Some rigorous relations for partial conductivities in ionic liquids
Starting with the rigorous expressions, derived previously for the generalized transport coefficients of a multicomponent fluid, we obtained several exact relations for partial conductivities of ionic charge-asymmetric mixtures. For a simpler case of a charge-symmetric binary mixture such kind of re...
Збережено в:
| Дата: | 2010 |
|---|---|
| Автори: | , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
2010
|
| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/32129 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Some rigorous relations for partial conductivities in ionic liquids / I. Mryglod, V. Kuporov // Condensed Matter Physics. — 2010. — Т. 13, № 4. — С. 43602:1-8. — Бібліогр.: 10 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-32129 |
|---|---|
| record_format |
dspace |
| spelling |
irk-123456789-321292012-04-10T12:16:58Z Some rigorous relations for partial conductivities in ionic liquids Mryglod, I. Kuporov, V. Starting with the rigorous expressions, derived previously for the generalized transport coefficients of a multicomponent fluid, we obtained several exact relations for partial conductivities of ionic charge-asymmetric mixtures. For a simpler case of a charge-symmetric binary mixture such kind of relations was discovered experimentally by Sundheim more than 50 years ago and is known as the “universal golden rule”. Some more complicate models, describing in particular the cases of ternary and multi-component mixtures, are considered. The general relation for partial ionic conductivities is derived for a multi-component ionic fluid. It is shown that such relations can be considered in fact as an example of a more general class of rigorous expressions valid for (k, ω)-dependent quantities. 2010 Article Some rigorous relations for partial conductivities in ionic liquids / I. Mryglod, V. Kuporov // Condensed Matter Physics. — 2010. — Т. 13, № 4. — С. 43602:1-8. — Бібліогр.: 10 назв. — англ. 1607-324X PACS: 66.10.cg, 66.10.Ed, 82.45.Gj, 47.10.-g http://dspace.nbuv.gov.ua/handle/123456789/32129 en Condensed Matter Physics Інститут фізики конденсованих систем НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| description |
Starting with the rigorous expressions, derived previously for the generalized transport coefficients of a multicomponent fluid, we obtained several exact relations for partial conductivities of ionic charge-asymmetric mixtures. For a simpler case of a charge-symmetric binary mixture such kind of relations was discovered experimentally by Sundheim more than 50 years ago and is known as the “universal golden rule”. Some more complicate models, describing in particular the cases of ternary and multi-component mixtures, are considered. The general relation for partial ionic conductivities is derived for a multi-component ionic fluid. It is shown that such relations can be considered in fact as an example of a more general class of rigorous expressions valid for (k, ω)-dependent quantities. |
| format |
Article |
| author |
Mryglod, I. Kuporov, V. |
| spellingShingle |
Mryglod, I. Kuporov, V. Some rigorous relations for partial conductivities in ionic liquids Condensed Matter Physics |
| author_facet |
Mryglod, I. Kuporov, V. |
| author_sort |
Mryglod, I. |
| title |
Some rigorous relations for partial conductivities in ionic liquids |
| title_short |
Some rigorous relations for partial conductivities in ionic liquids |
| title_full |
Some rigorous relations for partial conductivities in ionic liquids |
| title_fullStr |
Some rigorous relations for partial conductivities in ionic liquids |
| title_full_unstemmed |
Some rigorous relations for partial conductivities in ionic liquids |
| title_sort |
some rigorous relations for partial conductivities in ionic liquids |
| publisher |
Інститут фізики конденсованих систем НАН України |
| publishDate |
2010 |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/32129 |
| citation_txt |
Some rigorous relations for partial conductivities in ionic liquids / I. Mryglod, V. Kuporov // Condensed Matter Physics. — 2010. — Т. 13, № 4. — С. 43602:1-8. — Бібліогр.: 10 назв. — англ. |
| series |
Condensed Matter Physics |
| work_keys_str_mv |
AT mryglodi somerigorousrelationsforpartialconductivitiesinionicliquids AT kuporovv somerigorousrelationsforpartialconductivitiesinionicliquids |
| first_indexed |
2023-10-18T17:34:03Z |
| last_indexed |
2023-10-18T17:34:03Z |
| _version_ |
1796141886625284096 |