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Determination of cerium valence state in alkali and alkali-earth borates

Determination of cerium valence state in alkali and alkali-earth borates

Procedures have been elaborated for rapid, selective, and high-precise determination of Ce(IV) and total cerium content in the raw blends and single crystals of scintillators on the basis of cerium-doped alkali and rari-earth borates. Ce(IV) was determined by photometry after dissolution of the samp...

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Main Authors: Gaiduk, O.V., Pantaler, R.P., Blank, A.B.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2005
Series:Functional Materials
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/139743
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spelling irk-123456789-1397432018-06-22T03:04:09Z Determination of cerium valence state in alkali and alkali-earth borates Gaiduk, O.V. Pantaler, R.P. Blank, A.B. Procedures have been elaborated for rapid, selective, and high-precise determination of Ce(IV) and total cerium content in the raw blends and single crystals of scintillators on the basis of cerium-doped alkali and rari-earth borates. Ce(IV) was determined by photometry after dissolution of the samples in sulfuric acid containing o-tolidine at room temperature. Разработаны методики, позволяющие быстро, селективно и с высокой точностью определить содержание Ce(IV) и общего церия в шихте и монокристаллах сцинтилляторов на основе боратов щелочных и редкоземельных элементов, активированных церием. Ce(IV) определяли фотометрическим методом после растворения анализируемого образца в сернокислом растворе о-толидина при комнатной температуре. Розроблено методики, що дозволяють швидко, селективно та з високою точністю визначити вміст Ce(IV) і загального церію у шихті та монокристалах сцинтиляторів на основі боратів лужних та рідкісноземельньїх елементів активованих церієм. Ce(IV) визначали фотометричним методом після розчинення зразку, що аналізується, у сірчанокислому розчині о-толідину при кімнатній температурі. 2005 Article Determination of cerium valence state in alkali and alkali-earth borates / O.V. Gaiduk, R.P. Pantaler, A.B. Blank // Functional Materials. — 2005. — Т. 12, № 1. — С. 69-71. — Бібліогр.: 8 назв. — англ. 1027-5495 http://dspace.nbuv.gov.ua/handle/123456789/139743 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description Procedures have been elaborated for rapid, selective, and high-precise determination of Ce(IV) and total cerium content in the raw blends and single crystals of scintillators on the basis of cerium-doped alkali and rari-earth borates. Ce(IV) was determined by photometry after dissolution of the samples in sulfuric acid containing o-tolidine at room temperature.
format Article
author Gaiduk, O.V.
Pantaler, R.P.
Blank, A.B.
spellingShingle Gaiduk, O.V.
Pantaler, R.P.
Blank, A.B.
Determination of cerium valence state in alkali and alkali-earth borates
Functional Materials
author_facet Gaiduk, O.V.
Pantaler, R.P.
Blank, A.B.
author_sort Gaiduk, O.V.
title Determination of cerium valence state in alkali and alkali-earth borates
title_short Determination of cerium valence state in alkali and alkali-earth borates
title_full Determination of cerium valence state in alkali and alkali-earth borates
title_fullStr Determination of cerium valence state in alkali and alkali-earth borates
title_full_unstemmed Determination of cerium valence state in alkali and alkali-earth borates
title_sort determination of cerium valence state in alkali and alkali-earth borates
publisher НТК «Інститут монокристалів» НАН України
publishDate 2005
url http://dspace.nbuv.gov.ua/handle/123456789/139743
citation_txt Determination of cerium valence state in alkali and alkali-earth borates / O.V. Gaiduk, R.P. Pantaler, A.B. Blank // Functional Materials. — 2005. — Т. 12, № 1. — С. 69-71. — Бібліогр.: 8 назв. — англ.
series Functional Materials
work_keys_str_mv AT gaidukov determinationofceriumvalencestateinalkaliandalkaliearthborates
AT pantalerrp determinationofceriumvalencestateinalkaliandalkaliearthborates
AT blankab determinationofceriumvalencestateinalkaliandalkaliearthborates
first_indexed 2023-10-18T21:21:17Z
last_indexed 2023-10-18T21:21:17Z
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