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Synthesis of strontium tetroborate SrB₄O₇ for single crystal growth

The possiblility of the single phase SrB₄O₇ synthesis the amorphous phase formation stage has been shown. Using XPA and DTA methods, the formation of strontium borate hydrates has been determined to occur at T = 95±5°C in the course of strontium carbonate interaction with boric acid. The dehydration...

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Bibliographic Details
Main Authors: Korshikova, T.I., Parkhomenko, S.V., Tolmachev, A.V., Yavetskiy, R.P.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2007
Series:Functional Materials
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/136489
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Summary:The possiblility of the single phase SrB₄O₇ synthesis the amorphous phase formation stage has been shown. Using XPA and DTA methods, the formation of strontium borate hydrates has been determined to occur at T = 95±5°C in the course of strontium carbonate interaction with boric acid. The dehydration of strontium borate crystal hydrates results in amorphous phase formation. A further phase transition (borate rearrangement) of this phase at T = 750°C results in formation of polycrystalline SrB₄O₇.