Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions

Ordinary cylindrical specimens with easy-axis anisotropy perpendicular to the axis of a cylinder are studied. As shown, the inhomogeneous long-wave magnetic configurations of harmonic type can be created and observed in such samples. A linear theory is developed to simplify the set of Landau— Lifshi...

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Veröffentlicht in:Металлофизика и новейшие технологии
Datum:2016
Hauptverfasser: Dzhezherya, Yu.I., Gorobets, O.Yu., Kuz, O.P., Klymuk, O.S., Gorobets, Yu.I.
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Sprache:Englisch
Veröffentlicht: Інститут металофізики ім. Г.В. Курдюмова НАН України 2016
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Zitieren:Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions / Yu.I. Dzhezherya, O.Yu. Gorobets, O.P. Kuz, O.S. Klymuk, and Yu.I. Gorobets // Металлофизика и новейшие технологии. — 2016. — Т. 38, № 10. — С. 1379-1393. — Бібліогр.: 18 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Dzhezherya, Yu.I.
Gorobets, O.Yu.
Kuz, O.P.
Klymuk, O.S.
Gorobets, Yu.I.
author_facet Dzhezherya, Yu.I.
Gorobets, O.Yu.
Kuz, O.P.
Klymuk, O.S.
Gorobets, Yu.I.
citation_txt Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions / Yu.I. Dzhezherya, O.Yu. Gorobets, O.P. Kuz, O.S. Klymuk, and Yu.I. Gorobets // Металлофизика и новейшие технологии. — 2016. — Т. 38, № 10. — С. 1379-1393. — Бібліогр.: 18 назв. — англ.
collection DSpace DC
container_title Металлофизика и новейшие технологии
description Ordinary cylindrical specimens with easy-axis anisotropy perpendicular to the axis of a cylinder are studied. As shown, the inhomogeneous long-wave magnetic configurations of harmonic type can be created and observed in such samples. A linear theory is developed to simplify the set of Landau— Lifshitz and Maxwell’s equations to one general equation for a magnetostatic potential. The ranges of magnetic fields and the self-parameters responsible for the inhomogeneous periodic configuration formation are determined when solving a boundary value problem for a magnetostatic potential. Dependence of the period of magnetization wave on a magnetic field value, the constant of anisotropy and diameter of a cylinder is determined. The proposed theory gives qualitative explanation of the experiment when, using the Bitter’s powder-like figures’ method, quasi-periodic distributions of the magnetostatic fields can be observed in samples. These fields arise under external magnetic field of about 1 kOe directed along the axis of a steel cylinder and are absent without external magnetic field. An example of practical application of long-wave magnetic structures for a surface morphology control during chemical etching of ferromagnetic metals in acid solutions is given. The quasi-periodic structure of a corrosion surface of ferromagnetic cylinder corresponds to the period of a long-range magnetic structure. Досліджено циліндричні зразки з легковісною анізотропією, перпендикулярною до осі циліндру. Показано, що в таких зразках можна створювати і спостерігати неоднорідні довгохвильові магнетні конфіґурації гармонічного типу. Було розвинуто лінійну теорію, яка зводить систему рівнянь Ландау—Ліфшиця та Максвеллових, що описують магнетний стан системи, до одного загального рівняння для магнетостатичного потенціялу. В ході розв’язання крайової задачі для магнетостатичного потенціялу визначено діяпазон магнетних полів і власних параметрів системи, за яких ймовірним є утворення неоднорідної періодичної конфіґурації. Визначено залежність періоду хвилі намагнетованости від амплітуди магнетного поля, константи анізотропії та діяметра циліндру. Запропонована теорія дає якісне пояснення експерименту, коли при застосуванні Біттерової методи порошкових фіґур можливе спостереження квазиперіодичних розподілів магнетостатичних полів, що утворені при прикладанні зовнішнього магнетного поля порядку 1 кЕ вздовж осі сталевого циліндру, тоді як без прикладання зовнішнього магнетного поля магнетостатичні поля відсутні. Наведено приклад практичного застосування довгохвильових магнетних структур для керування морфологією поверхні при хемічному щавленні феромагнетних металів у розчинах кислот. При цьому квазиперіодична структура поверхні кородованого феромагнетного циліндра відповідає періоду його довгомасштабної магнетної структури. Исследованы цилиндрические образцы с легкоосной анизотропией, перпендикулярной оси цилиндра. Показано, что в таких образцах можно создать и наблюдать неоднородные длинноволновые магнитные конфигурации гармонического типа. Развита линейная теория, которая сводит систему уравнений Ландау—Лифшица и Максвелла, описывающих магнитное состояние системы, к одному общему уравнению для магнитостатического потенциала. В ходе решения краевой задачи для магнитостатического потенциала определён диапазон магнитных полей и собственных параметров системы, при которых вероятным является образование неоднородной периодической конфигурации. Определена зависимость периода волны намагниченности от амплитуды магнитного поля, константы анизотропии и диаметра цилиндра. Предложенная теория даёт качественное объяснение эксперимента, когда при применении метода порошковых фигур Биттера возможно наблюдение квазипериодических распределений магнитостатических полей, образованных при воздействии внешнего магнитного поля порядка 1 кЕ вдоль оси стального цилиндра, в то время как без приложения внешнего магнитного поля магнитостатические поля отсутствуют. Приведён пример практического использования длинноволновых магнитных структур для управления морфологией поверхности при химическом травлении ферромагнитных материалов в растворах кислот. При этом квазипериодическая структура поверхности корродированного ферромагнитного цилиндра соответствует периоду его длинномасштабной структуры.
