Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals

• Дата: 1997
• Автори: Avdeenko, A.A., Buravtseva, L.M., Gorobchenko, V.S., Eremenko, V.V., Izvekov, S.V., Kravchenko, A.E., Pyshkin, O.S., Sugakov, V.I.
• Формат: Стаття
• Мова: English
• Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 1997
• Назва видання: Физика низких температур
• Онлайн доступ: http://dspace.nbuv.gov.ua/handle/123456789/175038
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Цитувати: Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals / A.А. Avdeenko, L.М. Buravtseva, V.S. Gorobchenko, V.V. Eremenko, S.V. lzvekov, А.Е. Кravchenko, О.S. Pyshkin, and V.І. Sugakov // Физика низких температур. — 1997. — Т. 23, № 3. — С. 334-337. — Бібліогр.: 20 назв. — англ.

The excited triplet states of shallow X-traps in neat single crystals of 4,4-dichlorobenzophenone were studied at liquid helium temperature by luminescence spectroscopy and magnetic resonance with optical detection. The vibrational phosphorescence bands, the polarization of phosphorescence spectra, and the triplet zero-field splitting parameters of these traps have been analyzed. A specific model of the structure defect (a molecule is turned by 180° on its long axis) has been considered in organic crystals of benzophenone type which consist of molecules whose dipole moments compensate each other in a unit cell. The calculated depth of such a dipole X-trap for triplet excitons in 4,4-dichlorobenzophenone crystals at the account of a defect molecule relaxation upon its slewing was found to be comparable with the experimental one.