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Scaling properties of dendrimers with long flexible branches

Monte-Carlo computer simulation as well as theoretical estimate of the properties of dendrimers with long, flexible branches in good solvent were conducted. It was shown that such dendrimers demonstrate universal behavior independent on details of their internal building. In particular, there exist...

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Bibliographic Details
Main Author: Ratner, M.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2007
Series:Functional Materials
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/136485
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spelling irk-123456789-1364852018-06-17T03:09:12Z Scaling properties of dendrimers with long flexible branches Ratner, M. Monte-Carlo computer simulation as well as theoretical estimate of the properties of dendrimers with long, flexible branches in good solvent were conducted. It was shown that such dendrimers demonstrate universal behavior independent on details of their internal building. In particular, there exist a critical dendrimer generation number Gcr≈5 that signifies the transfer from coil-type structure with properties similar to linear polymer coil to fractal structure (with fractal dimension ε≈1.82). Numerical simulations as well as theoretical estimate shows that both Gcr and E (at G > Gcr) are independent on the number of spacers M in dendrimer branch and on dendrimer generation G (at G > Gcr). 2007 Article Scaling properties of dendrimers with long flexible branches / M. Ratner // A.V. Kolisnikov // Functional Materials. — 2007. — Т. 14, № 2. — С. 171-176. — Бібліогр.: 5 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/136485 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description Monte-Carlo computer simulation as well as theoretical estimate of the properties of dendrimers with long, flexible branches in good solvent were conducted. It was shown that such dendrimers demonstrate universal behavior independent on details of their internal building. In particular, there exist a critical dendrimer generation number Gcr≈5 that signifies the transfer from coil-type structure with properties similar to linear polymer coil to fractal structure (with fractal dimension ε≈1.82). Numerical simulations as well as theoretical estimate shows that both Gcr and E (at G > Gcr) are independent on the number of spacers M in dendrimer branch and on dendrimer generation G (at G > Gcr).
format Article
author Ratner, M.
spellingShingle Ratner, M.
Scaling properties of dendrimers with long flexible branches
Functional Materials
author_facet Ratner, M.
author_sort Ratner, M.
title Scaling properties of dendrimers with long flexible branches
title_short Scaling properties of dendrimers with long flexible branches
title_full Scaling properties of dendrimers with long flexible branches
title_fullStr Scaling properties of dendrimers with long flexible branches
title_full_unstemmed Scaling properties of dendrimers with long flexible branches
title_sort scaling properties of dendrimers with long flexible branches
publisher НТК «Інститут монокристалів» НАН України
publishDate 2007
url http://dspace.nbuv.gov.ua/handle/123456789/136485
citation_txt Scaling properties of dendrimers with long flexible branches / M. Ratner // A.V. Kolisnikov // Functional Materials. — 2007. — Т. 14, № 2. — С. 171-176. — Бібліогр.: 5 назв. — англ.
series Functional Materials
work_keys_str_mv AT ratnerm scalingpropertiesofdendrimerswithlongflexiblebranches
first_indexed 2023-10-18T21:13:17Z
last_indexed 2023-10-18T21:13:17Z
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