Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
In this paper we describe an unusual electrochemical phenomenon, namely cathodic corrosion of platinum. We show that all existing models of cathodic corrosion are inconsistent with our experimental observations. Therefore, we present a new model of cathodic corrosion, which is based on the assumpt...
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| Veröffentlicht in: | Физика низких температур |
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| Datum: | 2013 |
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| Sprache: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2013
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| Zitieren: | Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium / Yu.I. Yanson, A.I. Yanson // Физика низких температур. — 2013. — Т. 39, № 3. — С. 390–398. — Бібліогр.: 46 назв. — англ. |
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Yanson, Yu.I. Yanson, A.I. 2017-05-29T14:03:39Z 2017-05-29T14:03:39Z 2013 Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium / Yu.I. Yanson, A.I. Yanson // Физика низких температур. — 2013. — Т. 39, № 3. — С. 390–398. — Бібліогр.: 46 назв. — англ. 0132-6414 PACS: 82.45.Aa, 82.45.Bb, 82.30.–b https://nasplib.isofts.kiev.ua/handle/123456789/118252 In this paper we describe an unusual electrochemical phenomenon, namely cathodic corrosion of platinum. We show that all existing models of cathodic corrosion are inconsistent with our experimental observations. Therefore, we present a new model of cathodic corrosion, which is based on the assumption that metal anions are formed at the electrode surface during the corrosion process. These anionic species function as precursors for the formation of the final product of cathodic corrosion–metal nanoparticles. A.I.Y. and Yu.I.Y. acknowledge the Dutch NWO vidi grant and STW Valorization grant (project 12572), respectively. We thank F. Tichelaar (TU Delft) for TEM analysis, T. Oosterkamp for providing generous SEM access, P. Rodriguez and N. Garcia-Araez for useful discussions and suggestions. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур К 75-летию со дня рождения И. К. Янсона Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium |
| spellingShingle |
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium Yanson, Yu.I. Yanson, A.I. К 75-летию со дня рождения И. К. Янсона |
| title_short |
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium |
| title_full |
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium |
| title_fullStr |
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium |
| title_full_unstemmed |
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium |
| title_sort |
cathodic corrosion: part 1. mechanism of corrosion via formation of metal anions in aqueous medium |
| author |
Yanson, Yu.I. Yanson, A.I. |
| author_facet |
Yanson, Yu.I. Yanson, A.I. |
| topic |
К 75-летию со дня рождения И. К. Янсона |
| topic_facet |
К 75-летию со дня рождения И. К. Янсона |
| publishDate |
2013 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
In this paper we describe an unusual electrochemical phenomenon, namely cathodic corrosion of platinum.
We show that all existing models of cathodic corrosion are inconsistent with our experimental observations.
Therefore, we present a new model of cathodic corrosion, which is based on the assumption that metal anions are
formed at the electrode surface during the corrosion process. These anionic species function as precursors for the
formation of the final product of cathodic corrosion–metal nanoparticles.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/118252 |
| citation_txt |
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium / Yu.I. Yanson, A.I. Yanson // Физика низких температур. — 2013. — Т. 39, № 3. — С. 390–398. — Бібліогр.: 46 назв. — англ. |
| work_keys_str_mv |
AT yansonyui cathodiccorrosionpart1mechanismofcorrosionviaformationofmetalanionsinaqueousmedium AT yansonai cathodiccorrosionpart1mechanismofcorrosionviaformationofmetalanionsinaqueousmedium |
| first_indexed |
2025-12-07T13:17:42Z |
| last_indexed |
2025-12-07T13:17:42Z |
| _version_ |
1850855614401478656 |