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fulltext 1379 PACS numbers:03.50.De, 41.20.Gz,75.10.-b,75.30.Gw,75.60.Ch,75.70.Kw, 81.65.Cf Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions Yu. I. Dzhezherya, O. Yu. Gorobets*, O. P. Kuz*, O. S. Klymuk*, and Yu. I. Gorobets  Institute of Magnetism, N.A.S. and M.E.S. of Ukraine, 36b Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine *National Technical University of Ukraine ‘KPI’, 37 Peremogy Ave., UA-03056 Kyiv, Ukraine Ordinary cylindrical specimens with easy-axis anisotropy perpendicular to the axis of a cylinder are studied. As shown, the inhomogeneous long-wave magnetic configurations of harmonic type can be created and observed in such samples. A linear theory is developed to simplify the set of Landau— Lifshitz and Maxwell’s equations to one general equation for a magnetostatic potential. The ranges of magnetic fields and the self-parameters responsible for the inhomogeneous periodic configuration formation are determined when solving a boundary value problem for a magnetostatic potential. De- pendence of the period of magnetization wave on a magnetic field value, the constant of anisotropy and diameter of a cylinder is determined. The pro- posed theory gives qualitative explanation of the experiment when, using the Bitter’s powder-like figures’ method, quasi-periodic distributions of the magnetostatic fields can be observed in samples. These fields arise under ex- ternal magnetic field of about 1 kOe directed along the axis of a steel cylinder and are absent without external magnetic field. An example of practical ap- plication of long-wave magnetic structures for a surface morphology control during chemical etching of ferromagnetic metals in acid solutions is given. Corresponding author: Yuri Ivanovich Dzhezherya E-mail: dui_kpi@ukr.net Please cite this article as: Yu. I. Dzhezherya, O. Yu. Gorobets, O. P. Kuz, O. S. Klymuk, and Yu. I. Gorobets, Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions, Metallofiz. Noveishie Tekhnol., 38, No. 10: 1379—1393 (2016), DOI: 10.15407/mfint.38.10.1379. Металлофиз. новейшие технол. / Metallofiz. Noveishie Tekhnol. 2016, т. 38, № 10, сс. 1379—1393 / DOI: 10.15407/mfint.38.10.1379 Оттиски доступны непосредственно от издателя Фотокопирование разрешено только в соответствии с лицензией 2016 ИМФ (Институт металлофизики им. Г. В. Курдюмова НАН Украины) Напечатано в Украине. 1380 Yu. I. DZHEZHERYA, O. Yu. GOROBETS, O. P. KUZ et al. The quasi-periodic structure of a corrosion surface of ferromagnetic cylinder corresponds to the period of a long-range magnetic structure. Key words: ferromagnets, domain structure, magnetostatic field, etching. Досліджено циліндричні зразки з легковісною анізотропією, перпенди- кулярною до осі циліндру. Показано, що в таких зразках можна створю- вати і спостерігати неоднорідні довгохвильові магнетні конфіґурації гар- монічного типу. Було розвинуто лінійну теорію, яка зводить систему рів- нянь Ландау—Ліфшиця та Максвеллових, що описують магнетний стан системи, до одного загального рівняння для магнетостатичного потенція- лу. В ході розв’язання крайової задачі для магнетостатичного потенціялу визначено діяпазон магнетних полів і власних параметрів системи, за яких ймовірним є утворення неоднорідної періодичної конфіґурації. Ви- значено залежність періоду хвилі намагнетованости від амплітуди магне- тного поля, константи анізотропії та діяметра циліндру. Запропонована теорія дає якісне пояснення експерименту, коли при застосуванні Бітте- рової методи порошкових фіґур можливе спостереження квазиперіодич- них розподілів магнетостатичних полів, що утворені при прикладанні зовнішнього магнетного поля порядку 1 кЕ вздовж осі сталевого цилінд- ру, тоді як без прикладання зовнішнього магнетного поля магнетостатич- ні поля відсутні. Наведено приклад практичного застосування довгохви- льових магнетних структур для керування морфологією поверхні при хе- мічному щавленні феромагнетних металів у розчинах кислот. При цьому квазиперіодична структура поверхні кородованого феромагнетного цилі- ндра відповідає періоду його довгомасштабної магнетної структури. Ключові слова: феромагнетики, доменна структура, магнетостатичне по- ле, щавлення. Исследованы цилиндрические образцы с легкоосной анизотропией, пер- пендикулярной оси цилиндра. Показано, что в таких образцах можно со- здать и наблюдать неоднородные длинноволновые магнитные конфигура- ции гармонического типа. Развита линейная теория, которая сводит си- стему уравнений Ландау—Лифшица и Максвелла, описывающих магнит- ное состояние системы, к одному общему уравнению для магнитостатиче- ского потенциала. В ходе решения краевой задачи для магнитостатиче- ского потенциала определён диапазон магнитных полей и собственных параметров системы, при которых вероятным является образование не- однородной периодической конфигурации. Определена зависимость пе- риода волны намагниченности от амплитуды магнитного поля, константы анизотропии и диаметра