Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions
This article studies the regularities of formation of isostructural to langbeinite phosphates from solutions in melts under crystallization conditions for K₂O-P₂O₅-M<m^>III₂O₃-SnO₂ (MIII - Fe, Cr) and K₂O-P₂O₅-LnF₃-SnO₂ (Ln - Y, REE) systems. Based on X-ray powder diffraction method the phase...
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| Дата: | 2017 |
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| Формат: | Стаття |
| Мова: | English |
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НТК «Інститут монокристалів» НАН України
2017
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| Назва видання: | Functional Materials |
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| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/136747 |
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| Цитувати: | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions / I.V. Zatovsky, N.S. Slobodyanik, T.I. Ushchapivska, W. Han // Functional Materials. — 2017. — Т. 24, № 2. — С. 298-302. — Бібліогр.: 15 назв. — англ. |
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irk-123456789-1367472018-06-17T03:09:41Z Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions Zatovsky, I.V. Slobodyanik, N.S. Ushchapivska, T.I. Han, W. Technology This article studies the regularities of formation of isostructural to langbeinite phosphates from solutions in melts under crystallization conditions for K₂O-P₂O₅-M<m^>III₂O₃-SnO₂ (MIII - Fe, Cr) and K₂O-P₂O₅-LnF₃-SnO₂ (Ln - Y, REE) systems. Based on X-ray powder diffraction method the phase composition of synthesized samples and lattice parameters have been determined for a number of new compounds with common composition K₂MIIISn(PO₄)₃. Analysis of obtained results shows that the crystallochemical criterion for formation of langbeinite-type framework on the basis of different multivalent metals is the difference in their ionic radii up to 35 %. 2017 Article Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions / I.V. Zatovsky, N.S. Slobodyanik, T.I. Ushchapivska, W. Han // Functional Materials. — 2017. — Т. 24, № 2. — С. 298-302. — Бібліогр.: 15 назв. — англ. 1027-5495 DOI: https://doi.org/10.15407/fm24.02.298 http://dspace.nbuv.gov.ua/handle/123456789/136747 en Functional Materials НТК «Інститут монокристалів» НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Technology Technology |
| spellingShingle |
Technology Technology Zatovsky, I.V. Slobodyanik, N.S. Ushchapivska, T.I. Han, W. Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions Functional Materials |
| description |
This article studies the regularities of formation of isostructural to langbeinite phosphates from solutions in melts under crystallization conditions for K₂O-P₂O₅-M<m^>III₂O₃-SnO₂ (MIII - Fe, Cr) and K₂O-P₂O₅-LnF₃-SnO₂ (Ln - Y, REE) systems. Based on X-ray powder diffraction method the phase composition of synthesized samples and lattice parameters have been determined for a number of new compounds with common composition K₂MIIISn(PO₄)₃. Analysis of obtained results shows that the crystallochemical criterion for formation of langbeinite-type framework on the basis of different multivalent metals is the difference in their ionic radii up to 35 %. |
| format |
Article |
| author |
Zatovsky, I.V. Slobodyanik, N.S. Ushchapivska, T.I. Han, W. |
| author_facet |
Zatovsky, I.V. Slobodyanik, N.S. Ushchapivska, T.I. Han, W. |
| author_sort |
Zatovsky, I.V. |
| title |
Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_short |
Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_full |
Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_fullStr |
Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_full_unstemmed |
Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_sort |
formation of complex phosphates k₂mᴵᴵᴵsn(po₄)₃ from solutions in melts under crystallization conditions |
| publisher |
НТК «Інститут монокристалів» НАН України |
| publishDate |
2017 |
| topic_facet |
Technology |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/136747 |
| citation_txt |
Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions / I.V. Zatovsky, N.S. Slobodyanik, T.I. Ushchapivska, W. Han // Functional Materials. — 2017. — Т. 24, № 2. — С. 298-302. — Бібліогр.: 15 назв. — англ. |
| series |
Functional Materials |
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2023-10-18T21:14:02Z |
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2023-10-18T21:14:02Z |
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