Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex
A new method to determine the absolute pressure in an ultra-high vacuum apparatus is tested using ion molecule reactions with CoAr₆⁺. In a collision with a neutral reactant, the complex between Co⁺ and the collision partner is stabilized by evaporation of argon atoms. If CoAr₆⁺ reacts with collision...
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| Veröffentlicht in: | Физика низких температур |
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| Datum: | 2010 |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2010
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Zitieren: | Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex / C. van der Linde, R.F. Höckendorf, O.P. Balaj, M.K. Beyer // Физика низких температур. — 2010. — Т. 36, № 5. — С. 516-523. — Бібліогр.: 63 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862708641022345216 |
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| author | Linde, C. van der Höckendorf, R.F. Balaj, O.P. Beyer, M.K. |
| author_facet | Linde, C. van der Höckendorf, R.F. Balaj, O.P. Beyer, M.K. |
| citation_txt | Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex / C. van der Linde, R.F. Höckendorf, O.P. Balaj, M.K. Beyer // Физика низких температур. — 2010. — Т. 36, № 5. — С. 516-523. — Бібліогр.: 63 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | A new method to determine the absolute pressure in an ultra-high vacuum apparatus is tested using ion molecule reactions with CoAr₆⁺. In a collision with a neutral reactant, the complex between Co⁺ and the collision partner is stabilized by evaporation of argon atoms. If CoAr₆⁺ reacts with collision rate, the absolute pressure can be determined by comparing the experimental collision rate with the collision rate calculated from average dipole orientation theory. The experimental results with N₂O, NO, and NO₂ indeed show that the collision complex is frozen out. Comparison of the rates of primary, secondary and tertiary reaction products, however, suggests that not all collisions of CoAr₆⁺ are reactive.
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| first_indexed | 2025-12-07T17:12:04Z |
| format | Article |
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| id | nasplib_isofts_kiev_ua-123456789-117041 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-12-07T17:12:04Z |
| publishDate | 2010 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Linde, C. van der Höckendorf, R.F. Balaj, O.P. Beyer, M.K. 2017-05-19T09:10:00Z 2017-05-19T09:10:00Z 2010 Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex / C. van der Linde, R.F. Höckendorf, O.P. Balaj, M.K. Beyer // Физика низких температур. — 2010. — Т. 36, № 5. — С. 516-523. — Бібліогр.: 63 назв. — англ. 0132-6414 PACS: 82.30.Fi https://nasplib.isofts.kiev.ua/handle/123456789/117041 A new method to determine the absolute pressure in an ultra-high vacuum apparatus is tested using ion molecule reactions with CoAr₆⁺. In a collision with a neutral reactant, the complex between Co⁺ and the collision partner is stabilized by evaporation of argon atoms. If CoAr₆⁺ reacts with collision rate, the absolute pressure can be determined by comparing the experimental collision rate with the collision rate calculated from average dipole orientation theory. The experimental results with N₂O, NO, and NO₂ indeed show that the collision complex is frozen out. Comparison of the rates of primary, secondary and tertiary reaction products, however, suggests that not all collisions of CoAr₆⁺ are reactive. Financial support from the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie is gratefully acknowledged. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Nanostructures and Impurity Centers in Cryogenic Environment Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex Article published earlier |
| spellingShingle | Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex Linde, C. van der Höckendorf, R.F. Balaj, O.P. Beyer, M.K. Nanostructures and Impurity Centers in Cryogenic Environment |
| title | Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex |
| title_full | Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex |
| title_fullStr | Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex |
| title_full_unstemmed | Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex |
| title_short | Ion–molecule reactions of CoAr₆⁺ with nitrogen oxides N₂O, NO, and NO₂: measuring absolute pressure by shock-freezing of the collision complex |
| title_sort | ion–molecule reactions of coar₆⁺ with nitrogen oxides n₂o, no, and no₂: measuring absolute pressure by shock-freezing of the collision complex |
| topic | Nanostructures and Impurity Centers in Cryogenic Environment |
| topic_facet | Nanostructures and Impurity Centers in Cryogenic Environment |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/117041 |
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