Structure, spectroscopic and thermal characterization of bis(acetylacetonato) dichlorotin (IV) synthesized in aqueous solution

Bis(acetylacetonato)dichlorotin(IV) is synthesized from the aqueous solutions of tin(IV) chloride and acetylacetone followed by vacuum drying at room temperature. DTA/TGA, FTIR, UV-VIS, X-ray powder and single crystal, mass spectra and elemental analysis are performed to characterize the product. X-...

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Збережено в:
Бібліографічні деталі
Дата:2010
Автори: Ulug, B., Turkdemir, H.M., Ulug, A., Buyukgungor, O., Yucel, M.B., Smyntyna, V.A., Grinevich, V.S., Filevskaya, L.N.
Формат: Стаття
Мова:English
Опубліковано: Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України 2010
Назва видання:Украинский химический журнал
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/186054
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Structure, spectroscopic and thermal characterization of bis(acetylacetonato) dichlorotin (IV) synthesized in aqueous solution / B. Ulug, H.M. Turkdemir, A. Ulug, O. Buyukgungor, M.B. Yucel, V.A. Smyntyna, V.S. Grinevich, L.N. Filevskaya // Украинский химический журнал. — 2010. — Т. 76, № 7. — С. 12-17. — Бібліогр.: 36 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Резюме:Bis(acetylacetonato)dichlorotin(IV) is synthesized from the aqueous solutions of tin(IV) chloride and acetylacetone followed by vacuum drying at room temperature. DTA/TGA, FTIR, UV-VIS, X-ray powder and single crystal, mass spectra and elemental analysis are performed to characterize the product. X-ray powder diffraction suggests that the sample may contain some impurities such as SnO, SnO₂ and Sn₂О₃ while the mass spectra indicates the existence of Sn(acac)₄, which is arguable due to the steric effect. Single crystal investigation reveals that the product synthesized in aqueous solution is Sn(acac)₂Cl₂, crystallized in monoclinic system in space group C2/c with unit cell constants a=13.983(2), b=7.8928(8), c=13.7889(19) Å and β =107.601(11)°, whose volume is 1.43 % smaller than the one synthesized in dry toluene.