Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇

Using the luminescence spectroscopy, the stability of Eu²⁺ ions in SrBPO₅ has been shown to exceed significantly that in SrAl₂B₂O₇. The luminescence spectrum of Eu²⁺ in SrBPO₅ and SrAl₂B₂O₇ consists of a broad band with a maximum at 390 and 490 nm, respectively. In contrast to SrBPO₅, the stabilizat...

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Видавець:НТК «Інститут монокристалів» НАН України
Дата:2007
Автори: Pir, P.V., Dotsenko, V.P., Efryushina, N.P, Klimenko, Z.D.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2007
Назва видання:Functional Materials
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/136439
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Цитувати:Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇ / P.V. Pir, V.P. Dotsenko, N.P Efryushina, Z.D. Klimenko // Functional Materials. — 2007. — Т. 14, № 1. — С. 57-60. — Бібліогр.: 11 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id irk-123456789-136439
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spelling irk-123456789-1364392018-06-17T03:07:22Z Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇ Pir, P.V. Dotsenko, V.P. Efryushina, N.P Klimenko, Z.D. Using the luminescence spectroscopy, the stability of Eu²⁺ ions in SrBPO₅ has been shown to exceed significantly that in SrAl₂B₂O₇. The luminescence spectrum of Eu²⁺ in SrBPO₅ and SrAl₂B₂O₇ consists of a broad band with a maximum at 390 and 490 nm, respectively. In contrast to SrBPO₅, the stabilization of Eu²⁺ ions in SrAl₂B₂O₇ requires an annealing in reducing medium. It is supposed that this is caused by the difference in the effectiveness of the excess charge compensating processes for Eu³⁺ which can be quantified by the formal volume per oxygen atom (V₀) in the compound structure. 2007 Article Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇ / P.V. Pir, V.P. Dotsenko, N.P Efryushina, Z.D. Klimenko // Functional Materials. — 2007. — Т. 14, № 1. — С. 57-60. — Бібліогр.: 11 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/136439 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description Using the luminescence spectroscopy, the stability of Eu²⁺ ions in SrBPO₅ has been shown to exceed significantly that in SrAl₂B₂O₇. The luminescence spectrum of Eu²⁺ in SrBPO₅ and SrAl₂B₂O₇ consists of a broad band with a maximum at 390 and 490 nm, respectively. In contrast to SrBPO₅, the stabilization of Eu²⁺ ions in SrAl₂B₂O₇ requires an annealing in reducing medium. It is supposed that this is caused by the difference in the effectiveness of the excess charge compensating processes for Eu³⁺ which can be quantified by the formal volume per oxygen atom (V₀) in the compound structure.
format Article
author Pir, P.V.
Dotsenko, V.P.
Efryushina, N.P
Klimenko, Z.D.
spellingShingle Pir, P.V.
Dotsenko, V.P.
Efryushina, N.P
Klimenko, Z.D.
Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇
Functional Materials
author_facet Pir, P.V.
Dotsenko, V.P.
Efryushina, N.P
Klimenko, Z.D.
author_sort Pir, P.V.
title Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇
title_short Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇
title_full Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇
title_fullStr Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇
title_full_unstemmed Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇
title_sort luminescent properties and stability of eu²⁺ ions in srbpo₅ and sral₂b₂o₇
publisher НТК «Інститут монокристалів» НАН України
publishDate 2007
url http://dspace.nbuv.gov.ua/handle/123456789/136439
citation_txt Luminescent properties and stability of Eu²⁺ ions in SrBPO₅ and SrAl₂B₂O₇ / P.V. Pir, V.P. Dotsenko, N.P Efryushina, Z.D. Klimenko // Functional Materials. — 2007. — Т. 14, № 1. — С. 57-60. — Бібліогр.: 11 назв. — англ.
series Functional Materials
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