Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine)
Crystalline and molecular structure of previously synthesized by the authors anion-radical salt (ARS) 7,7,8,8-tetracyanoquinodimethane (TCNQ) of an unusual [N-(H₅C₂)-Pz](TCNQ)₃ composition (where Pz is pyrazine) has been determined. The structure of the given ARS is also unusual because unlike...
Збережено в:
| Дата: | 2005 |
|---|---|
| Автори: | , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
НТК «Інститут монокристалів» НАН України
2005
|
| Назва видання: | Functional Materials |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/138860 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) / D.V. Ziolkovskiy, A.V. Kravchenko, V.A. Starodub, O.N. Kazheva, A.V. Khotkevich // Functional Materials. — 2005. — Т. 12, № 3. — С. 577-582. — Бібліогр.: 15 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-138860 |
|---|---|
| record_format |
dspace |
| spelling |
irk-123456789-1388602018-06-20T03:07:21Z Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) Ziolkovskiy, D.V. Kravchenko, A.V. Starodub, V.A. Kazheva, O.N. Khotkevich, A.V. Crystalline and molecular structure of previously synthesized by the authors anion-radical salt (ARS) 7,7,8,8-tetracyanoquinodimethane (TCNQ) of an unusual [N-(H₅C₂)-Pz](TCNQ)₃ composition (where Pz is pyrazine) has been determined. The structure of the given ARS is also unusual because unlike most of structures known it consists of bulks formed by two А and С TCNQ types, particles of the third В type being located at the angle of 117.7 and respectively 117.4 degrees relatively to them. С type particles interact appreciable with pyrazine cations through pyrazine non-alkylated nitrogen atom. В-type particles as well as TCNQ particles in columns, possess an appreciable charge (about -0.3).Such a peculiarity of structure renders ARS electronic system some what two-dimensional that is unusual for TCNQ ARS and agrees with the electrophysical measurements. Определена кристаллическая и молекулярная структура синтезированной ранее авторами анион-радикальной соли (АРС) 7,7,8,8-тетрацианохинодиметана (TCNQ) необычного состава [N-(H₅C₂)-Pz](TCNQ)₃, где Pz - пиразин. Структура данной АРС также необычна - в отличие от большинства известных структур, она состоит из стопок, образованных двумя типами TCNQ - А и С, перпендикулярно которым расположены частицы третьего типа - В. Частицы типа С заметно взаимодействуют с катионами пиразина посредством неалкилированного атома азота пиразина. Частицы типа В, как и частицы TCNQ в стопках, обладают заметным зарядом (около -0,3). Такая особенность структуры придает электронной системе АРС определенную двумерность, необычную для АРС TCNQ, и согласуется с результатами электрофизических измерений. Визначено кристалiчну i молекулярну структуру синтезованої авторами ранiше анiон-радикальної солi (АРС) 7,7,8,8-тетрацiанохiнодиметану (TCNQ) незвичайного складу [N-(H₅C₂)-Pz](TCNQ)₃, де Pz - пiразин. Структура даної АРС також незвичайна - на вiдмiну вiд бiльшостi вiдомих структур, вона складається зi стопок, утворених двома типами TCNQ - А та С, перпендикулярно яким розташованi частки третього типу - В. Частки типу С помiтно взаємодiють з катiонами пiразину за допомогою неалкильованого атому азоту пiразину. Частки типу В, як i частки TCNQ у стопках, мають помiтний заряд (близько -0,3). Така особливiсть структури додає електроннiй системi АРС певну двомiрнiсть, незвичайну для АРС TCNQ, i добре узгоджується з результатами електрофiзичних вимiрiв. 2005 Article Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) / D.V. Ziolkovskiy, A.V. Kravchenko, V.A. Starodub, O.N. Kazheva, A.V. Khotkevich // Functional Materials. — 2005. — Т. 12, № 3. — С. 577-582. — Бібліогр.: 15 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/138860 en Functional Materials НТК «Інститут монокристалів» НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
Crystalline and molecular structure of previously synthesized by the authors anion-radical salt (ARS) 7,7,8,8-tetracyanoquinodimethane (TCNQ) of an unusual [N-(H₅C₂)-Pz](TCNQ)₃ composition (where Pz is pyrazine) has been determined. The structure of the given ARS is also unusual because unlike most of structures known it consists of bulks formed by two А and С TCNQ types, particles of the third В type being located at the angle of 117.7 and respectively 117.4 degrees relatively to them. С type particles interact appreciable with pyrazine cations through pyrazine non-alkylated nitrogen atom. В-type particles as well as TCNQ particles in columns, possess an appreciable charge (about -0.3).Such a peculiarity of structure renders ARS electronic system some what two-dimensional that is unusual for TCNQ ARS and agrees with the electrophysical measurements. |
| format |
Article |
| author |
Ziolkovskiy, D.V. Kravchenko, A.V. Starodub, V.A. Kazheva, O.N. Khotkevich, A.V. |
| spellingShingle |
Ziolkovskiy, D.V. Kravchenko, A.V. Starodub, V.A. Kazheva, O.N. Khotkevich, A.V. Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) Functional Materials |
| author_facet |
Ziolkovskiy, D.V. Kravchenko, A.V. Starodub, V.A. Kazheva, O.N. Khotkevich, A.V. |
| author_sort |
Ziolkovskiy, D.V. |
| title |
Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) |
| title_short |
Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) |
| title_full |
Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) |
| title_fullStr |
Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) |
| title_full_unstemmed |
Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) |
| title_sort |
crystalline and molecular structure of novel anion-radical salt (n-et-pz)(tcnq)₃ (pz is pyrazine) |
| publisher |
НТК «Інститут монокристалів» НАН України |
| publishDate |
2005 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/138860 |
| citation_txt |
Crystalline and molecular structure of novel anion-radical salt (N-Et-Pz)(TCNQ)₃ (Pz is pyrazine) / D.V. Ziolkovskiy, A.V. Kravchenko, V.A. Starodub, O.N. Kazheva, A.V. Khotkevich // Functional Materials. — 2005. — Т. 12, № 3. — С. 577-582. — Бібліогр.: 15 назв. — англ. |
| series |
Functional Materials |
| work_keys_str_mv |
AT ziolkovskiydv crystallineandmolecularstructureofnovelanionradicalsaltnetpztcnq3pzispyrazine AT kravchenkoav crystallineandmolecularstructureofnovelanionradicalsaltnetpztcnq3pzispyrazine AT starodubva crystallineandmolecularstructureofnovelanionradicalsaltnetpztcnq3pzispyrazine AT kazhevaon crystallineandmolecularstructureofnovelanionradicalsaltnetpztcnq3pzispyrazine AT khotkevichav crystallineandmolecularstructureofnovelanionradicalsaltnetpztcnq3pzispyrazine |
| first_indexed |
2023-10-18T21:19:31Z |
| last_indexed |
2023-10-18T21:19:31Z |
| _version_ |
1796152511669731328 |