Transient HDO rovibrational satellite peaks in solid parahydrogen: evidence of hydrogen atoms or vacancies?

• Published in: Физика низких температур
• Date: 2012
• Main Authors: Wonderly, W.R., Anderson, D.T.
• Format: Article
• Language: English
• Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2012
• Subjects: Low Temperature Spectroscopy and Radiation Effects
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/117419
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Transient HDO rovibrational satellite peaks in solid parahydrogen: evidence of hydrogen atoms or vacancies? / W.R. Wonderly , D.T. Anderson // Физика низких температур. — 2012. — Т. 38, № 8. — С. 853-859. — Бібліогр.: 31 назв. — англ.

We present FTIR studies of the 193 nm photolysis of fully deuterated formic acid (DCOOD) isolated in solid parahydrogen at 1.9 K which show evidence of transient HDO rovibrational satellite peaks. The S1 and S2 satellite peaks are readily detected for α-type (1₀₁ ← 0₀₀) rovibrational transitions...