Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article)

We review results of theoretical and experimental studies of charge transfer (CT) transitions in multiferroic manganites, ferrites, and related insulators. Starting with a simple cluster model approach we address both onecenter p–d and two-center d–d CT transitions, their polarization properties, th...

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Veröffentlicht in:Физика низких температур
Datum:2010
Hauptverfasser: Moskvin, A.S., Pisarev, R.V.
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Sprache:Englisch
Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2010
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/117048
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Zitieren:Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article) / A.S. Moskvin, R.V. Pisarev // Физика низких температур. — 2010. — Т. 36, № 6. — С. 613-639. — Бібліогр.: 102 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Moskvin, A.S.
Pisarev, R.V.
author_facet Moskvin, A.S.
Pisarev, R.V.
citation_txt Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article) / A.S. Moskvin, R.V. Pisarev // Физика низких температур. — 2010. — Т. 36, № 6. — С. 613-639. — Бібліогр.: 102 назв. — англ.
collection DSpace DC
container_title Физика низких температур
description We review results of theoretical and experimental studies of charge transfer (CT) transitions in multiferroic manganites, ferrites, and related insulators. Starting with a simple cluster model approach we address both onecenter p–d and two-center d–d CT transitions, their polarization properties, the role played by structural parameters, orbital mixing, and spin degree of freedom. We analyze optical ellipsometry data in the spectral range of 0.6–5.8 eV in perovskite and hexagonal rare-earth manganites RMnO₃ and in orthorhombic manganites RMn₂O₅. We discuss two groups of iron oxides where Fe³⁺ ions occupy either only octahedral positions (BiFeO₃, orhoferrites RFeO₃ et al.) and materials with Fe³⁺ ions both in octahedral and tetrahedral positions (hematite α-Fe₂O₃, garnets RFe₅O₁₂, lithium ferrite LiFe₅O₈, Ca₂Fe₂O₅ et al.).
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language English
last_indexed 2025-12-07T18:17:21Z
publishDate 2010
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
record_format dspace
spelling Moskvin, A.S.
Pisarev, R.V.
2017-05-19T09:32:48Z
2017-05-19T09:32:48Z
2010
Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article) / A.S. Moskvin, R.V. Pisarev // Физика низких температур. — 2010. — Т. 36, № 6. — С. 613-639. — Бібліогр.: 102 назв. — англ.
0132-6414
PACS: 78.20.Bh, 78.20.Ci, 75.50.Ee, 77.80.–e
https://nasplib.isofts.kiev.ua/handle/123456789/117048
We review results of theoretical and experimental studies of charge transfer (CT) transitions in multiferroic manganites, ferrites, and related insulators. Starting with a simple cluster model approach we address both onecenter p–d and two-center d–d CT transitions, their polarization properties, the role played by structural parameters, orbital mixing, and spin degree of freedom. We analyze optical ellipsometry data in the spectral range of 0.6–5.8 eV in perovskite and hexagonal rare-earth manganites RMnO₃ and in orthorhombic manganites RMn₂O₅. We discuss two groups of iron oxides where Fe³⁺ ions occupy either only octahedral positions (BiFeO₃, orhoferrites RFeO₃ et al.) and materials with Fe³⁺ ions both in octahedral and tetrahedral positions (hematite α-Fe₂O₃, garnets RFe₅O₁₂, lithium ferrite LiFe₅O₈, Ca₂Fe₂O₅ et al.).
This work is supported in part by the Russian Foundation for Basic Research and State Contract No. 02.740.11.0384.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Магнитоэлектрические эффекты в сегнетомагнетиках
Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article)
Article
published earlier
spellingShingle Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article)
Moskvin, A.S.
Pisarev, R.V.
Магнитоэлектрические эффекты в сегнетомагнетиках
title Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article)
title_full Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article)
title_fullStr Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article)
title_full_unstemmed Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article)
title_short Optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (Review Article)
title_sort optical spectroscopy of charge transfer transitions in multiferroic manganites, ferrites, and related insulators (review article)
topic Магнитоэлектрические эффекты в сегнетомагнетиках
topic_facet Магнитоэлектрические эффекты в сегнетомагнетиках
url https://nasplib.isofts.kiev.ua/handle/123456789/117048
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AT pisarevrv opticalspectroscopyofchargetransfertransitionsinmultiferroicmanganitesferritesandrelatedinsulatorsreviewarticle