цилиндра. Предложенная теория даёт каче- ственное объяснение эксперимента, когда при применении метода по- рошковых фигур Биттера возможно наблюдение квазипериодических распределений магнитостатических полей, образованных при воздей- ствии внешнего магнитного поля порядка 1 кЕ вдоль оси стального ци- линдра, в то время как без приложения внешнего магнитного поля магни- тостатические поля отсутствуют. Приведён пример практического ис- пользования длинноволновых магнитных структур для управления мор- фологией поверхности при химическом травлении ферромагнитных ма- PERIODIC MODULATIONS OF MAGNETOSTATIC FIELD IN CYLINDER 1381 териалов в растворах кислот. При этом квазипериодическая структура поверхности корродированного ферромагнитного цилиндра соответствует периоду его длинномасштабной структуры. Ключевые слова: ферромагнетики, доменная структура, магнитостатиче- ское поле, травление. (Received September 12, 2016) 1. INTRODUCTION Ferromagnetic materials are known to possess domain structure due to competition of magnetic interactions of the certain types. On the one hand, it is the energy of a magnetic anisotropy and exchange interac- tion; on the other hand, it is dipole—dipole interaction of magnetic moments of the system. Domain structure acquires the various forms depending on the contribution of the mentioned interactions, a speci- men shape and characteristics of external magnetic field [1—4]. It can be a system of stripe domains, serpentine domain structure, a lattice of cylindrical domains, spiral domains, etc. Similar structures appear spontaneously or artificially and correspond to an absolute or a local minimum of complete energy among the variety of magnetic configu- rations. The parameters of certain types of domain structures (DS) and their separate elements have been widely studied both by experimental and theoretical methods, for example [1—6]. These papers report on ther- modynamic properties of ferromagnetic materials, the influence of DS on their magnetization processes and their practical use in magnetic devices. Except the practical application, investigation of magnetic configurations is interesting itself in the theory of the non-linear equations and theirs soliton-like solutions. There are some elements of domain structures describing system magnetization field distribution, which satisfy the joint solution of the magnetostatic equations and the Landau—Lifshitz non-linear equa- tions. These are the Néel and Bloch one-dimensional domain walls, the Shirobokov stripe domain structure, and the Belavin—Polyakov two- dimensional soliton configurations. However, for real systems with geometrical restrictions of the samples, the mentioned solutions could be considered only as certain approach to the real magnetic configura- tions. Certain simplifications are necessary to take into account fac- tors of magnetic objects shape and a wide spectrum of magnetic inter- actions influence. One of the most useful simplifications consists in representation of a domain wall as geometrical boundary characterized by a surface energy. A number of important domain configurations and their elements have been investigated due to this approach [1, 2, 4]. 1382 Yu. I. DZHEZHERYA, O. Yu. GOROBETS, O. P. KUZ et al. However, there are magnetic configurations with the fundamentally different magnetization distribution compared to traditional domain structures, which are formed in ferromagnetic systems under certain conditions. These are non-uniform magnetic configurations in systems with biaxial anisotropy. Inhomogeneous magnetic ordering character of such configurations is caused by a demagnetizing field in the presence of exchange interac- tion. These structures are characterized by the sinusoidal type modula- tion of magnetization components. The existence of such structures in magnetic films or plates with anisotropy factor lower than unit, were predicted in papers [7, 8]. The inhomogeneous structure period de- pendence on the thickness and parameters of material was determined as well. The development of this theory was the discovery of a magnetic field influence on the magnetization distribution in such structures [9]. 2. THEORETICAL DETAILS 2.1. Problem Definition It will be shown further that the inhomogeneous long-wave magnetic configuration of harmonic type can be created and observed in cylin- drical samples with ‘easy magnetic plane’ anisotropy, which is perpen- dicular to the axis of the cylinder. The necessary condition of sinusoi- dal modulations creation in such systems is the magnetic field directed along the cylinder axis. 2.2. The Equation for the Magnetostatic Potential and the Distribution of Magnetization in Ferromagnetic Film We assume that the system is a ferromagnetic cylinder in an external magnetic field. The cylinder axis coincides with the direction of the field and is directed along 0z. It is supposed that while making such a sample form (by rolling or drawing), uniaxial anisotropy of ‘easy