Magnetic phenomena in Co-containing layered double hydroxides

Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments...

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Дата:2017
Автори: Vieira, D.E.L., Salak, A.N., Fedorchenko, A.V., Pashkevich, Y.G., Fertman, E.L., Desnenko, V.A., Babkin, R.Y., Čižmár, E., Feher, A., Lopes, A.B., Ferreira, M.G.S.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2017
Назва видання:Физика низких температур
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/175128
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Magnetic phenomena in Co-containing layered double hydroxides / D.E.L. Vieira, A.N. Salak, A.V. Fedorchenko, Y.G. Pashkevich, E.L. Fertman, V.A. Desnenko, R.Y. Babkin, E. Čižmár, A. Feher, A.B. Lopes, M.G.S. Ferreira // Физика низких температур. — 2017. — Т. 43, № 8. — С. 1214-1218. — Бібліогр.: 17 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id irk-123456789-175128
record_format dspace
spelling irk-123456789-1751282021-02-01T01:27:17Z Magnetic phenomena in Co-containing layered double hydroxides Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S. Low dimensionality and inhomogeneity effects in quantum matter Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments reach the maximum values at Tmax of 4.0 K and 3.2 K for Co(2)Al–NO₃ and Co(3)Al–NO₃, respectively. Below Tmax, the zero-field-cooled and the field-cooled static magnetization curves are strongly different. Along with this low-temperature phenomena, Co(2)Al–NO₃ and Co(3)Al–NO₃ demonstrate anomalous behavior of their temperature dependence magnetic susceptibility in a higher-temperature range: between 75 and 175 K, both the paramagnetic Curie temperature and the effective magnetic moment change in a non-monotonous way. Possible structural reasons of the observed magnetic behavior of the CoII(n)AlIII LDHs are discussed. 2017 Article Magnetic phenomena in Co-containing layered double hydroxides / D.E.L. Vieira, A.N. Salak, A.V. Fedorchenko, Y.G. Pashkevich, E.L. Fertman, V.A. Desnenko, R.Y. Babkin, E. Čižmár, A. Feher, A.B. Lopes, M.G.S. Ferreira // Физика низких температур. — 2017. — Т. 43, № 8. — С. 1214-1218. — Бібліогр.: 17 назв. — англ. 0132-6414 PACS: 61.43.Gt, 75.50.Lk, 75.70.Cn http://dspace.nbuv.gov.ua/handle/123456789/175128 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Low dimensionality and inhomogeneity effects in quantum matter
Low dimensionality and inhomogeneity effects in quantum matter
spellingShingle Low dimensionality and inhomogeneity effects in quantum matter
Low dimensionality and inhomogeneity effects in quantum matter
Vieira, D.E.L.
Salak, A.N.
Fedorchenko, A.V.
Pashkevich, Y.G.
Fertman, E.L.
Desnenko, V.A.
Babkin, R.Y.
Čižmár, E.
Feher, A.
Lopes, A.B.
Ferreira, M.G.S.
Magnetic phenomena in Co-containing layered double hydroxides
Физика низких температур
description Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments reach the maximum values at Tmax of 4.0 K and 3.2 K for Co(2)Al–NO₃ and Co(3)Al–NO₃, respectively. Below Tmax, the zero-field-cooled and the field-cooled static magnetization curves are strongly different. Along with this low-temperature phenomena, Co(2)Al–NO₃ and Co(3)Al–NO₃ demonstrate anomalous behavior of their temperature dependence magnetic susceptibility in a higher-temperature range: between 75 and 175 K, both the paramagnetic Curie temperature and the effective magnetic moment change in a non-monotonous way. Possible structural reasons of the observed magnetic behavior of the CoII(n)AlIII LDHs are discussed.
format Article
author Vieira, D.E.L.
Salak, A.N.
Fedorchenko, A.V.
Pashkevich, Y.G.
Fertman, E.L.
Desnenko, V.A.
Babkin, R.Y.
Čižmár, E.
Feher, A.
Lopes, A.B.
Ferreira, M.G.S.
author_facet Vieira, D.E.L.
Salak, A.N.
Fedorchenko, A.V.
Pashkevich, Y.G.
Fertman, E.L.
Desnenko, V.A.
Babkin, R.Y.
Čižmár, E.
Feher, A.
Lopes, A.B.
Ferreira, M.G.S.
author_sort Vieira, D.E.L.
title Magnetic phenomena in Co-containing layered double hydroxides
title_short Magnetic phenomena in Co-containing layered double hydroxides
title_full Magnetic phenomena in Co-containing layered double hydroxides
title_fullStr Magnetic phenomena in Co-containing layered double hydroxides
title_full_unstemmed Magnetic phenomena in Co-containing layered double hydroxides
title_sort magnetic phenomena in co-containing layered double hydroxides
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
publishDate 2017
topic_facet Low dimensionality and inhomogeneity effects in quantum matter
url http://dspace.nbuv.gov.ua/handle/123456789/175128
citation_txt Magnetic phenomena in Co-containing layered double hydroxides / D.E.L. Vieira, A.N. Salak, A.V. Fedorchenko, Y.G. Pashkevich, E.L. Fertman, V.A. Desnenko, R.Y. Babkin, E. Čižmár, A. Feher, A.B. Lopes, M.G.S. Ferreira // Физика низких температур. — 2017. — Т. 43, № 8. — С. 1214-1218. — Бібліогр.: 17 назв. — англ.
series Физика низких температур
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