Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity

Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity

Considered in the article is the basic possibility of increasing of electric conductivity of thermostable fluorine-containing aromatic polyamide by its doping with graphene platelets. The raised concentration of a conducting graphene phase (78 wt.%) in the top layer (~ 50 μm) of the film composite i...

Повний опис

Збережено в:
Бібліографічні деталі
Дата:2019
Автори: Kachkovsky, A.D., Pavlenko, E.L., Sheludko, E.V., Kulish, N.P., Dmitrenko, O.P., Sendyuk, V.A., Smertenko, P.S., Kremenitsky, V.V., Tarasyuk, O.P., Rogalsky, S.P.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2019
Назва видання:Functional Materials
Теми:
Characterization and properties
Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/157405
Теги: Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity / A.D. Kachkovsky, E.L. Pavlenko, E.V. Sheludko, N.P. Kulish, O.P. Dmitrenko, V.A. Sendyuk, P.S. Smertenko, V.V. Kremenitsky, O.P. Tarasyuk, S.P. Rogalsky // Functional Materials. — 2019. — Т. 26, № 1. — С. 100-106. — Бібліогр.: 19 назв. — англ.

Репозитарії

Digital Library of Periodicals of National Academy of Sciences of Ukraine
id irk-123456789-157405
record_format dspace
spelling irk-123456789-1574052019-06-21T01:25:32Z Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity Kachkovsky, A.D. Pavlenko, E.L. Sheludko, E.V. Kulish, N.P. Dmitrenko, O.P. Sendyuk, V.A. Smertenko, P.S. Kremenitsky, V.V. Tarasyuk, O.P. Rogalsky, S.P. Characterization and properties Considered in the article is the basic possibility of increasing of electric conductivity of thermostable fluorine-containing aromatic polyamide by its doping with graphene platelets. The raised concentration of a conducting graphene phase (78 wt.%) in the top layer (~ 50 μm) of the film composite is established. The microstructure of cross-section of the film and topography of its surface are studied by SEM and AFM. Corresponding volt-ampere characteristics are resulted. Carried out here are quantum-chemical calculations of model system &qout;a polyamide fragment + graphene strip&qout;: localization of boundary and close molecular orbitals in the composite and also distribution of spin density of the composite in electric field. Conductivity of the composite is explained within the framework of stacking interaction between π-systems of the polymer and graphene. 2019 Article Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity / A.D. Kachkovsky, E.L. Pavlenko, E.V. Sheludko, N.P. Kulish, O.P. Dmitrenko, V.A. Sendyuk, P.S. Smertenko, V.V. Kremenitsky, O.P. Tarasyuk, S.P. Rogalsky // Functional Materials. — 2019. — Т. 26, № 1. — С. 100-106. — Бібліогр.: 19 назв. — англ. 1027-5495 DOI:https://doi.org/10.15407/fm26.01.100 http://dspace.nbuv.gov.ua/handle/123456789/157405 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Characterization and properties
Characterization and properties
spellingShingle Characterization and properties
Characterization and properties
Kachkovsky, A.D.
Pavlenko, E.L.
Sheludko, E.V.
Kulish, N.P.
Dmitrenko, O.P.
Sendyuk, V.A.
Smertenko, P.S.
Kremenitsky, V.V.
Tarasyuk, O.P.
Rogalsky, S.P.
Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity
Functional Materials
description Considered in the article is the basic possibility of increasing of electric conductivity of thermostable fluorine-containing aromatic polyamide by its doping with graphene platelets. The raised concentration of a conducting graphene phase (78 wt.%) in the top layer (~ 50 μm) of the film composite is established. The microstructure of cross-section of the film and topography of its surface are studied by SEM and AFM. Corresponding volt-ampere characteristics are resulted. Carried out here are quantum-chemical calculations of model system &qout;a polyamide fragment + graphene strip&qout;: localization of boundary and close molecular orbitals in the composite and also distribution of spin density of the composite in electric field. Conductivity of the composite is explained within the framework of stacking interaction between π-systems of the polymer and graphene.
format Article
author Kachkovsky, A.D.
Pavlenko, E.L.
Sheludko, E.V.
Kulish, N.P.
Dmitrenko, O.P.
Sendyuk, V.A.
Smertenko, P.S.
Kremenitsky, V.V.
Tarasyuk, O.P.
Rogalsky, S.P.
author_facet Kachkovsky, A.D.
Pavlenko, E.L.
Sheludko, E.V.
Kulish, N.P.
Dmitrenko, O.P.
Sendyuk, V.A.
Smertenko, P.S.
Kremenitsky, V.V.
Tarasyuk, O.P.
Rogalsky, S.P.
author_sort Kachkovsky, A.D.
title Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity
title_short Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity
title_full Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity
title_fullStr Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity
title_full_unstemmed Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity
title_sort composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity
publisher НТК «Інститут монокристалів» НАН України
publishDate 2019
topic_facet Characterization and properties
url http://dspace.nbuv.gov.ua/handle/123456789/157405
citation_txt Composite "graphene nanoplatelets - fluorine-containing polyamide": synthesis, properties and quantum-chemical simulation of electroconductivity / A.D. Kachkovsky, E.L. Pavlenko, E.V. Sheludko, N.P. Kulish, O.P. Dmitrenko, V.A. Sendyuk, P.S. Smertenko, V.V. Kremenitsky, O.P. Tarasyuk, S.P. Rogalsky // Functional Materials. — 2019. — Т. 26, № 1. — С. 100-106. — Бібліогр.: 19 назв. — англ.
series Functional Materials
work_keys_str_mv AT kachkovskyad compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT pavlenkoel compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT sheludkoev compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT kulishnp compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT dmitrenkoop compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT sendyukva compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT smertenkops compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT kremenitskyvv compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT tarasyukop compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
AT rogalskysp compositegraphenenanoplateletsfluorinecontainingpolyamidesynthesispropertiesandquantumchemicalsimulationofelectroconductivity
first_indexed 2023-05-20T17:52:34Z
last_indexed 2023-05-20T17:52:34Z
_version_ 1796154295839621120

Схожі ресурси