mag- netization’ occurs in the material in plane that is perpendicular to the axis of the cylinder. Thus, the magnetic energy density of the film material consists of the exchange interaction energy, the Zeeman energy and magnetic ani- sotropy energy and is given by: 2 2 , 2 2 M z z k w M HM x         M (1) where –a constant of exchange magnetic interaction, M–a system PERIODIC MODULATIONS OF MAGNETOSTATIC FIELD IN CYLINDER 1383 magnetization vector, –the uniaxial anisotropy constant, H– magnetic field value in the direction of cylinder axis 0z. In case of   0, we have anisotropy of ‘easy plane’ (x0y plane). The fragment of a cylindrical ferromagnetic sample is shown in Fig. 1. As, in ferromagnetic systems at fixed temperature, the absolute value of magnetization is constant, 2 2 2 2 2 0 constx y zM M M M    M (where M0–the saturation magnetization), we can represent Eq. (1) in form:   2 2 2 2 0 . 2 2 M x y z k w M M M HM x           M (2) Based on Eq. (2), we can express effective magnetic field determined through variation derivative:  eff ,M i x x y y i w M M             H M e e M (3) where i–a potential of a magnetostatic field in the cylinder, 2 i i x x     –the Laplace operator, i –gradient of magnetostatic potential in the cylinder, describing demagnetizing field of the sample .m i i  H Last term in Eq. (3) determines demagnetizing field caused by mag- netization inhomogeneities. The first term M is caused by exchange interactions. When changing of the magnetization modulations at great space scale (for example, the radius of a cylinder), it makes small contribution and can be neglected. Indeed, for cylindrical magnetic system of the radius R, we can es- timate M as follows: Fig. 1. The fragment of the ferromagnetic sample of a cylinder shape. 1384 Yu. I. DZHEZHERYA, O. Yu. GOROBETS, O. P. KUZ et al. 2 2 4 ,M RR           M M where 4 (4 ) 10 cm      –the characteristic magnetic length. Thus, for ferromagnetic rods or wires of the diameter of 2 2 10 cm,R  the value of 4 4 10M     M is of the same order with the terrestrial magnetic field. The self-consistent distribution of magnetostatic fields and system magnetization in the cylinder is described by the Landau—Lifshitz and Maxwell’s equation sets, which correspond to a static case:  eff eff 0, div 0, 4 , . i i i z i z H H            M H B B e M H e (4) If the macroscopically modulations of a magnetization field with a wavelength close to the cylinder diameter are considered, then, the quantities with the second spatial derivatives in an effective field could be ignored, and the set of equations (4) will be as follows: ( ) ( ), ( ) ( ), ( ) ( ), 4 div . x y i y x i x i z x i y i z y i i M M y M M x M H z M M x M H z M M y                             M (5) The potential e and magnetic induction Be satisfy to relations out- side the sample: 0, . e e e zH     B e (6) Requirements of the continuity of potential and the magnetic field component normal to the surface of the cylinder should be satisfied at the boundary of two media: , 4 , i e r R i e n r R M r r              (7) where Mn–magnetization vector component normal to the cylinder surface. PERIODIC MODULATIONS OF MAGNETOSTATIC FIELD IN CYLINDER 1385 If magnetic field H directed along cylinder axis is greater than ani- sotropy field, H  M0, then, ferromagnetic sample obtains homogene- ous magnetization. Otherwise, H  M0, magnetization direction can deviate from the cylinder axis 0z. Suppose that such deviations are negligibly small. So, zM  2 2 2 0 0x yM M M M    . In such approximation, we excluded terms 2 2 0 0 ( ) , ( ) 1. x y M M M M  (8) Condition (8) is a soft constraint, because it allows operating with ra- ther noticeable magnetization modulations: 0 , 0.3x yM M M . Considering that the magnetostatic potential changes are caused by magnetization modulations and have a small value as well, let us keep only the linear terms in the equations (4). As a result, the following re- lation is obtained between magnetization and magnetostatic potential components: 4 , 4 ,i i x y x y M M Q h Q h           (9) where 0 (4 )h H M  –a reduced magnetic field and (4 )Q    –a re- duced anisotropy of the system. Substituting the relation (9) in (4), the equation for magnetostatic potential is obtained in the self-contained view: 2 2 2 2 2 2 2 2 0, 1 ( ) . i i ia x y z Q h a Q h                 (10) As a system possesses axial symmetry, it makes sense to represent equations (10) in a cylindrical coordinate system: 2 2 2 2 2 2 1 1 0,i i ia r r r r r z               where 2 2 , arct ( ).r x y g y x    The equation (10) changes into wave one and can describe spontane- ous modulation of magnetization of cylindrical sample, if the coeffi- cient before a bracket has positive value. This condition can be pre- sented as 0 1Q h   or in initial designations: 0 0 0 4 .M H M     (11) 1386 Yu. I. DZHEZHERYA, O. Yu. GOROBETS, O. P. KUZ et al. It follows from (11) that the magnetostatic wave structure cannot spontaneously be