2025-02-23T18:47:07-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: Query fl=%2A&wt=json&json.nl=arrarr&q=id%3A%22irk-123456789-186229%22&qt=morelikethis&rows=5
2025-02-23T18:47:07-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: => GET http://localhost:8983/solr/biblio/select?fl=%2A&wt=json&json.nl=arrarr&q=id%3A%22irk-123456789-186229%22&qt=morelikethis&rows=5
2025-02-23T18:47:07-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: <= 200 OK
2025-02-23T18:47:07-05:00 DEBUG: Deserialized SOLR response

Peroxyhydrocarbonate and peroxocarbonate ions as typical α-nucleophiles in phosphonyl transfer

In a search for novel, high-reactivity, α-nucleophiles we examined the kinetics of decomposition of 4-nitrophenyldiethyl phosphonate (NPDEPN) by Н₂О₂/NH₄HCO₃/HО⁻ at рН 7.7—10.4. This system generates HCO₄⁻ and CO₄²⁻, and their equilibrium concentrations were calculated with the corresponding equilib...

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Bibliographic Details
Main Authors: Prokop’eva, T.M., Sadovskii, Yu.S., Savyolova, V.A., Solomoichenko, T.N., Piskunova, Zh.P., Bunton, C.A., Popov, A.F.
Format: Article
Language:English
Published: Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України 2011
Series:Украинский химический журнал
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Online Access:http://dspace.nbuv.gov.ua/handle/123456789/186229
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2025-02-23T18:47:07-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: Query fl=%2A&rows=40&rows=5&wt=json&json.nl=arrarr&q=id%3A%22irk-123456789-186229%22&qt=morelikethis
2025-02-23T18:47:07-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: => GET http://localhost:8983/solr/biblio/select?fl=%2A&rows=40&rows=5&wt=json&json.nl=arrarr&q=id%3A%22irk-123456789-186229%22&qt=morelikethis
2025-02-23T18:47:07-05:00 DEBUG: VuFindSearch\Backend\Solr\Connector: <= 200 OK
2025-02-23T18:47:07-05:00 DEBUG: Deserialized SOLR response