Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II)
Peculiarities of thermal solid-phase transformations of Co₁₋xMnxHPO₄·1.5 H₂O (0 ≤ x ≤ 0.45), which accompanying the formation of a final product of thermolysis - anhydrous diphosphate solid solution with composition β-(Co₁₋xMnx)₂P₂O₇ (0 < x le; 0.45) are established. It is shown that low-temperat...
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| Дата: | 2018 |
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| Формат: | Стаття |
| Мова: | English |
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НТК «Інститут монокристалів» НАН України
2018
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| Назва видання: | Functional Materials |
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| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/154445 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) / N.M. Antraptseva, N.V. Solod, R.S. Zhyla // Functional Materials. — 2018. — Т. 25, № 1. — С. 151-157. — Бібліогр.: 14 назв. — англ. |
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irk-123456789-1544452019-06-16T01:28:52Z Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) Antraptseva, N.M. Solod, N.V. Zhyla, R.S. Technology Peculiarities of thermal solid-phase transformations of Co₁₋xMnxHPO₄·1.5 H₂O (0 ≤ x ≤ 0.45), which accompanying the formation of a final product of thermolysis - anhydrous diphosphate solid solution with composition β-(Co₁₋xMnx)₂P₂O₇ (0 < x le; 0.45) are established. It is shown that low-temperature α-modification of the diphosphate is the first formed during heat treatment of the hydrogenphosphates Co₁₋xMnxHPO₄·1.5H₂O with 0 <x ≤ 0.15. Crystalline β-(Co₁₋xMnx)₂P₂O₇ (x≤0.15) is formed only after the polymorphic transformation of the α-form into the β-form. The formation of β-(Co₁₋xMnx)₂P₂O₇ with 0.15 < x ≤ 0.45 occurs bypassing the α-form. Free phosphoric acid during the heat treatment Co₁₋xMnxHPO₄·1.5H₂O (0 < x ≤ 0.45) are is not formed. 2018 Article Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) / N.M. Antraptseva, N.V. Solod, R.S. Zhyla // Functional Materials. — 2018. — Т. 25, № 1. — С. 151-157. — Бібліогр.: 14 назв. — англ. 1027-5495 DOI:https://doi.org/10.15407/fm25.01.151 http://dspace.nbuv.gov.ua/handle/123456789/154445 en Functional Materials НТК «Інститут монокристалів» НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Technology Technology |
| spellingShingle |
Technology Technology Antraptseva, N.M. Solod, N.V. Zhyla, R.S. Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) Functional Materials |
| description |
Peculiarities of thermal solid-phase transformations of Co₁₋xMnxHPO₄·1.5 H₂O (0 ≤ x ≤ 0.45), which accompanying the formation of a final product of thermolysis - anhydrous diphosphate solid solution with composition β-(Co₁₋xMnx)₂P₂O₇ (0 < x le; 0.45) are established. It is shown that low-temperature α-modification of the diphosphate is the first formed during heat treatment of the hydrogenphosphates Co₁₋xMnxHPO₄·1.5H₂O with 0 <x ≤ 0.15. Crystalline β-(Co₁₋xMnx)₂P₂O₇ (x≤0.15) is formed only after the polymorphic transformation of the α-form into the β-form. The formation of β-(Co₁₋xMnx)₂P₂O₇ with 0.15 < x ≤ 0.45 occurs bypassing the α-form. Free phosphoric acid during the heat treatment Co₁₋xMnxHPO₄·1.5H₂O (0 < x ≤ 0.45) are is not formed. |
| format |
Article |
| author |
Antraptseva, N.M. Solod, N.V. Zhyla, R.S. |
| author_facet |
Antraptseva, N.M. Solod, N.V. Zhyla, R.S. |
| author_sort |
Antraptseva, N.M. |
| title |
Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_short |
Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_full |
Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_fullStr |
Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_full_unstemmed |
Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_sort |
peculiarities of thermal solid-phase transformations of hydrogenphosphates co(ii)-mn(ii) |
| publisher |
НТК «Інститут монокристалів» НАН України |
| publishDate |
2018 |
| topic_facet |
Technology |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/154445 |
| citation_txt |
Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) / N.M. Antraptseva, N.V. Solod, R.S. Zhyla // Functional Materials. — 2018. — Т. 25, № 1. — С. 151-157. — Бібліогр.: 14 назв. — англ. |
| series |
Functional Materials |
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AT antraptsevanm peculiaritiesofthermalsolidphasetransformationsofhydrogenphosphatescoiimnii AT solodnv peculiaritiesofthermalsolidphasetransformationsofhydrogenphosphatescoiimnii AT zhylars peculiaritiesofthermalsolidphasetransformationsofhydrogenphosphatescoiimnii |
| first_indexed |
2023-05-20T17:43:57Z |
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2023-05-20T17:43:57Z |
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1796153962297032704 |