generated without magnetic field presence in a direc- tion of system axis at large value of anisotropy when 4   . The re- quirement of occurrence of such magnetization modulation is carried out starting from some fixed value of the magnetic field. Taking into account the relations (9), boundary conditions for the magnetostatic potential (7) on the surface of the cylinder gain the fol- lowing meaning: 2 , . i e r R i e r R a r r           (12) Besides, the magnetic field on some distance from the sample should be converted in zero. We will search for the solution of the boundary value problem (5), (10), (12) in case of the axial symmetry in the following form:          0 0 ( , ) cos , ( , ) ( ) cos , i e kr r z AJ kz a r z BK kr kz (13) where Jn(x)–the Bessel functions, and Kn(x)–McDonald’s functions decaying at r   , k–a wave number, A, B–some constants defying amplitude of modulation. The given functions turn the equation for the magnetostatic field potential to identity at any value of a wave number k. The real value of k is determined from the characteristic equation, which can be written out from the boundary conditions (12). Substitut- ing (13) in relations for boundary conditions, the set of the homogene- ous linear equations is obtained: 0 0 1 1 ( ) ( ) 0 . ( ) ( ) 0 J kR a K kR A aJ kR a K kR B                  (14) The requirement of non-zero solvability of the set (14) leads to the characteristic equation: 0 1 1 0 ( ) ( ) ( ) ( ) 0.J kR a K kR aJ kR a K kR  (15) The equation (15) has a discrete set of solutions concerning a wave number. We will be restricted by the definition of the minimum of k value as the configurations with high values of wave numbers are characterised by greater energy at the account of an exchange interac- tion. PERIODIC MODULATIONS OF MAGNETOSTATIC FIELD IN CYLINDER 1387 2.3. Discussion It follows from the Eq. (15) that the wave number depends on a mag- netic field and anisotropy of a material. The dependences of modula- tion wavelengths on the quality factor Q and magnetic field h for the first numbers of a discrete spectrum are presented in Fig. 2. Asymptotic behaviour of the magnetization wavelengths depend- ences on the external magnetic field can be easily obtained from the (15). Thus, having h Q , we can get for the spectrum brunches: 2 ,n n R L Q h P   (16) where Pn–zeros of the Bessel function J1(x): 1 ( ) 0,nJ P  1 2 3.817, 7.0156, ...P P  For the ferromagnetic systems with high anisotropy Q  1, we can get asymptotic behaviour at ( 1) 0 :h Q   2 , ( 1) n n R L G h Q    (17) where Gn–zeros of the Bessel function J0(x): 0 ( ) 0,nJ G  1 2 2.4048, 5.5201, ...G G  It follows from the Eqs. (16), (17) that, at h Q for any mode, the magnetostatic modulations wavelength tends to zero obeying square- root law, while, for the systems with 1Q  at ( 1) 0h Q   , the wavelength asymptotically tends to . a b c Fig. 2. Magnetostatic modulations wavelength dependence for several first modes of a spectrum. 1388 Yu. I. DZHEZHERYA, O. Yu. GOROBETS, O. P. KUZ et al. 3. EXPERIMENTAL DETAILS As it has been already mentioned, there are different types of lattices of magnetic domains in the ferromagnetic materials under certain conditions: the stripe domain structure, hexagonal lattices of cylindri- cal magnetic domains, etc. However, the situation is even more typical when there are more complicated inhomogeneous magnetization pat- terns in ferromagnets, for which existence of the large-scale qua- siperiodic ‘over-lattices’ is typically observed ‘against’ micro scale pe- riodic structure of magnetic domains. For example, open domain structure with a magnetization direction perpendicular to the magnetic microwire surface [10]. As a rule, long ferromagnetic cylinder can have such configurations of domains that we can see not only the microscale domain structure for the amorphous magnetic micro wire but the quasi-periodic change of magnetization direction which is expressed in large-scale quasi-periodic change of the angle slope of magnetic domains concerning the symmetry axis of a microwire [10]. Similarly, the long-range magnetic structures of iron and steel cyl- inders with the Bitter’s method application (a sedimentation method of highly dispersed paramagnetic powders (Fe2O3) on a ferromagnetic surface from the distilled water) were revealed [11]. Magnetic structures observed experimentally in [11—16] for thin iron and steel cylinders are typical in comparison with the structures observed by other authors [10]. Such long-range domain structures of steel and iron cylinders as those have been shown in [11—16] can essen- tially affect the processes in electrolytes in the vicinity of their surfac- es, in particular the processes of chemical etching in acids solutions. In the present work with the use of the Bitter’s powder-like figures’ method, we have revealed the quasi-periodic distribution of magneto- static fields formed by an external magnetic field of about 1—10 kOe applied along the axis of