The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles

The heat capacity of bundles of closed-cap single-walled carbon nanotubes with one-dimensional chains of nitrogen molecules adsorbed in the grooves has been first experimentally studied at temperatures from 2 to 40 K using an adiabatic calorimeter. The contribution of nitrogen CN₂ to the total heat...

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Veröffentlicht in:Физика низких температур
Datum:2013
Hauptverfasser: Bagatskii, M.I., Barabashko, M.S., Sumarokov, V.V.
Format: Artikel
Sprache:Englisch
Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2013
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/118457
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Zitieren:The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles / M.I. Bagatskii, M.S. Barabashko, V.V. Sumarokov // Физика низких температур. — 2013. — Т. 39, № 5. — С. 568–573. — Бібліогр.: 65 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Bagatskii, M.I.
Barabashko, M.S.
Sumarokov, V.V.
author_facet Bagatskii, M.I.
Barabashko, M.S.
Sumarokov, V.V.
citation_txt The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles / M.I. Bagatskii, M.S. Barabashko, V.V. Sumarokov // Физика низких температур. — 2013. — Т. 39, № 5. — С. 568–573. — Бібліогр.: 65 назв. — англ.
collection DSpace DC
container_title Физика низких температур
description The heat capacity of bundles of closed-cap single-walled carbon nanotubes with one-dimensional chains of nitrogen molecules adsorbed in the grooves has been first experimentally studied at temperatures from 2 to 40 K using an adiabatic calorimeter. The contribution of nitrogen CN₂ to the total heat capacity has been separated. In the region 28 K the behavior of the curve CN₂(T) is qualitatively similar to the theoretical prediction of the phonon heat capacity of 1D chains of Kr atoms localized in the grooves of SWNT bundles. Below 3 K the de-pendence CN₂(Т) is linear. Above 8 K the dependence CN₂(Т) becomes steeper in comparison with the case of Kr atoms. This behavior of the heat capacity CN₂(Т) is due to the contribution of the rotational degrees of free-dom of the N₂ molecules.
first_indexed 2025-11-25T22:46:31Z
format Article
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn 0132-6414
language English
last_indexed 2025-11-25T22:46:31Z
publishDate 2013
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
record_format dspace
spelling Bagatskii, M.I.
Barabashko, M.S.
Sumarokov, V.V.
2017-05-30T11:49:48Z
2017-05-30T11:49:48Z
2013
The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles / M.I. Bagatskii, M.S. Barabashko, V.V. Sumarokov // Физика низких температур. — 2013. — Т. 39, № 5. — С. 568–573. — Бібліогр.: 65 назв. — англ.
0132-6414
PACS: 65.40.Ba, 65.80.–g, 68.65.–k, 81.07.De
https://nasplib.isofts.kiev.ua/handle/123456789/118457
The heat capacity of bundles of closed-cap single-walled carbon nanotubes with one-dimensional chains of nitrogen molecules adsorbed in the grooves has been first experimentally studied at temperatures from 2 to 40 K using an adiabatic calorimeter. The contribution of nitrogen CN₂ to the total heat capacity has been separated. In the region 28 K the behavior of the curve CN₂(T) is qualitatively similar to the theoretical prediction of the phonon heat capacity of 1D chains of Kr atoms localized in the grooves of SWNT bundles. Below 3 K the de-pendence CN₂(Т) is linear. Above 8 K the dependence CN₂(Т) becomes steeper in comparison with the case of Kr atoms. This behavior of the heat capacity CN₂(Т) is due to the contribution of the rotational degrees of free-dom of the N₂ molecules.
The authors are indebted to V.G. Manzhelii, M.A. Strzhemechny,
 K.A. Chishko, S.B. Feodosyev, E.S. Syrkin, E.V.
 Manzhelii, and I.A. Gospodarev for helpful discussions.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
9th International Conference on Cryocrystals and Quantum Crystals
The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles
Article
published earlier
spellingShingle The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles
Bagatskii, M.I.
Barabashko, M.S.
Sumarokov, V.V.
9th International Conference on Cryocrystals and Quantum Crystals
title The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles
title_full The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles
title_fullStr The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles
title_full_unstemmed The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles
title_short The heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles
title_sort heat capacity of nitrogen chain in grooves of single-walled carbon nanotube bundles
topic 9th International Conference on Cryocrystals and Quantum Crystals
topic_facet 9th International Conference on Cryocrystals and Quantum Crystals
url https://nasplib.isofts.kiev.ua/handle/123456789/118457
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