Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton
Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines f...
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2010
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| Zitieren: | Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. |
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nasplib_isofts_kiev_ua-123456789-1170422025-02-09T11:56:29Z Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. Nanostructures and Impurity Centers in Cryogenic Environment Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines for individual spin-orbit J states of the a⁶D←a⁶S transition recorded with laser-induced excitation spectroscopy. Excellent agreement exists between the predicted crystal field splitting patterns for the J levels of the a⁶D state isolated in the «red» tetravacancy site of solid Kr. The tetrahedral crystal field of the «red» trapping site splits J>3/2 levels of the a⁶DJ and a⁴D₇/₂ states by approximately 30 cm⁻¹. This report represents the first definitive evidence of crystal field splitting, induced by the weak van der Waals interactions between a neutral metal atom and the rare gas atoms surrounding it in a well defined solid state site. This research was funded by the Irish Government Enterprise Ireland, SC/98/403 Basic Science research grant to whom MC gratefully acknowledges receipt of a Ph.D. studentship. The iCCD camera used in this work was acquired with the financial support of Science Foundation Ireland (SFI), Investigator grant 02/IN.1/B032. OB gratefully acknowledges the award of a Ph.D. studentship from Embark Initiative Irish Research Council for Science and Engineering (IRCSET) and a John & Pat Hume scholarship from N.U.I. - Maynooth. 2010 Article Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. 0132-6414 PACS: 31.70.Dk, 78.40.–q, 78.55.–m https://nasplib.isofts.kiev.ua/handle/123456789/117042 en Физика низких температур application/pdf Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
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| language |
English |
| topic |
Nanostructures and Impurity Centers in Cryogenic Environment Nanostructures and Impurity Centers in Cryogenic Environment |
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Nanostructures and Impurity Centers in Cryogenic Environment Nanostructures and Impurity Centers in Cryogenic Environment Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton Физика низких температур |
| description |
Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines for individual spin-orbit J states of the a⁶D←a⁶S transition recorded with laser-induced excitation spectroscopy. Excellent agreement exists between the predicted crystal field splitting patterns for the J levels of the a⁶D state isolated in the «red» tetravacancy site of solid Kr. The tetrahedral crystal field of the «red» trapping site splits J>3/2 levels of the a⁶DJ and a⁴D₇/₂ states by approximately 30 cm⁻¹. This report represents the first definitive evidence of crystal field splitting, induced by the weak van der Waals interactions between a neutral metal atom and the rare gas atoms surrounding it in a well defined solid state site. |
| format |
Article |
| author |
Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. |
| author_facet |
Byrne, O. Collier, M.A. Ryan, M.C. McCaffrey, J.G. |
| author_sort |
Byrne, O. |
| title |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_short |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_full |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_fullStr |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_full_unstemmed |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton |
| title_sort |
crystal field splitting on d↔s transitions of atomic manganese isolated in solid krypton |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| publishDate |
2010 |
| topic_facet |
Nanostructures and Impurity Centers in Cryogenic Environment |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/117042 |
| citation_txt |
Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton / O. Byrne, M.A. Collier, M.C. Ryan, J.G. McCaffrey // Физика низких температур. — 2010. — Т. 36, № 5. — С. 524-531. — Бібліогр.: 13 назв. — англ. |
| series |
Физика низких температур |
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2025-11-25T22:43:37Z |
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