Magnetic phenomena in Co-containing layered double hydroxides
Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments...
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Дата: | 2017 |
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Автори: | , , , , , , , , , , |
Формат: | Стаття |
Мова: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2017
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Назва видання: | Физика низких температур |
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Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/175128 |
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Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
Цитувати: | Magnetic phenomena in Co-containing layered double hydroxides / D.E.L. Vieira, A.N. Salak, A.V. Fedorchenko, Y.G. Pashkevich, E.L. Fertman, V.A. Desnenko, R.Y. Babkin, E. Čižmár, A. Feher, A.B. Lopes, M.G.S. Ferreira // Физика низких температур. — 2017. — Т. 43, № 8. — С. 1214-1218. — Бібліогр.: 17 назв. — англ. |
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irk-123456789-1751282021-02-01T01:27:17Z Magnetic phenomena in Co-containing layered double hydroxides Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S. Low dimensionality and inhomogeneity effects in quantum matter Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments reach the maximum values at Tmax of 4.0 K and 3.2 K for Co(2)Al–NO₃ and Co(3)Al–NO₃, respectively. Below Tmax, the zero-field-cooled and the field-cooled static magnetization curves are strongly different. Along with this low-temperature phenomena, Co(2)Al–NO₃ and Co(3)Al–NO₃ demonstrate anomalous behavior of their temperature dependence magnetic susceptibility in a higher-temperature range: between 75 and 175 K, both the paramagnetic Curie temperature and the effective magnetic moment change in a non-monotonous way. Possible structural reasons of the observed magnetic behavior of the CoII(n)AlIII LDHs are discussed. 2017 Article Magnetic phenomena in Co-containing layered double hydroxides / D.E.L. Vieira, A.N. Salak, A.V. Fedorchenko, Y.G. Pashkevich, E.L. Fertman, V.A. Desnenko, R.Y. Babkin, E. Čižmár, A. Feher, A.B. Lopes, M.G.S. Ferreira // Физика низких температур. — 2017. — Т. 43, № 8. — С. 1214-1218. — Бібліогр.: 17 назв. — англ. 0132-6414 PACS: 61.43.Gt, 75.50.Lk, 75.70.Cn http://dspace.nbuv.gov.ua/handle/123456789/175128 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine |
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English |
topic |
Low dimensionality and inhomogeneity effects in quantum matter Low dimensionality and inhomogeneity effects in quantum matter |
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Low dimensionality and inhomogeneity effects in quantum matter Low dimensionality and inhomogeneity effects in quantum matter Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S. Magnetic phenomena in Co-containing layered double hydroxides Физика низких температур |
description |
Magnetic behavior of CoII(n)AlIII layered double hydroxides (LDHs) (n = Co/Al = 2 and 3) intercalated with nitrate was studied as a function of temperature. Both LDH compounds are paramagnetic above about 8 K. A rapid increase of their magnetic moments occurs below this temperature until the moments reach the maximum values at Tmax of 4.0 K and 3.2 K for Co(2)Al–NO₃ and Co(3)Al–NO₃, respectively. Below Tmax, the zero-field-cooled and the field-cooled static magnetization curves are strongly different. Along with this low-temperature phenomena, Co(2)Al–NO₃ and Co(3)Al–NO₃ demonstrate anomalous behavior of their temperature dependence magnetic susceptibility in a higher-temperature range: between 75 and 175 K, both the paramagnetic Curie temperature and the effective magnetic moment change in a non-monotonous way. Possible structural reasons of the observed magnetic behavior of the CoII(n)AlIII LDHs are discussed. |
format |
Article |
author |
Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S. |
author_facet |
Vieira, D.E.L. Salak, A.N. Fedorchenko, A.V. Pashkevich, Y.G. Fertman, E.L. Desnenko, V.A. Babkin, R.Y. Čižmár, E. Feher, A. Lopes, A.B. Ferreira, M.G.S. |
author_sort |
Vieira, D.E.L. |
title |
Magnetic phenomena in Co-containing layered double hydroxides |
title_short |
Magnetic phenomena in Co-containing layered double hydroxides |
title_full |
Magnetic phenomena in Co-containing layered double hydroxides |
title_fullStr |
Magnetic phenomena in Co-containing layered double hydroxides |
title_full_unstemmed |
Magnetic phenomena in Co-containing layered double hydroxides |
title_sort |
magnetic phenomena in co-containing layered double hydroxides |
publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
publishDate |
2017 |
topic_facet |
Low dimensionality and inhomogeneity effects in quantum matter |
url |
http://dspace.nbuv.gov.ua/handle/123456789/175128 |
citation_txt |
Magnetic phenomena in Co-containing layered double hydroxides / D.E.L. Vieira, A.N. Salak, A.V. Fedorchenko, Y.G. Pashkevich, E.L. Fertman, V.A. Desnenko, R.Y. Babkin, E. Čižmár, A. Feher, A.B. Lopes, M.G.S. Ferreira // Физика низких температур. — 2017. — Т. 43, № 8. — С. 1214-1218. — Бібліогр.: 17 назв. — англ. |
series |
Физика низких температур |
work_keys_str_mv |
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first_indexed |
2023-10-18T22:38:06Z |
last_indexed |
2023-10-18T22:38:06Z |
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1796156032605487104 |