Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton
Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines f...
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| Опубліковано в: : | Физика низких температур |
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| Дата: | 2010 |
| Автори: | , , , |
| Формат: | Стаття |
| Мова: | Англійська |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2010
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/117042 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862558112992460800 |
|---|---|
| author | Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. |
| author_facet | Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. |
| citation_txt | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines for individual spin-orbit J states of the a⁶D←a⁶S transition recorded with laser-induced excitation spectroscopy. Excellent agreement exists between the predicted crystal field splitting patterns for the J levels of the a⁶D state isolated in the «red» tetravacancy site of solid Kr. The tetrahedral crystal field of the «red» trapping site splits J>3/2 levels of the a⁶DJ and a⁴D₇/₂ states by approximately 30 cm⁻¹. This report represents the first definitive evidence of crystal field splitting, induced by the weak van der Waals interactions between a neutral metal atom and the rare gas atoms surrounding it in a well defined solid state site.
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| first_indexed | 2025-11-25T22:43:37Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-117042 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-11-25T22:43:37Z |
| publishDate | 2010 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. 2017-05-19T09:11:28Z 2017-05-19T09:11:28Z 2010 Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. 0132-6414 PACS: 31.70.Dk, 78.40.–q, 78.55.–m https://nasplib.isofts.kiev.ua/handle/123456789/117042 Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines for individual spin-orbit J states of the a⁶D←a⁶S transition recorded with laser-induced excitation spectroscopy. Excellent agreement exists between the predicted crystal field splitting patterns for the J levels of the a⁶D state isolated in the «red» tetravacancy site of solid Kr. The tetrahedral crystal field of the «red» trapping site splits J>3/2 levels of the a⁶DJ and a⁴D₇/₂ states by approximately 30 cm⁻¹. This report represents the first definitive evidence of crystal field splitting, induced by the weak van der Waals interactions between a neutral metal atom and the rare gas atoms surrounding it in a well defined solid state site. This research was funded by the Irish Government Enterprise Ireland, SC/98/403 Basic Science research grant to whom MC gratefully acknowledges receipt of a Ph.D. studentship. The iCCD camera used in this work was acquired with the financial support of Science Foundation Ireland (SFI), Investigator grant 02/IN.1/B032. OB gratefully acknowledges the award of a Ph.D. studentship from Embark Initiative Irish Research Council for Science and Engineering (IRCSET) and a John & Pat Hume scholarship from N.U.I. - Maynooth. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Nanostructures and Impurity Centers in Cryogenic Environment Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton Article published earlier |
| spellingShingle | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. Nanostructures and Impurity Centers in Cryogenic Environment |
| title | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_full | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_fullStr | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_full_unstemmed | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_short | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_sort | crystal field splitting on d↔s transitions of atomic manganese isolated in solid krypton |
| topic | Nanostructures and Impurity Centers in Cryogenic Environment |
| topic_facet | Nanostructures and Impurity Centers in Cryogenic Environment |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/117042 |
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