Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ
The results of our study deal with the NQR spectra of ¹²⁷| at 77 K in mixed layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ in a wide range of content Pbl₂ and Bil ₃ 0 < x < 1. It is shown that in the range of content 0 < x < 0.02 the crystal (Bil₃)₍₁₋ₓ₎(Pbl₂)ₓ has the properties of th...
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| Дата: | 2012 |
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НТК «Інститут монокристалів» НАН України
2012
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| Назва видання: | Functional Materials |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI2)(1-x)(BiI3)x / O.I. Barabash, I.G. Vertegel, E.D. Chesnokov, O.I. Ovcharenko, L.S. Ivanova // Functional Materials. — 2012. — Т. 19, № 3. — С. 330-333. — Бібліогр.: 11 назв. — англ. |
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irk-123456789-1353102018-06-15T03:08:10Z Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ Barabash, O.I. Vertegel, I.G. Chesnokov, E.D. Ovcharenko, O.I. Ivanova, L.S. Characterization and properties The results of our study deal with the NQR spectra of ¹²⁷| at 77 K in mixed layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ in a wide range of content Pbl₂ and Bil ₃ 0 < x < 1. It is shown that in the range of content 0 < x < 0.02 the crystal (Bil₃)₍₁₋ₓ₎(Pbl₂)ₓ has the properties of the impure crystal Pbl₂, which contains intralayer Bil₃ clusters, and in the range 0.8 < x < 1 it contains intralayer clusters Pbl2. Under the concentration x = 0.10 and x = 0.80 the crystal (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ undergoes a phase transition and in the concentration range 0.1 < x < 0.8 there is a new crystal (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ, in which groups of atoms Pbl₂ and Pbl₃ are intercalants fully or partially ordered in the crystal system. 2012 Article Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI2)(1-x)(BiI3)x / O.I. Barabash, I.G. Vertegel, E.D. Chesnokov, O.I. Ovcharenko, L.S. Ivanova // Functional Materials. — 2012. — Т. 19, № 3. — С. 330-333. — Бібліогр.: 11 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/135310 en Functional Materials НТК «Інститут монокристалів» НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Characterization and properties Characterization and properties |
| spellingShingle |
Characterization and properties Characterization and properties Barabash, O.I. Vertegel, I.G. Chesnokov, E.D. Ovcharenko, O.I. Ivanova, L.S. Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ Functional Materials |
| description |
The results of our study deal with the NQR spectra of ¹²⁷| at 77 K in mixed layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ in a wide range of content Pbl₂ and Bil ₃ 0 < x < 1. It is shown that in the range of content 0 < x < 0.02 the crystal (Bil₃)₍₁₋ₓ₎(Pbl₂)ₓ has the properties of the impure crystal Pbl₂, which contains intralayer Bil₃ clusters, and in the range 0.8 < x < 1 it contains intralayer clusters Pbl2. Under the concentration x = 0.10 and x = 0.80 the crystal (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ undergoes a phase transition and in the concentration range 0.1 < x < 0.8 there is a new crystal (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ, in which groups of atoms Pbl₂ and Pbl₃ are intercalants fully or partially ordered in the crystal system. |
| format |
Article |
| author |
Barabash, O.I. Vertegel, I.G. Chesnokov, E.D. Ovcharenko, O.I. Ivanova, L.S. |
| author_facet |
Barabash, O.I. Vertegel, I.G. Chesnokov, E.D. Ovcharenko, O.I. Ivanova, L.S. |
| author_sort |
Barabash, O.I. |
| title |
Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ |
| title_short |
Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ |
| title_full |
Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ |
| title_fullStr |
Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ |
| title_full_unstemmed |
Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI₂)₍₁₋ₓ₎(BiI₃)ₓ |
| title_sort |
symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (pbi₂)₍₁₋ₓ₎(bii₃)ₓ |
| publisher |
НТК «Інститут монокристалів» НАН України |
| publishDate |
2012 |
| topic_facet |
Characterization and properties |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/135310 |
| citation_txt |
Symmetry peculiarities of the intracrystalline fields layered semiconductor crystals (PbI2)(1-x)(BiI3)x / O.I. Barabash, I.G. Vertegel, E.D. Chesnokov, O.I. Ovcharenko, L.S. Ivanova // Functional Materials. — 2012. — Т. 19, № 3. — С. 330-333. — Бібліогр.: 11 назв. — англ. |
| series |
Functional Materials |
| work_keys_str_mv |
AT barabashoi symmetrypeculiaritiesoftheintracrystallinefieldslayeredsemiconductorcrystalspbi21xbii3x AT vertegelig symmetrypeculiaritiesoftheintracrystallinefieldslayeredsemiconductorcrystalspbi21xbii3x AT chesnokoved symmetrypeculiaritiesoftheintracrystallinefieldslayeredsemiconductorcrystalspbi21xbii3x AT ovcharenkooi symmetrypeculiaritiesoftheintracrystallinefieldslayeredsemiconductorcrystalspbi21xbii3x AT ivanovals symmetrypeculiaritiesoftheintracrystallinefieldslayeredsemiconductorcrystalspbi21xbii3x |
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2023-10-18T21:10:53Z |
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2023-10-18T21:10:53Z |
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