Phase transitions in clusters

General concepts of cluster phase transitions are reviewed as well as the cluster behavior near the melting point. Configuration excitation determines the nature of the cluster phase transitions, but a significant contribution to the entropy jump is given by thermal motion of atoms that allows one t...

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Опубліковано в: :Физика низких температур
Дата:2009
Автори: Berry, R.S., Smirnov, B.M.
Формат: Стаття
Мова:English
Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2009
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Онлайн доступ:https://nasplib.isofts.kiev.ua/handle/123456789/117105
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Phase transitions in clusters / R.S. Berry, B.M. Smirnov // Физика низких температур. — 2009. — Т. 35, № 4. — С. 339-349. — Бібліогр.: 47 назв. — англ.

Репозитарії

Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-117105
record_format dspace
spelling Berry, R.S.
Smirnov, B.M.
2017-05-19T19:20:18Z
2017-05-19T19:20:18Z
2009
Phase transitions in clusters / R.S. Berry, B.M. Smirnov // Физика низких температур. — 2009. — Т. 35, № 4. — С. 339-349. — Бібліогр.: 47 назв. — англ.
0132-6414
PACS: 36.40.Ei, 61.72.J–, 64.70.D–, 64.70.P–
https://nasplib.isofts.kiev.ua/handle/123456789/117105
General concepts of cluster phase transitions are reviewed as well as the cluster behavior near the melting point. Configuration excitation determines the nature of the cluster phase transitions, but a significant contribution to the entropy jump is given by thermal motion of atoms that allows one to characterize the phase transition through thermal atom motion in the Lindemann and other criteria. The phase coexistence near the melting point is the peculiarity of not large clusters. The void concept of phase transitions with a void as an elementary configuration excitation allows one to describe the phase transition for clusters and macroscopic atomic systems. Phase transitions in metal clusters resemble those in clusters with pairwise atomic interactions, but their numerical parameters are other because of a large number of isomers and an additional electron degree of freedom. Cluster models are convenient for the analysis of macroscopic atomic systems. They allow us to understand the nature of glassy transitions and the reason of absence of a stable infinite crystal lattice for gases at zero temperature and high pressure.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
7th International Conference on Cryocrystals and Quantum Crystals
Phase transitions in clusters
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Phase transitions in clusters
spellingShingle Phase transitions in clusters
Berry, R.S.
Smirnov, B.M.
7th International Conference on Cryocrystals and Quantum Crystals
title_short Phase transitions in clusters
title_full Phase transitions in clusters
title_fullStr Phase transitions in clusters
title_full_unstemmed Phase transitions in clusters
title_sort phase transitions in clusters
author Berry, R.S.
Smirnov, B.M.
author_facet Berry, R.S.
Smirnov, B.M.
topic 7th International Conference on Cryocrystals and Quantum Crystals
topic_facet 7th International Conference on Cryocrystals and Quantum Crystals
publishDate 2009
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description General concepts of cluster phase transitions are reviewed as well as the cluster behavior near the melting point. Configuration excitation determines the nature of the cluster phase transitions, but a significant contribution to the entropy jump is given by thermal motion of atoms that allows one to characterize the phase transition through thermal atom motion in the Lindemann and other criteria. The phase coexistence near the melting point is the peculiarity of not large clusters. The void concept of phase transitions with a void as an elementary configuration excitation allows one to describe the phase transition for clusters and macroscopic atomic systems. Phase transitions in metal clusters resemble those in clusters with pairwise atomic interactions, but their numerical parameters are other because of a large number of isomers and an additional electron degree of freedom. Cluster models are convenient for the analysis of macroscopic atomic systems. They allow us to understand the nature of glassy transitions and the reason of absence of a stable infinite crystal lattice for gases at zero temperature and high pressure.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/117105
citation_txt Phase transitions in clusters / R.S. Berry, B.M. Smirnov // Физика низких температур. — 2009. — Т. 35, № 4. — С. 339-349. — Бібліогр.: 47 назв. — англ.
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