Study of thallium iodide dissolution kinetics in aqueous sodium iodide solutions in production conditions

The kinetics of thallium iodide dissolution in sodium iodide solutions at concentration of the latter ranging from 0.6 to 6.3 mol/dm³ has been investigated. An essential time-depended variation of thallium iodide dissolution rate has been established. Consideration of thallium iodide solubility de...

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Bibliographic Details
Date:2006
Main Authors: Babich, G.A., Blank, A.B., Kisil', E.P., Filippovich, L.I.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2006
Series:Functional Materials
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Online Access:http://dspace.nbuv.gov.ua/handle/123456789/139967
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Study of thallium iodide dissolution kinetics in aqueous sodium iodide solutions in production conditions / G.A. Babich, A.B. Blank, E.P. Kisil', L.I. Filippovich // Functional Materials. — 2006. — Т. 13, № 1. — С. 139-143. — Бібліогр.: 7 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Summary:The kinetics of thallium iodide dissolution in sodium iodide solutions at concentration of the latter ranging from 0.6 to 6.3 mol/dm³ has been investigated. An essential time-depended variation of thallium iodide dissolution rate has been established. Consideration of thallium iodide solubility dependence on sodium iodide concentration under varying eхperimental conditions has evidenced the presence of two parallel processes. The first is an equilibrium one and is connected with formation of thallium ion compleх with iodide ions. The second process is non-equilibrium one and is due to interaction with iodine.