The point radiation defects in Li₆YB₃O₉:Eu³⁺ single crystals

The point radiation defects in Li₆YB₃O₉:Eu³⁺ single crystals have been studied. The irradiation of Li₆YB₃O₉:Eu³⁺ single crystals with beta particles has been found to cause a valence state change (Eu³⁺ -> Eu²⁺) in some fraction of europium ions being detected by decrease of Eu³⁺ photoluminescence...

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Збережено в:
Бібліографічні деталі
Дата:2008
Автор: Yavetskiy, R.P.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2008
Назва видання:Functional Materials
Теми:
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/135262
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:The point radiation defects in Li₆YB₃O₉:Eu³⁺ single crystals // R.P. Yavetskiy // Functional Materials. — 2008. — Т. 15, № 3. — С. 338-342. — Бібліогр.: 31 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:The point radiation defects in Li₆YB₃O₉:Eu³⁺ single crystals have been studied. The irradiation of Li₆YB₃O₉:Eu³⁺ single crystals with beta particles has been found to cause a valence state change (Eu³⁺ -> Eu²⁺) in some fraction of europium ions being detected by decrease of Eu³⁺ photoluminescence integral intensity, as well as formation of O⁻ hole centers resulting in appearance of a radiation induced broad absorption band in the λ = 320-500 nm range. Two models of hole centers in Li₆YB₃O₉:Eu³⁺ crystals (O⁻ isolated ion or BO₃²⁻ complex ion) have been proposed.