the steel cylinder and absent when the exter- nal magnetic field is not applied. To investigate the magnetic field influence on the surface structure as a result of metal ferromagnet corrosion, we compared the steel cyl- inder surfaces as a result of corrosion in the solution of nitric acid without and with the magnetic field applied along the steel cylinder axis. Besides, the steel cylinders’ surfaces under the experiments be- fore the immersion on the solution were controlled by the optical mi- croscope and the error of the medial diameter was less than 1 micron along the whole length. For definiteness, let us consider typical change of the steel cylinder shape in a magnetic field in a nitric acid solution. The steel that the cylinder (DSTU 1050-88) has been made of, has the following composi- tion: iron–98%, other elements (nickel, copper, chrome, carbon, PERIODIC MODULATIONS OF MAGNETOSTATIC FIELD IN CYLINDER 1389 phosphorus, sulphur, silicon, manganese)–2%, and a surface before the experiment had smooth enough structure (Fig. 3, a), the cylinder length was equal to 18 mm in the experiments which results are given in Figs. 3, 4 and in Table 1. The optical images of initial cylinder surface and cylinders after etching in 7% water solution of nitric acid are given in Figs. 3, b—e. It is clear that the cylinders corrode uniformly along the axis with formation of a smooth surface without appreciable dents and hills without external magnetic field. The diameter of cylinders along the axis within an error did not depend on coordinate. Magnetostatic fields’ distribution in dependence on initial diameter of a ferromagnetic cylinder was visualized by the Bitter’s powder-like figures’ method. The highly dispersed paramagnetic powder of iron oxide was used. Powder sedimentation was carried out with and with- out external magnetic field. Non-magnetized cylinders of different Fig. 3. The images of the initial cylinder d  550 m (a) and the cylinders after different duration of etching in a 7% solution of nitric acid without external magnetic field: b–460 m, c–440 m, d–400 m, e–360 m. Fig. 4. Allocation of paramagnetic powder on a surface of the not magnetized cylinder of D  440 m. 1390 diameter purpose. The 23 distilled system o field app ized. The until the 460 m a ternal ma It is cl periodic The av the etchi Accord periods o der figur ders of a TABLE 1 on the cyl The cylin der diam- eter D, m 460 440 400 360 Yu. I. DZH rs were fas 3 ml of sus water were or in a cons plied, the cy e powder se e saturation after sedim agnetic fiel lear from F magnetic d verage dim ing figures ding to the of the struc res and etc a wide rang . The image linder diame n- - m The image visualisat scale distr HEZHERYA, stened on a spension co e added to t stant homo ylinder tur edimentatio n. The opti mentation o ld is given i Fig. 4 that domain stru mensional ch are given i e results, th ctures  3 L ching are id e of diamet of the powd eter. e of the powd tion of quasi ribution of m fields O. Yu. GORO a thread an ontaining a the cell, wh ogeneous m rned along on on the c ical image of the para in Fig. 4. t, without m ucture of th haracterist in Table 2. he width of   1 2 L L ob dentical wi ters in exte der figures a der figures f iperiodic lon magnetostat OBETS, O. P. K nd placed in a paramag hich was ou magnetic fi its directio ylinder wa of the cyli amagnetic magnetic f he steel cyli tics of the f elevation btained by ithin the e ernal magn and the etchi for ng tic The im figures eleva KUZ et al. nside a cel netic powd utside of a eld. With on and was s carried fo inder with powder wit ield, the la inder is not powder fig s L1, caviti the method rror for st netic field f ing figures d mage of the e s with quasi- ations and ca ll for this der in the magnetic magnetic s magnet- or 15 min diameter thout ex- arge-scale t formed. gures and ies L2 and d of pow- teel cylin- for homo- depending etching -periodic avities PERIODIC MODULATIONS OF MAGNETOSTATIC FIELD IN CYLINDER 1391 geneous external magnetic field value В  3 kG. The average width of elevations of the Bitter’s powder figures and elevations of etching fig- ures is about 100 m. The length of cavities is about 200 m. There- fore, the cavities are approximately twice wider than elevations. The length of period of the structures is approximately 300 m. The regions with the increased and decreased etching rates of fer- romagnetic cylinder appear due to the inhomogeneous quasi-periodic magnetostatic-fields’ distribution in the ferromagnetic cylinder. The nonuniform magnetic fields of cylinder domain structure create the nonuniform concentration distribution of paramagnetic or effectively paramagnetic cluster products of chemical etching [17] at the interface with an electrolyte that leads to the cylinder heterogeneity dissolution along the axis and to formation of the quasi-periodic structure on its surface [11—16]. The hysteresis curve of the steel cylinder is presented in Fig. 5. The Fig. 