Ion exchange in photoactivated inorganic matters

The effects of monovalent and bivalent impurities on the diffusive mobility sodium, caesium and strontium in magnesium potassium phosphate hexahydrate and clinoptilolite were analysed. It was determined that ratio of diffusion coeffcients of sodium concerning caesium and strontium are in antagonisti...

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Date:2017
Main Authors: Dikiy, N.P., Dovbnya, A.N., Lyashko, Yu.V., Medvedev, D.V., Medvedeva, E.P., Parhomenko, Yu.G., Uvarov, V.L., Fedorets, I.D.
Format: Article
Language:English
Published: Національний науковий центр «Харківський фізико-технічний інститут» НАН України 2017
Series:Вопросы атомной науки и техники
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Online Access:http://dspace.nbuv.gov.ua/handle/123456789/136064
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Ion exchange in photoactivated inorganic matters / N.P. Dikiy, A.N. Dovbnya, Yu.V. Lyashko, D.V. Medvedev, E.P. Medvedeva, Yu.G. Parhomenko, V.L. Uvarov, I.D. Fedorets // Вопросы атомной науки и техники. — 2017. — № 3. — С. 40-44. — Бібліогр.: 13 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Summary:The effects of monovalent and bivalent impurities on the diffusive mobility sodium, caesium and strontium in magnesium potassium phosphate hexahydrate and clinoptilolite were analysed. It was determined that ratio of diffusion coeffcients of sodium concerning caesium and strontium are in antagonistic dependence on the caesium and strontium content in a matrices on the basis of magnesium potassium phosphate hexahydrate. It is established that the diffusion process in the magnesium potassium phosphate hexahydrate is due to the Frenkel. The influence of the diffusion of impurity elements as a function of the ionic radius and the ion position in the crystal lattice of clinoptilolite has been studied.