Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate

Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate

A regular research of phases on the basis of Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) using various electrochemical methods has been carried out. The area of solid solutions, electrolytic temperature interval, average ion transfer numbers and electron transfer numbers have been determined. The structures havi...

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Бібліографічні деталі
Дата:2006
Автори: Medvedeva, O.V., Yurlov, I.S., Kalinina, L.A., Ushakova, Yu.N., Fominykh, E.G., Shirokova, G.I., Ananchenko, B.A.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2006
Назва видання:Functional Materials
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/135011
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate / O.V. Medvedeva, I.S. Yurlov, L.A. Kalinina, Yu.N. Ushakova, E.G. Fominykh, G.I. Shirokova, B.A. Ananchenko // Functional Materials. — 2006. — Т. 13, № 3. — С. 519-525. — Бібліогр.: 9 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1350112018-06-15T03:04:13Z Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate Medvedeva, O.V. Yurlov, I.S. Kalinina, L.A. Ushakova, Yu.N. Fominykh, E.G. Shirokova, G.I. Ananchenko, B.A. A regular research of phases on the basis of Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) using various electrochemical methods has been carried out. The area of solid solutions, electrolytic temperature interval, average ion transfer numbers and electron transfer numbers have been determined. The structures having the best electrolytic properties are established. The conductivity nature of solid electrolyte on the basis of barium thiosamarate and calcium thiogadolinate has been investigated. The data obtained allow to consider phases Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) as ionic conductors. The possible mechanism of defect formation is proposed. 2006 Article Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate / O.V. Medvedeva, I.S. Yurlov, L.A. Kalinina, Yu.N. Ushakova, E.G. Fominykh, G.I. Shirokova, B.A. Ananchenko // Functional Materials. — 2006. — Т. 13, № 3. — С. 519-525. — Бібліогр.: 9 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/135011 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description A regular research of phases on the basis of Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) using various electrochemical methods has been carried out. The area of solid solutions, electrolytic temperature interval, average ion transfer numbers and electron transfer numbers have been determined. The structures having the best electrolytic properties are established. The conductivity nature of solid electrolyte on the basis of barium thiosamarate and calcium thiogadolinate has been investigated. The data obtained allow to consider phases Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) as ionic conductors. The possible mechanism of defect formation is proposed.
format Article
author Medvedeva, O.V.
Yurlov, I.S.
Kalinina, L.A.
Ushakova, Yu.N.
Fominykh, E.G.
Shirokova, G.I.
Ananchenko, B.A.
spellingShingle Medvedeva, O.V.
Yurlov, I.S.
Kalinina, L.A.
Ushakova, Yu.N.
Fominykh, E.G.
Shirokova, G.I.
Ananchenko, B.A.
Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
Functional Materials
author_facet Medvedeva, O.V.
Yurlov, I.S.
Kalinina, L.A.
Ushakova, Yu.N.
Fominykh, E.G.
Shirokova, G.I.
Ananchenko, B.A.
author_sort Medvedeva, O.V.
title Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_short Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_full Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_fullStr Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_full_unstemmed Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_sort electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
publisher НТК «Інститут монокристалів» НАН України
publishDate 2006
url http://dspace.nbuv.gov.ua/handle/123456789/135011
citation_txt Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate / O.V. Medvedeva, I.S. Yurlov, L.A. Kalinina, Yu.N. Ushakova, E.G. Fominykh, G.I. Shirokova, B.A. Ananchenko // Functional Materials. — 2006. — Т. 13, № 3. — С. 519-525. — Бібліогр.: 9 назв. — англ.
series Functional Materials
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first_indexed 2023-10-18T21:08:16Z
last_indexed 2023-10-18T21:08:16Z
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