5. The hysteresis curve of the steel cylinder, coercive forceНс  17 Oe. TABLE 2. The average dimensional characteristics of the powder figures and the etching figures. D, m Dimensional characteristics of the powder figures Dimensional characteristics of the etching figures L1, m 1, m L2, m 2, m L3, m 3, m L1, m 1, m L2, m 2, m L3, m 3, m 460 100 10 240 20 340 30 100 10 230 30 320 30 440 100 10 220 20 320 20 100 10 200 20 300 20 400 110 10 220 30 320 30 110 10 200 20 310 20 360 100 10 210 30 310 30 110 10 180 30 310 30 1392 Yu. I. DZHEZHERYA, O. Yu. GOROBETS, O. P. KUZ et al. hysteresis curve comparison with the results of visualization of the large-scale distribution of magnetostatic fields by means of the powder figures gives the possibility to admit that the short-range non-regular domain structure with the sizes of separate domains less than the cyl- inder diameter exists in external magnetic fields, lower than critical field Нcr. The process of cylinder magnetization is not terminated with the ex- ternal magnetic field exceeding Нcr, and the large-scale quasi-periodic domain structure is created, and the magnetization of the sample line- arly grows at the subsequent increase of an external magnetic field. 4. CONCLUSION It is shown for cylinders of different diameters (Table 2) that for- mation of etching figures under external magnetic field is caused by spatial distribution of their magnetostatic fields. As a result, it is shown in the present work for the steel cylinders of different diameter that the quasi-periodic structure of corrode surfaces is created during their chemical etching in a solution of nitric acid with the constant magnetic field applied, while the quasi-periodic structure of corrode surfaces is not formed under the same experimental conditions with- out magnetic field influence. Besides, the quasi-periodic structure of the cylinder that is observed due to its etching arises only on ferro- magnetic samples and the characteristic period of the quasi-periodic structure equals to the period of the long-range magnetic structure of ferromagnetic sample. The results of the present work prove experimentally the possibility of formation of inhomogeneous boundary conditions for the electric field potential and a current density, offered in [18], on an interface metal—electrolyte, if metal is spatially homogeneous with its chemical compound and mechanical properties. REFERENCES 1. Ch. Kittel, Phys. Rev., 70, 965 (1946). 2. A. A. Thiele, Bell System Techn. J., 48: 3287 (1969). 3. A. H. Bobeck and E. Della Torre, Magnetic Bubbles (Amsterdam: North-Holland Publishing Co.: 1975). 4. A. P. Malozemoff and J. C. Slonczewski, Magnetic Domain Walls in Bubble Materials (New York: Academic Press: 1979). 5. A. N. Eschenfelder, Physics and Technology of Cylindrical Magnetic Domains (New York: Wiley: 1983). 6. J. A. Cape and G. W. Lehman, J. Appl. Phys., 42: 5732 (1971). 7. Yu. І. Dzhezherya, M. V. Sorokіn, and O. O. Bubuk, Naukovі Visti NTUU ‘KPI’, 4: 51 (2006) (in Ukrainian). PERIODIC MODULATIONS OF MAGNETOSTATIC FIELD IN CYLINDER 1393 8. Yu. I. Dzhezherya, M. V. Sorokin, and E. A. Bubuk, Zh. Eksp. Teor. Fiz., 133: 844 (2007). 9. Yu. I. Dzhezherya and K. O. Demіshev, Metallofiz. Noveishie Tekhnol., 34, No. 4: 429 (2012) (in Ukrainian). 10. Yu. Kabanov, A. Zukov, V. Zukova, and J. Gonzalez, International Conference ‘Functional Materials’ (Partenit, The Crimea, Ukraine, 2005), p. 66. 11. M. Yu. Ilchenko, S. V. Gorobets, O. Yu. Gorobets, and O. K. Dvoynenko, International Conference ‘Functional Matetials’ ICFM-2011 (Partenit, The Crimea, Ukraine, October 3—8, 2011), p. 393. 12. O. Yu. Gorobets, S. V. Gorobets, D. O. Derecha, and O. M. Brukva, J. Phys. Chem. C, 112: 3373 (2008). 13. O. Yu. Gorobets and D. O. Derecha, Mater. Sci., 24: 1017 (2007). 14. S. V. Gorobets, O. Yu. Gorobets, O. K. Dvoinenko, and G. L. Lebeda, Phys. Met. Metallogr., 113: 129 (2012). 15. S. V. Gorobets, O. Yu. Gorobets, S. P. Mazur, and A. A. Slusar, physica status solidi (c), 1: 3686 (2004). 16. S. V. Gorobets, O. Yu. Gorobets, and O. M. Brukva, Appl. Surf. Sci., 252/2: 448 (2005). 17. O. Yu. Gorobets, Yu. I. Gorobets, I. A. Bondar, and Yu. A. Legenkiy, J. Magn. Magn. Mater., 330: 76 (2013). 18. О. Yu. Gorobets, Yu. I. Gorobets, and V. P. Rospotnyuk, Metallofiz. 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id nasplib_isofts_kiev_ua-123456789-112623
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn 1024-1809
language English
last_indexed 2025-12-07T18:40:01Z
publishDate 2016
publisher Інститут металофізики ім. Г.В. Курдюмова НАН України
record_format dspace
spelling Dzhezherya, Yu.I.
Gorobets, O.Yu.
Kuz, O.P.
Klymuk, O.S.
Gorobets, Yu.I.
2017-01-24T12:37:24Z
2017-01-24T12:37:24Z
2016
Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions / Yu.I. Dzhezherya, O.Yu. Gorobets, O.P. Kuz, O.S. Klymuk, and Yu.I. Gorobets // Металлофизика и новейшие технологии. — 2016. — Т. 38, № 10. — С. 1379-1393. — Бібліогр.: 18 назв. — англ.
