Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II)

Peculiarities of thermal solid-phase transformations of Co₁₋xMnxHPO₄·1.5 H₂O (0 ≤ x ≤ 0.45), which accompanying the formation of a final product of thermolysis - anhydrous diphosphate solid solution with composition β-(Co₁₋xMnx)₂P₂O₇ (0 < x le; 0.45) are established. It is shown that low-temperat...

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Збережено в:
Бібліографічні деталі
Дата:2018
Автори: Antraptseva, N.M., Solod, N.V., Zhyla, R.S.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2018
Назва видання:Functional Materials
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/154445
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) / N.M. Antraptseva, N.V. Solod, R.S. Zhyla // Functional Materials. — 2018. — Т. 25, № 1. — С. 151-157. — Бібліогр.: 14 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:Peculiarities of thermal solid-phase transformations of Co₁₋xMnxHPO₄·1.5 H₂O (0 ≤ x ≤ 0.45), which accompanying the formation of a final product of thermolysis - anhydrous diphosphate solid solution with composition β-(Co₁₋xMnx)₂P₂O₇ (0 < x le; 0.45) are established. It is shown that low-temperature α-modification of the diphosphate is the first formed during heat treatment of the hydrogenphosphates Co₁₋xMnxHPO₄·1.5H₂O with 0 <x ≤ 0.15. Crystalline β-(Co₁₋xMnx)₂P₂O₇ (x≤0.15) is formed only after the polymorphic transformation of the α-form into the β-form. The formation of β-(Co₁₋xMnx)₂P₂O₇ with 0.15 < x ≤ 0.45 occurs bypassing the α-form. Free phosphoric acid during the heat treatment Co₁₋xMnxHPO₄·1.5H₂O (0 < x ≤ 0.45) are is not formed.