Nonlinear dynamics of ferroelectrics with three-well local potential

For Sn₂P₂S₆ ferroelectrics, the appearance of spontaneous polarization is related to stereoactivity of tin cations and valence fluctuations of phosphorous cations. Here, the continuous phase transition and its behavior under pressure is determined by thee-well local potential and can be described...

Повний опис

Збережено в:
Бібліографічні деталі
Дата:2018
Автори: Yevych, R., Medulych, M., Vysochanskii, Yu.
Формат: Стаття
Мова:English
Опубліковано: Інститут фізики конденсованих систем НАН України 2018
Назва видання:Condensed Matter Physics
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/157049
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Nonlinear dynamics of ferroelectrics with three-well local potential / R. Yevych, M. Medulych, Yu. Vysochanskii // Condensed Matter Physics. — 2018. — Т. 21, № 2. — С. 23001: 1–8. — Бібліогр.: 25 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:For Sn₂P₂S₆ ferroelectrics, the appearance of spontaneous polarization is related to stereoactivity of tin cations and valence fluctuations of phosphorous cations. Here, the continuous phase transition and its behavior under pressure is determined by thee-well local potential and can be described in an anharmonic quantum oscillator model. For such a model, the spectrum of pseudospin fluctuations at different temperatures and pressures has been calculated and compared with the data of Raman spectroscopy. It was revealed that the ferroelectric lattice instability is related to several low energy optic modes.