1024-1809
DOI: 10.15407/mfint.38.10.1379
PACS: 03.50.De, 41.20.Gz, 75.10.-b, 75.30.Gw, 75.60.Ch, 75.70.Kw, 81.65.Cf
https://nasplib.isofts.kiev.ua/handle/123456789/112623
Ordinary cylindrical specimens with easy-axis anisotropy perpendicular to the axis of a cylinder are studied. As shown, the inhomogeneous long-wave magnetic configurations of harmonic type can be created and observed in such samples. A linear theory is developed to simplify the set of Landau— Lifshitz and Maxwell’s equations to one general equation for a magnetostatic potential. The ranges of magnetic fields and the self-parameters responsible for the inhomogeneous periodic configuration formation are determined when solving a boundary value problem for a magnetostatic potential. Dependence of the period of magnetization wave on a magnetic field value, the constant of anisotropy and diameter of a cylinder is determined. The proposed theory gives qualitative explanation of the experiment when, using the Bitter’s powder-like figures’ method, quasi-periodic distributions of the magnetostatic fields can be observed in samples. These fields arise under external magnetic field of about 1 kOe directed along the axis of a steel cylinder and are absent without external magnetic field. An example of practical application of long-wave magnetic structures for a surface morphology control during chemical etching of ferromagnetic metals in acid solutions is given. The quasi-periodic structure of a corrosion surface of ferromagnetic cylinder corresponds to the period of a long-range magnetic structure.
Досліджено циліндричні зразки з легковісною анізотропією, перпендикулярною до осі циліндру. Показано, що в таких зразках можна створювати і спостерігати неоднорідні довгохвильові магнетні конфіґурації гармонічного типу. Було розвинуто лінійну теорію, яка зводить систему рівнянь Ландау—Ліфшиця та Максвеллових, що описують магнетний стан системи, до одного загального рівняння для магнетостатичного потенціялу. В ході розв’язання крайової задачі для магнетостатичного потенціялу визначено діяпазон магнетних полів і власних параметрів системи, за яких ймовірним є утворення неоднорідної періодичної конфіґурації. Визначено залежність періоду хвилі намагнетованости від амплітуди магнетного поля, константи анізотропії та діяметра циліндру. Запропонована теорія дає якісне пояснення експерименту, коли при застосуванні Біттерової методи порошкових фіґур можливе спостереження квазиперіодичних розподілів магнетостатичних полів, що утворені при прикладанні зовнішнього магнетного поля порядку 1 кЕ вздовж осі сталевого циліндру, тоді як без прикладання зовнішнього магнетного поля магнетостатичні поля відсутні. Наведено приклад практичного застосування довгохвильових магнетних структур для керування морфологією поверхні при хемічному щавленні феромагнетних металів у розчинах кислот. При цьому квазиперіодична структура поверхні кородованого феромагнетного циліндра відповідає періоду його довгомасштабної магнетної структури.
Исследованы цилиндрические образцы с легкоосной анизотропией, перпендикулярной оси цилиндра. Показано, что в таких образцах можно создать и наблюдать неоднородные длинноволновые магнитные конфигурации гармонического типа. Развита линейная теория, которая сводит систему уравнений Ландау—Лифшица и Максвелла, описывающих магнитное состояние системы, к одному общему уравнению для магнитостатического потенциала. В ходе решения краевой задачи для магнитостатического потенциала определён диапазон магнитных полей и собственных параметров системы, при которых вероятным является образование неоднородной периодической конфигурации. Определена зависимость периода волны намагниченности от амплитуды магнитного поля, константы анизотропии и диаметра цилиндра. Предложенная теория даёт качественное объяснение эксперимента, когда при применении метода порошковых фигур Биттера возможно наблюдение квазипериодических распределений магнитостатических полей, образованных при воздействии внешнего магнитного поля порядка 1 кЕ вдоль оси стального цилиндра, в то время как без приложения внешнего магнитного поля магнитостатические поля отсутствуют. Приведён пример практического использования длинноволновых магнитных структур для управления морфологией поверхности при химическом травлении ферромагнитных материалов в растворах кислот. При этом квазипериодическая структура поверхности корродированного ферромагнитного цилиндра соответствует периоду его длинномасштабной структуры.
en
Інститут металофізики ім. Г.В. Курдюмова НАН України
Металлофизика и новейшие технологии
Металлические поверхности и плёнки
Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions
Періодичні модуляції магнетостатичного поля у феромагнетному циліндрі та їх вплив на формування фіґур щавлення у розчинах кислот
Периодические модуляции магнитостатического поля в ферромагнитном цилиндре и их влияние на формирование фигур травления в растворах кислот
Article
published earlier
spellingShingle Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions
Dzhezherya, Yu.I.
Gorobets, O.Yu.
Kuz, O.P.
Klymuk, O.S.
Gorobets, Yu.I.
Металлические поверхности и плёнки
title Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions
title_alt Періодичні модуляції магнетостатичного поля у феромагнетному циліндрі та їх вплив на формування фіґур щавлення у розчинах кислот
Периодические модуляции магнитостатического поля в ферромагнитном цилиндре и их влияние на формирование фигур травления в растворах кислот
title_full Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions
title_fullStr Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions
title_full_unstemmed Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions
title_short Periodic Modulations of Magnetostatic Field in Ferromagnetic Cylinder and Their Influence on Etching Figure Formation in Acid Solutions
title_sort periodic modulations of magnetostatic field in ferromagnetic cylinder and their influence on etching figure formation in acid solutions
topic Металлические поверхности и плёнки
topic_facet Металлические поверхности и плёнки
url https://nasplib.isofts.kiev.ua/handle/123456789/112623
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