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Magnetic phenomena in Co-containing layered double hydroxides

Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments...

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Main Authors:	Vieira, D.E.L., Salak, A.N., Fedorchenko, A.V., Pashkevich, Y.G., Fertman, E.L., Desnenko, V.A., Babkin, R.Y., Čižmár, E., Feher, A., Lopes, A.B., Ferreira, M.G.S.
Format:	Article
Language:	English
Published:	Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2017
Series:	Физика низких температур
Subjects:	Low dimensionality and inhomogeneity effects in quantum matter
Online Access:	http://dspace.nbuv.gov.ua/handle/123456789/175128
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spelling	irk-123456789-1751282021-02-01T01:27:17Z Magnetic phenomena in Co-containing layered double hydroxides Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S. Low dimensionality and inhomogeneity effects in quantum matter Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments reach the maximum values at Tmax of 4.0 K and 3.2 K for Co(2)Al–NO₃ and Co(3)Al–NO₃, respectively. Below Tmax, the zero-field-cooled and the field-cooled static magnetization curves are strongly different. Along with this low-temperature phenomena, Co(2)Al–NO₃ and Co(3)Al–NO₃ demonstrate anomalous behavior of their temperature dependence magnetic susceptibility in a higher-temperature range: between 75 and 175 K, both the paramagnetic Curie temperature and the effective magnetic moment change in a non-monotonous way. Possible structural reasons of the observed magnetic behavior of the CoII(n)AlIII LDHs are discussed. 2017 Article Magnetic phenomena in Co-containing layered double hydroxides / D.E.L. Vieira, A.N. Salak, A.V. Fedorchenko, Y.G. Pashkevich, E.L. Fertman, V.A. Desnenko, R.Y. Babkin, E. Čižmár, A. Feher, A.B. Lopes, M.G.S. Ferreira // Физика низких температур. — 2017. — Т. 43, № 8. — С. 1214-1218. — Бібліогр.: 17 назв. — англ. 0132-6414 PACS: 61.43.Gt, 75.50.Lk, 75.70.Cn http://dspace.nbuv.gov.ua/handle/123456789/175128 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution	Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection	DSpace DC
language	English
topic	Low dimensionality and inhomogeneity effects in quantum matter Low dimensionality and inhomogeneity effects in quantum matter
spellingShingle	Low dimensionality and inhomogeneity effects in quantum matter Low dimensionality and inhomogeneity effects in quantum matter Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S. Magnetic phenomena in Co-containing layered double hydroxides Физика низких температур
description	Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments reach the maximum values at Tmax of 4.0 K and 3.2 K for Co(2)Al–NO₃ and Co(3)Al–NO₃, respectively. Below Tmax, the zero-field-cooled and the field-cooled static magnetization curves are strongly different. Along with this low-temperature phenomena, Co(2)Al–NO₃ and Co(3)Al–NO₃ demonstrate anomalous behavior of their temperature dependence magnetic susceptibility in a higher-temperature range: between 75 and 175 K, both the paramagnetic Curie temperature and the effective magnetic moment change in a non-monotonous way. Possible structural reasons of the observed magnetic behavior of the CoII(n)AlIII LDHs are discussed.
format	Article
author	Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S.
author_facet	Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S.
author_sort	Vieira, D.E.L.
title	Magnetic phenomena in Co-containing layered double hydroxides
title_short	Magnetic phenomena in Co-containing layered double hydroxides
title_full	Magnetic phenomena in Co-containing layered double hydroxides
title_fullStr	Magnetic phenomena in Co-containing layered double hydroxides
title_full_unstemmed	Magnetic phenomena in Co-containing layered double hydroxides
title_sort	magnetic phenomena in co-containing layered double hydroxides
publisher	Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate	2017
topic_facet	Low dimensionality and inhomogeneity effects in quantum matter
url	http://dspace.nbuv.gov.ua/handle/123456789/175128
citation_txt	Magnetic phenomena in Co-containing layered double hydroxides / D.E.L. Vieira, A.N. Salak, A.V. Fedorchenko, Y.G. Pashkevich, E.L. Fertman, V.A. Desnenko, R.Y. Babkin, E. Čižmár, A. Feher, A.B. Lopes, M.G.S. Ferreira // Физика низких температур. — 2017. — Т. 43, № 8. — С. 1214-1218. — Бібліогр.: 17 назв. — англ.
series	Физика низких температур
work_keys_str_mv	AT vieiradel magneticphenomenaincocontaininglayereddoublehydroxides AT salakan magneticphenomenaincocontaininglayereddoublehydroxides AT fedorchenkoav magneticphenomenaincocontaininglayereddoublehydroxides AT pashkevichyg magneticphenomenaincocontaininglayereddoublehydroxides AT fertmanel magneticphenomenaincocontaininglayereddoublehydroxides AT desnenkova magneticphenomenaincocontaininglayereddoublehydroxides AT babkinry magneticphenomenaincocontaininglayereddoublehydroxides AT cizmare magneticphenomenaincocontaininglayereddoublehydroxides AT fehera magneticphenomenaincocontaininglayereddoublehydroxides AT lopesab magneticphenomenaincocontaininglayereddoublehydroxides AT ferreiramgs magneticphenomenaincocontaininglayereddoublehydroxides
first_indexed	2023-10-18T22:38:06Z
last_indexed	2023-10-18T22:38:06Z
_version_	1796156032605487104

Magnetic phenomena in Co-containing layered double hydroxides

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