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The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation

The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation

The optical properties, chemical and phase composition of ZnxCd₁-xS films obtained by close-spaced vacuum sublimation (CSS) were studied using X-ray diffraction, energy dispersive X-ray analysis and optical spectroscopy methods. The solid solution films were deposited at the substrate and evaporator...

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Main Authors: Yeromenko, Yu., Opanasyuk, A., Voznyi, A., Shpetnyi, I., Gnatenko, Yu., Grebinaha, V.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2019
Series:Functional Materials
Subjects:
Characterization and properties
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/157442
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spelling irk-123456789-1574422019-06-21T01:28:42Z The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation Yeromenko, Yu. Opanasyuk, A. Voznyi, A. Shpetnyi, I. Gnatenko, Yu. Grebinaha, V. Characterization and properties The optical properties, chemical and phase composition of ZnxCd₁-xS films obtained by close-spaced vacuum sublimation (CSS) were studied using X-ray diffraction, energy dispersive X-ray analysis and optical spectroscopy methods. The solid solution films were deposited at the substrate and evaporator temperatures of Ts = 573 K and Te = 1273 K, respectively. ZnS and CdS powders were mixed with different weight ratios (x = 0; 0.2; 0.4; 0.6; 0.8; 1.0) for further deposition of ZnxCd₁-xS films. It was found that the optical properties (band gap, transmission and absorption coefficients) of ZnxCd₁-xS films depends on the chemical composition and can be controlled by the weight percentages of the initial powders. It was found that the actual zinc concentrations in the films is higher than expected and the film thickness reduces with increasing of x. This results demonstrate that ZnxCd₁-xS solid solutions films obtained by CSS have improved optical parameters, high crystal quality and good stoichiometry. 2019 Article The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation / Yu. Yeromenko, A. Opanasyuk, A. Voznyi, I. Shpetnyi, Yu. Gnatenko, V. Grebinaha // Functional Materials. — 2019. — Т. 26, № 1. — С. 16-22. — Бібліогр.: 30 назв. — англ. 1027-5495 DOI:https://doi.org/10.15407/fm26.01.16 http://dspace.nbuv.gov.ua/handle/123456789/157442 en Functional Materials НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Characterization and properties
Characterization and properties
spellingShingle Characterization and properties
Characterization and properties
Yeromenko, Yu.
Opanasyuk, A.
Voznyi, A.
Shpetnyi, I.
Gnatenko, Yu.
Grebinaha, V.
The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation
Functional Materials
description The optical properties, chemical and phase composition of ZnxCd₁-xS films obtained by close-spaced vacuum sublimation (CSS) were studied using X-ray diffraction, energy dispersive X-ray analysis and optical spectroscopy methods. The solid solution films were deposited at the substrate and evaporator temperatures of Ts = 573 K and Te = 1273 K, respectively. ZnS and CdS powders were mixed with different weight ratios (x = 0; 0.2; 0.4; 0.6; 0.8; 1.0) for further deposition of ZnxCd₁-xS films. It was found that the optical properties (band gap, transmission and absorption coefficients) of ZnxCd₁-xS films depends on the chemical composition and can be controlled by the weight percentages of the initial powders. It was found that the actual zinc concentrations in the films is higher than expected and the film thickness reduces with increasing of x. This results demonstrate that ZnxCd₁-xS solid solutions films obtained by CSS have improved optical parameters, high crystal quality and good stoichiometry.
format Article
author Yeromenko, Yu.
Opanasyuk, A.
Voznyi, A.
Shpetnyi, I.
Gnatenko, Yu.
Grebinaha, V.
author_facet Yeromenko, Yu.
Opanasyuk, A.
Voznyi, A.
Shpetnyi, I.
Gnatenko, Yu.
Grebinaha, V.
author_sort Yeromenko, Yu.
title The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation
title_short The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation
title_full The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation
title_fullStr The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation
title_full_unstemmed The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation
title_sort chemical, phase composition and optical properties of znxcd₁-xs films obtained by close spaced vacuum sublimation
publisher НТК «Інститут монокристалів» НАН України
publishDate 2019
topic_facet Characterization and properties
url http://dspace.nbuv.gov.ua/handle/123456789/157442
citation_txt The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation / Yu. Yeromenko, A. Opanasyuk, A. Voznyi, I. Shpetnyi, Yu. Gnatenko, V. Grebinaha // Functional Materials. — 2019. — Т. 26, № 1. — С. 16-22. — Бібліогр.: 30 назв. — англ.
series Functional Materials
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first_indexed 2023-05-20T17:52:24Z
last_indexed 2023-05-20T17:52:24Z
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