The effect of stirring on the heterogeneous nucleation of water and of clathrates of tetrahydrofuran/water mixtures

The statistics of liquid-to-crystal nucleation are measured for both water and for clathrate-forming mixtures of tetrahydrofuran (THF) and water using an automatic lag time apparatus (ALTA). We measure the nucleation temperature using this apparatus in which a single sample is repeatedly cooled, nuc...

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Збережено в:
Бібліографічні деталі
Дата:2016
Автори: Wilson, P.W., Haymet, A.D.J.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики конденсованих систем НАН України 2016
Назва видання:Condensed Matter Physics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/155808
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:The effect of stirring on the heterogeneous nucleation of water and of clathrates of tetrahydrofuran/water mixtures / P.W. Wilson, A.D.J. Haymet // Condensed Matter Physics. — 2016. — Т. 19, № 2. — С. 23602: 1–4. — Бібліогр.: 3 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:The statistics of liquid-to-crystal nucleation are measured for both water and for clathrate-forming mixtures of tetrahydrofuran (THF) and water using an automatic lag time apparatus (ALTA). We measure the nucleation temperature using this apparatus in which a single sample is repeatedly cooled, nucleated and thawed. The effect of stirring on nucleation has been evaluated numerically and is discussed. We find that stirring of the solution makes no difference to the nucleation temperature of a given solution in a given tube.