Erosion behavior of nickel diffusion membranes in conditions of water electrolysis

Preliminary studies of the erosion resistance of Ni diffusion membranes under the conditions of water electrolysis in various modes were carried out. Particular attention was paid to the time dependencies of the current, voltage and the electrolyte temperature during the process. Both electrodes, an...

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Дата:2022
Автори: Glazunov, G.P., Bodnar, A.S., Konotopskiy, A.L., Vinogradov, D.M., Maznichenko, S.M., Garkusha, I.E.
Формат: Стаття
Мова:English
Опубліковано: Національний науковий центр «Харківський фізико-технічний інститут» НАН України 2022
Назва видання:Problems of Atomic Science and Technology
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Онлайн доступ:http://dspace.nbuv.gov.ua/handle/123456789/195898
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Erosion behaviour of nickel diffusion membranes in conditions of water electrolysis / G.P. Glazunov, A.S. Bodnar, A.L. Konotopskiy, D.M. Vinogradov, S.M. Maznichenko, I.E. Garkusha // Problems of Atomic Science and Technology. — 2022. — № 6. — С. 111-113. — Бібліогр.: 8 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling irk-123456789-1958982023-12-08T12:58:31Z Erosion behavior of nickel diffusion membranes in conditions of water electrolysis Glazunov, G.P. Bodnar, A.S. Konotopskiy, A.L. Vinogradov, D.M. Maznichenko, S.M. Garkusha, I.E. Low temperature plasma and plasma technologies Preliminary studies of the erosion resistance of Ni diffusion membranes under the conditions of water electrolysis in various modes were carried out. Particular attention was paid to the time dependencies of the current, voltage and the electrolyte temperature during the process. Both electrodes, anode and cathode, were in the form of tubes of Ni-99.5% wt. The electrolyte was pure drinking water after the filter with mineralization (ppm) 14, as well as water with the addition of sodium bicarbonate (mineralization 140...160 ppm). It is demonstrated that after several hours of operation cathodes showed no signs of erosion or other damages. The degree of erosion was assessed by weighing, and the state (morphology) of the surface was visually examined using an optical microscope. As for the anode, even when electrolyzing sufficiently pure water (ppm = 14), there is noticeable erosion and surface damage. To elucidate the reasons for such behavior of Ni electrodes, further studies are planned, in particular, using some other materials as an anode. Проведено попередні дослідження ерозійної стійкості дифузійних мембран з Ni в умовах електролізу води в різних режимах. Особливу увагу було приділено вимірюванню залежності струму та напруги на електродах, температури електроліту від часу процесу. Обидва електроди, анод та катод, були виконані у вигляді трубок з Ni-99,5 ваг.%. Як електроліт використовували чисту воду після фільтра з мінералізацією 14 проміле, а також воду з додаванням соди (мінералізація 140...160 проміле). Показано, що катоди після декількох годин роботи не виявили жодних ознак ерозії чи інших ушкоджень. Ступінь ерозії оцінювали шляхом зважування, а стан (морфологію) поверхні візуально за допомогою оптичного мікроскопа. Що стосується анода, навіть при електролізі достатньо чистої води (14 проміле), спостерігається суттєва ерозія та пошкодження поверхні. Для з’ясування причин такої поведінки планується провести подальші дослідження, зокрема, використовуючи інші матеріали в якості аноду. 2022 Article Erosion behaviour of nickel diffusion membranes in conditions of water electrolysis / G.P. Glazunov, A.S. Bodnar, A.L. Konotopskiy, D.M. Vinogradov, S.M. Maznichenko, I.E. Garkusha // Problems of Atomic Science and Technology. — 2022. — № 6. — С. 111-113. — Бібліогр.: 8 назв. — англ. 1562-6016 PACS: 52.40.Hf DOI: https://doi.org/10.46813/2022-142-111 http://dspace.nbuv.gov.ua/handle/123456789/195898 en Problems of Atomic Science and Technology Національний науковий центр «Харківський фізико-технічний інститут» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Low temperature plasma and plasma technologies
Low temperature plasma and plasma technologies
spellingShingle Low temperature plasma and plasma technologies
Low temperature plasma and plasma technologies
Glazunov, G.P.
Bodnar, A.S.
Konotopskiy, A.L.
Vinogradov, D.M.
Maznichenko, S.M.
Garkusha, I.E.
Erosion behavior of nickel diffusion membranes in conditions of water electrolysis
Problems of Atomic Science and Technology
description Preliminary studies of the erosion resistance of Ni diffusion membranes under the conditions of water electrolysis in various modes were carried out. Particular attention was paid to the time dependencies of the current, voltage and the electrolyte temperature during the process. Both electrodes, anode and cathode, were in the form of tubes of Ni-99.5% wt. The electrolyte was pure drinking water after the filter with mineralization (ppm) 14, as well as water with the addition of sodium bicarbonate (mineralization 140...160 ppm). It is demonstrated that after several hours of operation cathodes showed no signs of erosion or other damages. The degree of erosion was assessed by weighing, and the state (morphology) of the surface was visually examined using an optical microscope. As for the anode, even when electrolyzing sufficiently pure water (ppm = 14), there is noticeable erosion and surface damage. To elucidate the reasons for such behavior of Ni electrodes, further studies are planned, in particular, using some other materials as an anode.
format Article
author Glazunov, G.P.
Bodnar, A.S.
Konotopskiy, A.L.
Vinogradov, D.M.
Maznichenko, S.M.
Garkusha, I.E.
author_facet Glazunov, G.P.
Bodnar, A.S.
Konotopskiy, A.L.
Vinogradov, D.M.
Maznichenko, S.M.
Garkusha, I.E.
author_sort Glazunov, G.P.
title Erosion behavior of nickel diffusion membranes in conditions of water electrolysis
title_short Erosion behavior of nickel diffusion membranes in conditions of water electrolysis
title_full Erosion behavior of nickel diffusion membranes in conditions of water electrolysis
title_fullStr Erosion behavior of nickel diffusion membranes in conditions of water electrolysis
title_full_unstemmed Erosion behavior of nickel diffusion membranes in conditions of water electrolysis
title_sort erosion behavior of nickel diffusion membranes in conditions of water electrolysis
publisher Національний науковий центр «Харківський фізико-технічний інститут» НАН України
publishDate 2022
topic_facet Low temperature plasma and plasma technologies
url http://dspace.nbuv.gov.ua/handle/123456789/195898
citation_txt Erosion behaviour of nickel diffusion membranes in conditions of water electrolysis / G.P. Glazunov, A.S. Bodnar, A.L. Konotopskiy, D.M. Vinogradov, S.M. Maznichenko, I.E. Garkusha // Problems of Atomic Science and Technology. — 2022. — № 6. — С. 111-113. — Бібліогр.: 8 назв. — англ.
series Problems of Atomic Science and Technology
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AT vinogradovdm erosionbehaviorofnickeldiffusionmembranesinconditionsofwaterelectrolysis
AT maznichenkosm erosionbehaviorofnickeldiffusionmembranesinconditionsofwaterelectrolysis
AT garkushaie erosionbehaviorofnickeldiffusionmembranesinconditionsofwaterelectrolysis
first_indexed 2024-03-31T09:17:49Z
last_indexed 2024-03-31T09:17:49Z
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