Deep traps in KMgF₃ and LiBaF₃ crystals

The influence of the high temperature annealing in air to the deep traps formation in KMgF₃ and LiBaF₃ fluoroperovskites was the subject of this study. An additional absorption and blue emission connected with O²⁻ ions presence in annealed crystal were revealed. The thermal destruction of colour cen...

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Бібліографічні деталі
Дата:2004
Автори: Gektin, A.V., Shiran, N.V., Neicheva, S.V., Krasovitskaya, I.M.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2004
Назва видання:Functional Materials
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/139496
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Deep traps in KMgF₃ and LiBaF₃ crystals / A.V. Gektin, N.V. Shiran, S.V. Neicheva, I.M. Krasovitskaya // Functional Materials. — 2004. — Т. 11, № 4. — С. 680-683. — Бібліогр.: 8 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:The influence of the high temperature annealing in air to the deep traps formation in KMgF₃ and LiBaF₃ fluoroperovskites was the subject of this study. An additional absorption and blue emission connected with O²⁻ ions presence in annealed crystal were revealed. The thermal destruction of colour centres in x-irradiated samples is accompanied by intensive recombination luminescence in high temperature TSL peaks. This phenomena was explained by pyrohydrolysis of crystal surface and oxygen diffusion into the crystal volume. Hydrolysed crystals were found to store the energy under UV irradiation.