Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes.
A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of co...
Збережено в:
| Дата: | 2005 |
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| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України
2005
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| Назва видання: | Украинский химический журнал |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/184079 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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irk-123456789-1840792022-05-05T01:26:52Z Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. Неорганическая и физическая химия A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of controlling the rate of the mass transfer process in electrochemical systems with a number of components of ≥ 3, the outer Helmholtz plane potential may take on two values at the same electrode potential value. The question of the appearance of anodic dissolution limiting currents has been studied for electrolytes containing four sorts of ions with arbitrary charges and diffusion coefficients. The existence and magnitude of limiting current are also dependent on the charge of the complex formed. 2005 Article Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. 0041–6045 http://dspace.nbuv.gov.ua/handle/123456789/184079 en Украинский химический журнал Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Неорганическая и физическая химия Неорганическая и физическая химия |
| spellingShingle |
Неорганическая и физическая химия Неорганическая и физическая химия Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. Украинский химический журнал |
| description |
A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of controlling the rate of the mass transfer process in electrochemical systems with a number of components of ≥ 3, the outer Helmholtz plane potential may take on two values at the same electrode potential value. The question of the appearance of anodic dissolution limiting currents has been studied for electrolytes containing four sorts of ions with arbitrary charges and diffusion coefficients. The existence and magnitude of limiting current are also dependent on the charge of the complex formed. |
| format |
Article |
| author |
Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. |
| author_facet |
Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. |
| author_sort |
Pototskaya, V.V. |
| title |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_short |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_full |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_fullStr |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_full_unstemmed |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_sort |
nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| publisher |
Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України |
| publishDate |
2005 |
| topic_facet |
Неорганическая и физическая химия |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/184079 |
| citation_txt |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. |
| series |
Украинский химический журнал |
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2023-10-18T22:58:20Z |
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