Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films

The change of an electronic absorption coefficient of polymer films, doped by symmetric cationic polymethine dye is researched in an external constant electric field. This effect are characterised by an increase of intensity on the shortwave edge of a band and its decrease at the longwave edge. The...

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Veröffentlicht in:Semiconductor Physics Quantum Electronics & Optoelectronics
Datum:2003
Hauptverfasser: Davidenko, N.A., Chuprin, N.G., Zabolotny, M.A., Derevyanko, N.A., Ishchenko, A.A.
Format: Artikel
Sprache:Englisch
Veröffentlicht: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2003
Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/117999
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films / N.A. Davidenko, N.G. Chuprin, M.A. Zabolotny, N.A. Derevyanko, A.A. Ishchenko // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2003. — Т. 6, № 2. — С. 217-222. — Бібліогр.: 12 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Davidenko, N.A.
Chuprin, N.G.
Zabolotny, M.A.
Derevyanko, N.A.
Ishchenko, A.A.
author_facet Davidenko, N.A.
Chuprin, N.G.
Zabolotny, M.A.
Derevyanko, N.A.
Ishchenko, A.A.
citation_txt Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films / N.A. Davidenko, N.G. Chuprin, M.A. Zabolotny, N.A. Derevyanko, A.A. Ishchenko // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2003. — Т. 6, № 2. — С. 217-222. — Бібліогр.: 12 назв. — англ.
collection DSpace DC
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
description The change of an electronic absorption coefficient of polymer films, doped by symmetric cationic polymethine dye is researched in an external constant electric field. This effect are characterised by an increase of intensity on the shortwave edge of a band and its decrease at the longwave edge. The charge distribution in dye cation in the model electric field 10⁷-10⁸ V/m of point charges and capacitor was calculated by the method AM1. Based on quantum chemical calculations, the spectral regularities in the electric field is interpreted by a change of the electronic charge value on the cation. The theoretical model based on changes of the value of eigenfrequencies inherent to charged anharmonic oscillators under the operation field is offered for the description of observed effects. The experimental spectra correlate well with those calculated theoretically.
first_indexed 2025-12-02T10:51:37Z
format Article
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id nasplib_isofts_kiev_ua-123456789-117999
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn 1560-8034
language English
last_indexed 2025-12-02T10:51:37Z
publishDate 2003
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
record_format dspace
spelling Davidenko, N.A.
Chuprin, N.G.
Zabolotny, M.A.
Derevyanko, N.A.
Ishchenko, A.A.
2017-05-28T05:44:14Z
2017-05-28T05:44:14Z
2003
Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films / N.A. Davidenko, N.G. Chuprin, M.A. Zabolotny, N.A. Derevyanko, A.A. Ishchenko // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2003. — Т. 6, № 2. — С. 217-222. — Бібліогр.: 12 назв. — англ.
1560-8034
PACS: 72.80.L, 73.61.J, 78.66.J
https://nasplib.isofts.kiev.ua/handle/123456789/117999
The change of an electronic absorption coefficient of polymer films, doped by symmetric cationic polymethine dye is researched in an external constant electric field. This effect are characterised by an increase of intensity on the shortwave edge of a band and its decrease at the longwave edge. The charge distribution in dye cation in the model electric field 10⁷-10⁸ V/m of point charges and capacitor was calculated by the method AM1. Based on quantum chemical calculations, the spectral regularities in the electric field is interpreted by a change of the electronic charge value on the cation. The theoretical model based on changes of the value of eigenfrequencies inherent to charged anharmonic oscillators under the operation field is offered for the description of observed effects. The experimental spectra correlate well with those calculated theoretically.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films
Article
published earlier
spellingShingle Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films
Davidenko, N.A.
Chuprin, N.G.
Zabolotny, M.A.
Derevyanko, N.A.
Ishchenko, A.A.
title Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films
title_full Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films
title_fullStr Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films
title_full_unstemmed Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films
title_short Effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films
title_sort effect of constant electric field on electronic absorption spectra of dye-doped amorphous polymer films
url https://nasplib.isofts.kiev.ua/handle/123456789/117999
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AT zabolotnyma effectofconstantelectricfieldonelectronicabsorptionspectraofdyedopedamorphouspolymerfilms
AT derevyankona effectofconstantelectricfieldonelectronicabsorptionspectraofdyedopedamorphouspolymerfilms
AT ishchenkoaa effectofconstantelectricfieldonelectronicabsorptionspectraofdyedopedamorphouspolymerfilms