Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy

Local structure of Ce₁₋xLaxRu₂ system, measured by EXAFS has been re-examined and correlated to the statistical ad hoc model, recently applied to the sphalerite, wurtzite and other intermetallic ternary alloys. The deconvolution of the EXAFS data show that the Ce₁₋xLaxRu₂ ternary system is essential...

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Published in:Физика низких температур
Date:2009
Main Authors: Robouch, B.V., Marcelli, A., Saini, N.L., Kisiel, A.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2009
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/116838
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy / B.V. Robouch, A. Marcelli, N.L. Saini, A. Kisiel// Физика низких температур. — 2009. — Т. 35, № 1. — С. 116-121. — Бібліогр.: 28 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-116838
record_format dspace
spelling Robouch, B.V.
Marcelli, A.
Saini, N.L.
Kisiel, A.
2017-05-16T16:18:43Z
2017-05-16T16:18:43Z
2009
Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy / B.V. Robouch, A. Marcelli, N.L. Saini, A. Kisiel// Физика низких температур. — 2009. — Т. 35, № 1. — С. 116-121. — Бібліогр.: 28 назв. — англ.
PACS: 61.05.cj, 74.70.Ad, 74.70.Tx
https://nasplib.isofts.kiev.ua/handle/123456789/116838
Local structure of Ce₁₋xLaxRu₂ system, measured by EXAFS has been re-examined and correlated to the statistical ad hoc model, recently applied to the sphalerite, wurtzite and other intermetallic ternary alloys. The deconvolution of the EXAFS data show that the Ce₁₋xLaxRu₂ ternary system is essentially a mixture of: CeRu₂ and LaRu₂ binary alloys with a small proportion of the Ce₀.₅La₀.₅Ru₂ ternary configuration, being maximum for the intermediate concentration. Moreover, the analysis reveals that while the LaRu₂ configuration exhibits a Bernoulli random distribution, the presence of a Ce atom affects both the CeRu₂ and Ce₀.₅La₀.₅Ru₂ distributions, strongly favoring the configuration with the CeCe pair, while keeping rare that with a single Ce ion.
This work is partially supported by the COMEPHS project.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
XVII Уральская международная зимняя школа по физике полупроводников
Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy
spellingShingle Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy
Robouch, B.V.
Marcelli, A.
Saini, N.L.
Kisiel, A.
XVII Уральская международная зимняя школа по физике полупроводников
title_short Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy
title_full Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy
title_fullStr Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy
title_full_unstemmed Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy
title_sort statistical model structure of a₁₋xzxb₂ laves phase c15 system - the superconducting ce₁₋xlaxru₂ alloy
author Robouch, B.V.
Marcelli, A.
Saini, N.L.
Kisiel, A.
author_facet Robouch, B.V.
Marcelli, A.
Saini, N.L.
Kisiel, A.
topic XVII Уральская международная зимняя школа по физике полупроводников
topic_facet XVII Уральская международная зимняя школа по физике полупроводников
publishDate 2009
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description Local structure of Ce₁₋xLaxRu₂ system, measured by EXAFS has been re-examined and correlated to the statistical ad hoc model, recently applied to the sphalerite, wurtzite and other intermetallic ternary alloys. The deconvolution of the EXAFS data show that the Ce₁₋xLaxRu₂ ternary system is essentially a mixture of: CeRu₂ and LaRu₂ binary alloys with a small proportion of the Ce₀.₅La₀.₅Ru₂ ternary configuration, being maximum for the intermediate concentration. Moreover, the analysis reveals that while the LaRu₂ configuration exhibits a Bernoulli random distribution, the presence of a Ce atom affects both the CeRu₂ and Ce₀.₅La₀.₅Ru₂ distributions, strongly favoring the configuration with the CeCe pair, while keeping rare that with a single Ce ion.
url https://nasplib.isofts.kiev.ua/handle/123456789/116838
citation_txt Statistical model structure of A₁₋xZxB₂ Laves phase C15 system - the superconducting Ce₁₋xLaxRu₂ alloy / B.V. Robouch, A. Marcelli, N.L. Saini, A. Kisiel// Физика низких температур. — 2009. — Т. 35, № 1. — С. 116-121. — Бібліогр.: 28 назв. — англ.
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