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Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory

Gas-liquid criticality in the ultrasoft restricted primitive model (URPM) of polyelectrolytes is studied using the collective variables-based theory. For the model, an effective Hamiltonian is derived and explicit expressions for all the coefficients are found in a one-loop approximation. Based on t...

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Main Author: Patsahan, O.
Format: Article
Language:English
Published: Інститут фізики конденсованих систем НАН України 2015
Series:Condensed Matter Physics
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/153588
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spelling irk-123456789-1535882019-06-15T01:25:15Z Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory Patsahan, O. Gas-liquid criticality in the ultrasoft restricted primitive model (URPM) of polyelectrolytes is studied using the collective variables-based theory. For the model, an effective Hamiltonian is derived and explicit expressions for all the coefficients are found in a one-loop approximation. Based on this Hamiltonian, the phase and critical behaviour is analysed. Our results provide evidence that the nature of the gas-liquid criticality in the URPM is the same as in the restricted primitive model that includes a hard core. Вивчається критичнiсть газ-рiдина ультрам’якої обмеженої примiтивної моделi (URPM) полiелектролiтiв, використовуючи теорiю, що базується на методi колективних змiнних. Для цiєї моделi виведено ефективний гамiльтонiан i отримано явнi вирази для всiх коефiцiєнтiв в однопетлевому наближеннi. На основi цього гамiльтонiану аналiзується фазова i критична поведiнка. Отриманi результати свiдчать про те, що природа критичностi газ-рiдина в URPM є такою ж, як i в обмеженiй примiтивнiй моделi, яка включає твердий кор. 2015 Article Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory / O. Patsahan // Condensed Matter Physics. — 2015. — Т. 18, № 2. — С. 24601: 1–6. — Бібліогр.: 17 назв. — англ. 1607-324X PACS: 64.75.-g, 64.60.De, 64.75.Cd, 64.60.fd DOI:10.5488/CMP.18.24601 arXiv:1504.06153 http://dspace.nbuv.gov.ua/handle/123456789/153588 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
description Gas-liquid criticality in the ultrasoft restricted primitive model (URPM) of polyelectrolytes is studied using the collective variables-based theory. For the model, an effective Hamiltonian is derived and explicit expressions for all the coefficients are found in a one-loop approximation. Based on this Hamiltonian, the phase and critical behaviour is analysed. Our results provide evidence that the nature of the gas-liquid criticality in the URPM is the same as in the restricted primitive model that includes a hard core.
format Article
author Patsahan, O.
spellingShingle Patsahan, O.
Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory
Condensed Matter Physics
author_facet Patsahan, O.
author_sort Patsahan, O.
title Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory
title_short Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory
title_full Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory
title_fullStr Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory
title_full_unstemmed Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory
title_sort gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory
publisher Інститут фізики конденсованих систем НАН України
publishDate 2015
url http://dspace.nbuv.gov.ua/handle/123456789/153588
citation_txt Gas-liquid critical point of the ultrasoft restricted primitive model from analytic theory / O. Patsahan // Condensed Matter Physics. — 2015. — Т. 18, № 2. — С. 24601: 1–6. — Бібліогр.: 17 назв. — англ.
series Condensed Matter Physics
work_keys_str_mv AT patsahano gasliquidcriticalpointoftheultrasoftrestrictedprimitivemodelfromanalytictheory
first_indexed 2023-05-20T17:41:48Z
last_indexed 2023-05-20T17:41:48Z
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