Deuteration effects in the thermal conductivity of molecular glasses
The thermal conductivity κ(T) of pure deuterated ethanol has been measured under its equilibrium vapor pressure in its orientationally-ordered crystal (T = 2 K – Tm), orientational glass and the glass state (T = 2 K – Tg, Tg is the glass transition temperature) solid phases. The temperature dependen...
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| Опубліковано в: : | Физика низких температур |
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| Дата: | 2011 |
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| Формат: | Стаття |
| Мова: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2011
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Deuteration effects in the thermal conductivity of molecular glasses / A.I. Krivchikov, F.J. Bermejo, I.V. Sharapova, O.A. Korolyuk, O.O. Romantsova // Физика низких температур. — 2011. — Т. 37, № 6. — С. 651–658. — Бібліогр.: 31 назв. — англ. |
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Krivchikov, A.I. Bermejo, F.J. Sharapova, I.V. Korolyuk, O.A. Romantsova, O.O. 2017-05-30T16:55:52Z 2017-05-30T16:55:52Z 2011 Deuteration effects in the thermal conductivity of molecular glasses / A.I. Krivchikov, F.J. Bermejo, I.V. Sharapova, O.A. Korolyuk, O.O. Romantsova // Физика низких температур. — 2011. — Т. 37, № 6. — С. 651–658. — Бібліогр.: 31 назв. — англ. 0132-6414 Deuteration effects in the thermal conductivity of molecular glasses / A.I. Krivchikov, F.J. Bermejo, I.V. Sharapova, O.A. Korolyuk, O.O. Romantsova // Физика низких температур. — 2011. — Т. 37, № 6. — С. 651–658. — Бібліогр.: 31 назв. — англ. https://nasplib.isofts.kiev.ua/handle/123456789/118586 The thermal conductivity κ(T) of pure deuterated ethanol has been measured under its equilibrium vapor pressure in its orientationally-ordered crystal (T = 2 K – Tm), orientational glass and the glass state (T = 2 K – Tg, Tg is the glass transition temperature) solid phases. The temperature dependence of the conductivity is well described by a sum of two contributions: κ(T) = κI(T) + κII(T), where κI(T) account for the heat transport by acoustic phonons and κII(T) for the heat transfer by localized high-frequency excitations respectively. The thermal conductivities of deuterated and hydrogenated ethanols are compared in different phases. The phonon scattering mechanisms in the glasses have been analyzed. In the investigated glasses the effect of complete deuteration shows up as a contribution κII(T). The authors are sincerely grateful to V.A. Konstantinov, V.G. Manzhelii, and M.A Strzhemechny for helpful and fruitful discussion and interest in this study. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Квантовые эффекты в полупроводниках и диэлектриках Deuteration effects in the thermal conductivity of molecular glasses Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Deuteration effects in the thermal conductivity of molecular glasses |
| spellingShingle |
Deuteration effects in the thermal conductivity of molecular glasses Krivchikov, A.I. Bermejo, F.J. Sharapova, I.V. Korolyuk, O.A. Romantsova, O.O. Квантовые эффекты в полупроводниках и диэлектриках |
| title_short |
Deuteration effects in the thermal conductivity of molecular glasses |
| title_full |
Deuteration effects in the thermal conductivity of molecular glasses |
| title_fullStr |
Deuteration effects in the thermal conductivity of molecular glasses |
| title_full_unstemmed |
Deuteration effects in the thermal conductivity of molecular glasses |
| title_sort |
deuteration effects in the thermal conductivity of molecular glasses |
| author |
Krivchikov, A.I. Bermejo, F.J. Sharapova, I.V. Korolyuk, O.A. Romantsova, O.O. |
| author_facet |
Krivchikov, A.I. Bermejo, F.J. Sharapova, I.V. Korolyuk, O.A. Romantsova, O.O. |
| topic |
Квантовые эффекты в полупроводниках и диэлектриках |
| topic_facet |
Квантовые эффекты в полупроводниках и диэлектриках |
| publishDate |
2011 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
The thermal conductivity κ(T) of pure deuterated ethanol has been measured under its equilibrium vapor pressure in its orientationally-ordered crystal (T = 2 K – Tm), orientational glass and the glass state (T = 2 K – Tg, Tg is the glass transition temperature) solid phases. The temperature dependence of the conductivity is well described by a sum of two contributions: κ(T) = κI(T) + κII(T), where κI(T) account for the heat transport by acoustic phonons and κII(T) for the heat transfer by localized high-frequency excitations respectively. The thermal conductivities of deuterated and hydrogenated ethanols are compared in different phases. The phonon scattering mechanisms in the glasses have been analyzed. In the investigated glasses the effect of complete deuteration shows up as a contribution κII(T).
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/118586 |
| citation_txt |
Deuteration effects in the thermal conductivity of molecular glasses / A.I. Krivchikov, F.J. Bermejo, I.V. Sharapova, O.A. Korolyuk, O.O. Romantsova // Физика низких температур. — 2011. — Т. 37, № 6. — С. 651–658. — Бібліогр.: 31 назв. — англ. |
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