Low-temperature properties of monoalcohol glasses and crystals

We review and jointly discuss both earlier and recent experiments conducted by us on simple aliphatic glass-forming monoalcohols at low temperatures, including specific heat, thermal conductivity, Brillouin scattering and x-ray diffraction experiments. The family of simple monoalcohols constitutes a...

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Published in:Физика низких температур
Date:2013
Main Authors: Ramos, M.A., Hassaine, M., Kabtoul, B., Jiménez-Riobóo, R.J., Shmyt’ko, I.M., Krivchikov, A.I., Sharapova, I.V., Korolyuk, O.A.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2013
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/118459
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Low-temperature properties of monoalcohol glasses and crystals / M.A. Ramos, M. Hassaine, B. Kabtoul, R.J. Jiménez-Riobóo, I.M. Shmyt’ko, A.I. Krivchikov, I.V. Sharapova, O.A. Korolyuk // Физика низких температур. — 2013. — Т. 39, № 5. — С. 600–605. — Бібліогр.: 29 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-118459
record_format dspace
spelling Ramos, M.A.
Hassaine, M.
Kabtoul, B.
Jiménez-Riobóo, R.J.
Shmyt’ko, I.M.
Krivchikov, A.I.
Sharapova, I.V.
Korolyuk, O.A.
2017-05-30T11:51:32Z
2017-05-30T11:51:32Z
2013
Low-temperature properties of monoalcohol glasses and crystals / M.A. Ramos, M. Hassaine, B. Kabtoul, R.J. Jiménez-Riobóo, I.M. Shmyt’ko, A.I. Krivchikov, I.V. Sharapova, O.A. Korolyuk // Физика низких температур. — 2013. — Т. 39, № 5. — С. 600–605. — Бібліогр.: 29 назв. — англ.
0132-6414
PACS: 65.60.+a, 65.40.Ba, 66.70.Hk, 63.50.–x
https://nasplib.isofts.kiev.ua/handle/123456789/118459
We review and jointly discuss both earlier and recent experiments conducted by us on simple aliphatic glass-forming monoalcohols at low temperatures, including specific heat, thermal conductivity, Brillouin scattering and x-ray diffraction experiments. The family of simple monoalcohols constitutes an interesting model system to explore different relevant issues concerning molecular glass-forming liquids, low-temperature universal proper-ties of glasses, and even the glass transition phenomenon itself. More specifically, we discuss the role played by the molecular aspect ratio in vitrification/crystallization kinetics, the reported appearance of particular cases of polymorphism (in ethanol) and polyamorphism (in butanol), and especially the influence of position isomerism and the location of the hydrogen bond on the lattice dynamics and hence on the low-temperature universal prop-erties of glasses.
The Laboratorio de Bajas Temperaturas (UAM) is an associated unit with the ICMM-CSIC. This work was par-tially supported by the Spanish MINECO (FIS2011-23488 and Consolider Ingenio Molecular Nanoscience CSD2007-00010 program) and by the Comunidad de Madrid through program Nanobiomagnet (S2009/MAT-1726).
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
9th International Conference on Cryocrystals and Quantum Crystals
Low-temperature properties of monoalcohol glasses and crystals
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Low-temperature properties of monoalcohol glasses and crystals
spellingShingle Low-temperature properties of monoalcohol glasses and crystals
Ramos, M.A.
Hassaine, M.
Kabtoul, B.
Jiménez-Riobóo, R.J.
Shmyt’ko, I.M.
Krivchikov, A.I.
Sharapova, I.V.
Korolyuk, O.A.
9th International Conference on Cryocrystals and Quantum Crystals
title_short Low-temperature properties of monoalcohol glasses and crystals
title_full Low-temperature properties of monoalcohol glasses and crystals
title_fullStr Low-temperature properties of monoalcohol glasses and crystals
title_full_unstemmed Low-temperature properties of monoalcohol glasses and crystals
title_sort low-temperature properties of monoalcohol glasses and crystals
author Ramos, M.A.
Hassaine, M.
Kabtoul, B.
Jiménez-Riobóo, R.J.
Shmyt’ko, I.M.
Krivchikov, A.I.
Sharapova, I.V.
Korolyuk, O.A.
author_facet Ramos, M.A.
Hassaine, M.
Kabtoul, B.
Jiménez-Riobóo, R.J.
Shmyt’ko, I.M.
Krivchikov, A.I.
Sharapova, I.V.
Korolyuk, O.A.
topic 9th International Conference on Cryocrystals and Quantum Crystals
topic_facet 9th International Conference on Cryocrystals and Quantum Crystals
publishDate 2013
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description We review and jointly discuss both earlier and recent experiments conducted by us on simple aliphatic glass-forming monoalcohols at low temperatures, including specific heat, thermal conductivity, Brillouin scattering and x-ray diffraction experiments. The family of simple monoalcohols constitutes an interesting model system to explore different relevant issues concerning molecular glass-forming liquids, low-temperature universal proper-ties of glasses, and even the glass transition phenomenon itself. More specifically, we discuss the role played by the molecular aspect ratio in vitrification/crystallization kinetics, the reported appearance of particular cases of polymorphism (in ethanol) and polyamorphism (in butanol), and especially the influence of position isomerism and the location of the hydrogen bond on the lattice dynamics and hence on the low-temperature universal prop-erties of glasses.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/118459
citation_txt Low-temperature properties of monoalcohol glasses and crystals / M.A. Ramos, M. Hassaine, B. Kabtoul, R.J. Jiménez-Riobóo, I.M. Shmyt’ko, A.I. Krivchikov, I.V. Sharapova, O.A. Korolyuk // Физика низких температур. — 2013. — Т. 39, № 5. — С. 600–605. — Бібліогр.: 29 назв. — англ.
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