and ways for sorption. The dependence of the activation energy on T reduction correlates well with the contents of the crystalline phase in GtO varying with a rise of the annealing temperature. |
| format |
Article |
| author |
Dolbin, A.V. Khlistuck, M.V. Esel’son, V.B. Gavrilko, V.G. Vinnikov, N.A. Basnukaeva, R.M. Prokhvatilov, A.I. Legchenkova, I.V. Meleshko, V.V. Maser, A.M. Benito, W.K. |
| author_facet |
Dolbin, A.V. Khlistuck, M.V. Esel’son, V.B. Gavrilko, V.G. Vinnikov, N.A. Basnukaeva, R.M. Prokhvatilov, A.I. Legchenkova, I.V. Meleshko, V.V. Maser, A.M. Benito, W.K. |
| author_sort |
Dolbin, A.V. |
| title |
The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide |
| title_short |
The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide |
| title_full |
The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide |
| title_fullStr |
The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide |
| title_full_unstemmed |
The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide |
| title_sort |
effect of the thermal reduction on the kinetics of low-temperature ⁴he sorption and the structural characteristics of graphene oxide |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2017 |
| topic_facet |
Наноструктуры при низких температурах |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/129422 |
| citation_txt |
The effect of the thermal reduction on the kinetics of low-temperature ⁴He sorption and the structural characteristics of graphene oxide / A.V. Dolbin, M.V. Khlistuck, V.B. Esel’son, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, A.I. Prokhvatilov, I.V. Legchenkova, V.V. Meleshko, W.K. Maser A.M. Benito // Физика низких температур. — 2017. — Т. 43, № 3. — С. 471-478. — Бібліогр.: 39 назв. — англ. |
| series |
Физика низких температур |
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