The effect of n-H₂ impurity on the heat capacity of solid Ne

The alloy of Ne - 5.1%n-H₂ was investigated calorimetrically under equilibrium vapor pressure in an interval of 0.9–25 K. The magnitudes and the temperatures dependencies of the heat capacity Cso₁(T) of the alloy at T = 11–20 K are strongly dependent on the conditions of sample preparation. The temp...

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Published in:Физика низких температур
Date:2009
Main Authors: Bagatskii, M.I., Minchina, I.Ya., Parbuzin, V.S.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2009
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/116989
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:The effect of n-H₂ impurity on the heat capacity of solid Ne / M.I. Bagatskii, I.Ya. Minchina, V.S. Parbuzin // Физика низких температур. — 2009. — Т. 35, № 2. — С. 204-207. — Бібліогр.: 20 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-116989
record_format dspace
spelling Bagatskii, M.I.
Minchina, I.Ya.
Parbuzin, V.S.
2017-05-18T17:32:21Z
2017-05-18T17:32:21Z
2009
The effect of n-H₂ impurity on the heat capacity of solid Ne / M.I. Bagatskii, I.Ya. Minchina, V.S. Parbuzin // Физика низких температур. — 2009. — Т. 35, № 2. — С. 204-207. — Бібліогр.: 20 назв. — англ.
PACS: 65.40.Ba., 65.60.+a., 65.40.–b., 63.50.+x.
https://nasplib.isofts.kiev.ua/handle/123456789/116989
The alloy of Ne - 5.1%n-H₂ was investigated calorimetrically under equilibrium vapor pressure in an interval of 0.9–25 K. The magnitudes and the temperatures dependencies of the heat capacity Cso₁(T) of the alloy at T = 11–20 K are strongly dependent on the conditions of sample preparation. The temperatures dependencies of the Cso₁(T) of the sample prepared in a calorimeter by direct condensation of a gas mixture at T = 15 K exhibit a smeared maximum near the triple point temperature of hydrogen and a phase transition at T = 17.1 K. The detected features of Cso₁(T) indicate that the preparation of the solid Ne – n-H₂ from a gas phase leads to the formation of a nonequilibrium long-living phase Ne with large H₂ concentrations and a small portion of H₂ inclusions with low Ne concentrations. The phase transition is caused by decompositions of this phase. The phase dose not recover on cooling the sample after the phase transition. It is found that the rate of the ortho-para conversion of the H₂ molecules in the solid Ne – n-H₂ solutions higher than that of solid H₂.
The authors are indebted to A.I. Prokhvatilov, and M.A. Strzhemechny for helpful discussions.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Физические свойства криокристаллов
The effect of n-H₂ impurity on the heat capacity of solid Ne
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title The effect of n-H₂ impurity on the heat capacity of solid Ne
spellingShingle The effect of n-H₂ impurity on the heat capacity of solid Ne
Bagatskii, M.I.
Minchina, I.Ya.
Parbuzin, V.S.
Физические свойства криокристаллов
title_short The effect of n-H₂ impurity on the heat capacity of solid Ne
title_full The effect of n-H₂ impurity on the heat capacity of solid Ne
title_fullStr The effect of n-H₂ impurity on the heat capacity of solid Ne
title_full_unstemmed The effect of n-H₂ impurity on the heat capacity of solid Ne
title_sort effect of n-h₂ impurity on the heat capacity of solid ne
author Bagatskii, M.I.
Minchina, I.Ya.
Parbuzin, V.S.
author_facet Bagatskii, M.I.
Minchina, I.Ya.
Parbuzin, V.S.
topic Физические свойства криокристаллов
topic_facet Физические свойства криокристаллов
publishDate 2009
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description The alloy of Ne - 5.1%n-H₂ was investigated calorimetrically under equilibrium vapor pressure in an interval of 0.9–25 K. The magnitudes and the temperatures dependencies of the heat capacity Cso₁(T) of the alloy at T = 11–20 K are strongly dependent on the conditions of sample preparation. The temperatures dependencies of the Cso₁(T) of the sample prepared in a calorimeter by direct condensation of a gas mixture at T = 15 K exhibit a smeared maximum near the triple point temperature of hydrogen and a phase transition at T = 17.1 K. The detected features of Cso₁(T) indicate that the preparation of the solid Ne – n-H₂ from a gas phase leads to the formation of a nonequilibrium long-living phase Ne with large H₂ concentrations and a small portion of H₂ inclusions with low Ne concentrations. The phase transition is caused by decompositions of this phase. The phase dose not recover on cooling the sample after the phase transition. It is found that the rate of the ortho-para conversion of the H₂ molecules in the solid Ne – n-H₂ solutions higher than that of solid H₂.
url https://nasplib.isofts.kiev.ua/handle/123456789/116989
citation_txt The effect of n-H₂ impurity on the heat capacity of solid Ne / M.I. Bagatskii, I.Ya. Minchina, V.S. Parbuzin // Физика низких температур. — 2009. — Т. 35, № 2. — С. 204-207. — Бібліогр.: 20 назв. — англ.
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