Peculiarities of valence band formation in As-Ge-Se semiconductor glasses

Peculiarities of valence bands formation in As-Ge-Se semiconductor glasses have been investigated within AsxGexSe₁₋₂x cut of glass forming region by highresolution X-ray photoelectron spectroscopy (XPS). It is shown that compositional dependence of XPS valence band spectra of the investigated glasse...

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Published in:Semiconductor Physics Quantum Electronics & Optoelectronics
Date:2012
Main Authors: Vakiv, M., Golovchak, R., Chalyy, D., Shpotyuk, M., Ubizskii, S., Shpotyuk, O.
Format: Article
Language:English
Published: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2012
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/118244
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Peculiarities of valence band formation in As-Ge-Se semiconductor glasses / M. Vakiv, R. Golovchak, D. Chalyy, M. Shpotyuk, S. Ubizskii, O. Shpotyuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2012. — Т. 15, № 1. — С. 32-34. — Бібліогр.: 16 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-118244
record_format dspace
spelling Vakiv, M.
Golovchak, R.
Chalyy, D.
Shpotyuk, M.
Ubizskii, S.
Shpotyuk, O.
2017-05-29T13:49:02Z
2017-05-29T13:49:02Z
2012
Peculiarities of valence band formation in As-Ge-Se semiconductor glasses / M. Vakiv, R. Golovchak, D. Chalyy, M. Shpotyuk, S. Ubizskii, O. Shpotyuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2012. — Т. 15, № 1. — С. 32-34. — Бібліогр.: 16 назв. — англ.
1560-8034
PACS 61.43.Fs, 71.23.Cq
https://nasplib.isofts.kiev.ua/handle/123456789/118244
Peculiarities of valence bands formation in As-Ge-Se semiconductor glasses have been investigated within AsxGexSe₁₋₂x cut of glass forming region by highresolution X-ray photoelectron spectroscopy (XPS). It is shown that compositional dependence of XPS valence band spectra of the investigated glasses correlates well with previously obtained data for constituent glasses of binary GexSe₁₋x and AsxGe₁₋x systems. In particular, increase in х leads to the decrease in the intensity of bands at ~2 eV responsible for Se lp-states. The valley at ~3 eV is filled by electronic states originated from Se-GE and Se-As bonds. An accompanying decrease in the intensity of the band at ~5 eV is explained by a decrease in Se 4p bonding states associated with covalent bonds.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Peculiarities of valence band formation in As-Ge-Se semiconductor glasses
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Peculiarities of valence band formation in As-Ge-Se semiconductor glasses
spellingShingle Peculiarities of valence band formation in As-Ge-Se semiconductor glasses
Vakiv, M.
Golovchak, R.
Chalyy, D.
Shpotyuk, M.
Ubizskii, S.
Shpotyuk, O.
title_short Peculiarities of valence band formation in As-Ge-Se semiconductor glasses
title_full Peculiarities of valence band formation in As-Ge-Se semiconductor glasses
title_fullStr Peculiarities of valence band formation in As-Ge-Se semiconductor glasses
title_full_unstemmed Peculiarities of valence band formation in As-Ge-Se semiconductor glasses
title_sort peculiarities of valence band formation in as-ge-se semiconductor glasses
author Vakiv, M.
Golovchak, R.
Chalyy, D.
Shpotyuk, M.
Ubizskii, S.
Shpotyuk, O.
author_facet Vakiv, M.
Golovchak, R.
Chalyy, D.
Shpotyuk, M.
Ubizskii, S.
Shpotyuk, O.
publishDate 2012
language English
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
format Article
description Peculiarities of valence bands formation in As-Ge-Se semiconductor glasses have been investigated within AsxGexSe₁₋₂x cut of glass forming region by highresolution X-ray photoelectron spectroscopy (XPS). It is shown that compositional dependence of XPS valence band spectra of the investigated glasses correlates well with previously obtained data for constituent glasses of binary GexSe₁₋x and AsxGe₁₋x systems. In particular, increase in х leads to the decrease in the intensity of bands at ~2 eV responsible for Se lp-states. The valley at ~3 eV is filled by electronic states originated from Se-GE and Se-As bonds. An accompanying decrease in the intensity of the band at ~5 eV is explained by a decrease in Se 4p bonding states associated with covalent bonds.
issn 1560-8034
url https://nasplib.isofts.kiev.ua/handle/123456789/118244
citation_txt Peculiarities of valence band formation in As-Ge-Se semiconductor glasses / M. Vakiv, R. Golovchak, D. Chalyy, M. Shpotyuk, S. Ubizskii, O. Shpotyuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2012. — Т. 15, № 1. — С. 32-34. — Бібліогр.: 16 назв. — англ.
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AT shpotyukm peculiaritiesofvalencebandformationinasgesesemiconductorglasses
AT ubizskiis peculiaritiesofvalencebandformationinasgesesemiconductorglasses
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first_indexed 2025-12-01T10:02:35Z
last_indexed 2025-12-01T10:02:35Z
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