Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium

In this paper we describe an unusual electrochemical phenomenon, namely cathodic corrosion of platinum.
 We show that all existing models of cathodic corrosion are inconsistent with our experimental observations.
 Therefore, we present a new model of cathodic corrosion, which is base...

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Published in:Физика низких температур
Date:2013
Main Authors: Yanson, Yu.I., Yanson, A.I.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2013
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/118252
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Cathodic corrosion: Part 1. Mechanism of corrosion
 via formation of metal anions in aqueous medium / Yu.I. Yanson, A.I. Yanson // Физика низких температур. — 2013. — Т. 39, № 3. — С. 390–398. — Бібліогр.: 46 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Yanson, Yu.I.
Yanson, A.I.
author_facet Yanson, Yu.I.
Yanson, A.I.
citation_txt Cathodic corrosion: Part 1. Mechanism of corrosion
 via formation of metal anions in aqueous medium / Yu.I. Yanson, A.I. Yanson // Физика низких температур. — 2013. — Т. 39, № 3. — С. 390–398. — Бібліогр.: 46 назв. — англ.
collection DSpace DC
container_title Физика низких температур
description In this paper we describe an unusual electrochemical phenomenon, namely cathodic corrosion of platinum.
 We show that all existing models of cathodic corrosion are inconsistent with our experimental observations.
 Therefore, we present a new model of cathodic corrosion, which is based on the assumption that metal anions are
 formed at the electrode surface during the corrosion process. These anionic species function as precursors for the
 formation of the final product of cathodic corrosion–metal nanoparticles.
first_indexed 2025-12-07T13:17:42Z
format Article
fulltext
id nasplib_isofts_kiev_ua-123456789-118252
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn 0132-6414
language English
last_indexed 2025-12-07T13:17:42Z
publishDate 2013
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
record_format dspace
spelling Yanson, Yu.I.
Yanson, A.I.
2017-05-29T14:03:39Z
2017-05-29T14:03:39Z
2013
Cathodic corrosion: Part 1. Mechanism of corrosion
 via formation of metal anions in aqueous medium / Yu.I. Yanson, A.I. Yanson // Физика низких температур. — 2013. — Т. 39, № 3. — С. 390–398. — Бібліогр.: 46 назв. — англ.
0132-6414
PACS: 82.45.Aa, 82.45.Bb, 82.30.–b
https://nasplib.isofts.kiev.ua/handle/123456789/118252
In this paper we describe an unusual electrochemical phenomenon, namely cathodic corrosion of platinum.
 We show that all existing models of cathodic corrosion are inconsistent with our experimental observations.
 Therefore, we present a new model of cathodic corrosion, which is based on the assumption that metal anions are
 formed at the electrode surface during the corrosion process. These anionic species function as precursors for the
 formation of the final product of cathodic corrosion–metal nanoparticles.
A.I.Y. and Yu.I.Y. acknowledge the Dutch NWO vidi
 grant and STW Valorization grant (project 12572), respectively.
 We thank F. Tichelaar (TU Delft) for TEM analysis,
 T. Oosterkamp for providing generous SEM access, P. Rodriguez
 and N. Garcia-Araez for useful discussions and suggestions.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
К 75-летию со дня рождения И. К. Янсона
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
Article
published earlier
spellingShingle Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
Yanson, Yu.I.
Yanson, A.I.
К 75-летию со дня рождения И. К. Янсона
title Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
title_full Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
title_fullStr Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
title_full_unstemmed Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
title_short Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
title_sort cathodic corrosion: part 1. mechanism of corrosion via formation of metal anions in aqueous medium
topic К 75-летию со дня рождения И. К. Янсона
topic_facet К 75-летию со дня рождения И. К. Янсона
url https://nasplib.isofts.kiev.ua/handle/123456789/118252
work_keys_str_mv AT yansonyui cathodiccorrosionpart1mechanismofcorrosionviaformationofmetalanionsinaqueousmedium
AT yansonai cathodiccorrosionpart1mechanismofcorrosionviaformationofmetalanionsinaqueousmedium