Structure, spectroscopic and thermal characterization of bis(acetylacetonato) dichlorotin (IV) synthesized in aqueous solution
Bis(acetylacetonato)dichlorotin(IV) is synthesized from the aqueous solutions of tin(IV) chloride and acetylacetone followed by vacuum drying at room temperature. DTA/TGA, FTIR, UV-VIS, X-ray powder and single crystal, mass spectra and elemental analysis are performed to characterize the product. X-...
Збережено в:
Дата: | 2010 |
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Автори: | , , , , , , , |
Формат: | Стаття |
Мова: | English |
Опубліковано: |
Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України
2010
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Назва видання: | Украинский химический журнал |
Теми: | |
Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/186054 |
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Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
Цитувати: | Structure, spectroscopic and thermal characterization of bis(acetylacetonato) dichlorotin (IV) synthesized in aqueous solution / B. Ulug, H.M. Turkdemir, A. Ulug, O. Buyukgungor, M.B. Yucel, V.A. Smyntyna, V.S. Grinevich, L.N. Filevskaya // Украинский химический журнал. — 2010. — Т. 76, № 7. — С. 12-17. — Бібліогр.: 36 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of UkraineРезюме: | Bis(acetylacetonato)dichlorotin(IV) is synthesized from the aqueous solutions of tin(IV) chloride and acetylacetone followed by vacuum drying at room temperature. DTA/TGA, FTIR, UV-VIS, X-ray powder and single crystal, mass spectra and elemental analysis are performed to characterize the product. X-ray powder diffraction suggests that the sample may contain some impurities such as SnO, SnO₂ and Sn₂О₃ while the mass spectra indicates the existence of Sn(acac)₄, which is arguable due to the steric effect. Single crystal investigation reveals that the product synthesized in aqueous solution is Sn(acac)₂Cl₂, crystallized in monoclinic system in space group C2/c with unit cell constants a=13.983(2), b=7.8928(8), c=13.7889(19) Å and β =107.601(11)°, whose volume is 1.43 % smaller than the one synthesized in dry toluene. |
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