Electronic structure peculiarities of disordered Mn and Co diphosphates
Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in i...
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| Дата: | 2012 |
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| Автори: | , , , |
| Формат: | Стаття |
| Мова: | English |
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НТК «Інститут монокристалів» НАН України
2012
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| Назва видання: | Functional Materials |
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| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/135380 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1353802018-06-16T03:09:07Z Electronic structure peculiarities of disordered Mn and Co diphosphates Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. Characterization and properties Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in increase of the chemical bond ionicity between oxygen anions and the metal cations. Such charge redistribution is responsible for forma¬tion of the states laying in the upper part of the valence band. 2012 Article Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/135380 en Functional Materials НТК «Інститут монокристалів» НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Characterization and properties Characterization and properties |
| spellingShingle |
Characterization and properties Characterization and properties Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. Electronic structure peculiarities of disordered Mn and Co diphosphates Functional Materials |
| description |
Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in increase of the chemical bond ionicity between oxygen anions and the metal cations. Such charge redistribution is responsible for forma¬tion of the states laying in the upper part of the valence band. |
| format |
Article |
| author |
Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. |
| author_facet |
Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. |
| author_sort |
Karbivskyy, V.L. |
| title |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_short |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_full |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_fullStr |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_full_unstemmed |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_sort |
electronic structure peculiarities of disordered mn and co diphosphates |
| publisher |
НТК «Інститут монокристалів» НАН України |
| publishDate |
2012 |
| topic_facet |
Characterization and properties |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/135380 |
| citation_txt |
Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. |
| series |
Functional Materials |
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2023-10-18T21:11:44Z |
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2023-10-18T21:11:44Z |
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