X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄
Thermochromic phase transition was studied in CuMoO₄ using the Cu and Mo K-edge x-ray absorption spectroscopy in the temperature range of 10–300 K. The hysteretic behavior has been evidenced from the temperature dependence of the pre-edge shoulder intensity at the Mo K-edge, indicating that the tran...
Збережено в:
| Дата: | 2018 |
|---|---|
| Автори: | , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2018
|
| Назва видання: | Физика низких температур |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/176119 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ / I. Jonane, A. Cintins, A. Kalinko, R. Chernikov, A. Kuzmin // Физика низких температур. — 2018. — Т. 44, № 5. — С. 568-572. — Бібліогр.: 39 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-176119 |
|---|---|
| record_format |
dspace |
| spelling |
irk-123456789-1761192021-02-04T01:28:58Z X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ Jonane, I. Cintins, A. Kalinko, A. Chernikov, R. Kuzmin, A. Динамика кристаллической решетки Thermochromic phase transition was studied in CuMoO₄ using the Cu and Mo K-edge x-ray absorption spectroscopy in the temperature range of 10–300 K. The hysteretic behavior has been evidenced from the temperature dependence of the pre-edge shoulder intensity at the Mo K-edge, indicating that the transition from brownish-red γ-CuMoO₄ to green α-CuMoO₄ occurs in the temperature range of 230–280 K upon heating, whereas the α-to-γ transition occurs between 200 and 120 K upon cooling. Such behavior of the pre-edge shoulder at the Mo K-edge correlates with the change of molybdenum coordination between distorted tetrahedral in α-CuMoO₄ and distorted octahedral in γ-CuMoO₄. This result has been supported by ab initio full-multiple-scattering x-ray absorption near edge structure (XANES) calculations. 2018 Article X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ / I. Jonane, A. Cintins, A. Kalinko, R. Chernikov, A. Kuzmin // Физика низких температур. — 2018. — Т. 44, № 5. — С. 568-572. — Бібліогр.: 39 назв. — англ. 0132-6414 PACS: 61.05.cj, 64.70.kp http://dspace.nbuv.gov.ua/handle/123456789/176119 en Физика низких температур Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Динамика кристаллической решетки Динамика кристаллической решетки |
| spellingShingle |
Динамика кристаллической решетки Динамика кристаллической решетки Jonane, I. Cintins, A. Kalinko, A. Chernikov, R. Kuzmin, A. X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ Физика низких температур |
| description |
Thermochromic phase transition was studied in CuMoO₄ using the Cu and Mo K-edge x-ray absorption spectroscopy in the temperature range of 10–300 K. The hysteretic behavior has been evidenced from the temperature dependence of the pre-edge shoulder intensity at the Mo K-edge, indicating that the transition from brownish-red γ-CuMoO₄ to green α-CuMoO₄ occurs in the temperature range of 230–280 K upon heating, whereas the α-to-γ transition occurs between 200 and 120 K upon cooling. Such behavior of the pre-edge shoulder at the Mo K-edge correlates with the change of molybdenum coordination between distorted tetrahedral in α-CuMoO₄ and distorted octahedral in γ-CuMoO₄. This result has been supported by ab initio full-multiple-scattering x-ray absorption near edge structure (XANES) calculations. |
| format |
Article |
| author |
Jonane, I. Cintins, A. Kalinko, A. Chernikov, R. Kuzmin, A. |
| author_facet |
Jonane, I. Cintins, A. Kalinko, A. Chernikov, R. Kuzmin, A. |
| author_sort |
Jonane, I. |
| title |
X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ |
| title_short |
X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ |
| title_full |
X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ |
| title_fullStr |
X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ |
| title_full_unstemmed |
X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ |
| title_sort |
x-ray absorption near edge spectroscopy of thermochromic phase transition in cumoo₄ |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2018 |
| topic_facet |
Динамика кристаллической решетки |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/176119 |
| citation_txt |
X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO₄ / I. Jonane, A. Cintins, A. Kalinko, R. Chernikov, A. Kuzmin // Физика низких температур. — 2018. — Т. 44, № 5. — С. 568-572. — Бібліогр.: 39 назв. — англ. |
| series |
Физика низких температур |
| work_keys_str_mv |
AT jonanei xrayabsorptionnearedgespectroscopyofthermochromicphasetransitionincumoo4 AT cintinsa xrayabsorptionnearedgespectroscopyofthermochromicphasetransitionincumoo4 AT kalinkoa xrayabsorptionnearedgespectroscopyofthermochromicphasetransitionincumoo4 AT chernikovr xrayabsorptionnearedgespectroscopyofthermochromicphasetransitionincumoo4 AT kuzmina xrayabsorptionnearedgespectroscopyofthermochromicphasetransitionincumoo4 |
| first_indexed |
2023-10-18T22:40:32Z |
| last_indexed |
2023-10-18T22:40:32Z |
| _version_ |
1796156139414487040 |