Structure and magnetism of copper substituted cobalt ludwigite Co₃O₂BO₃

The single crystals Co₃O₂BO₃ with partial (4%) substitution of Co by Cu ions were synthesized by the flux technique. X-ray diffraction and magnetic properties investigations were carried out. The x-ray diffraction meas-urements have shown that Cu clearly prefers only one from four nonequivalent crys...

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Published in:Физика низких температур
Date:2013
Main Authors: Ivanova, N.B., Kazak, N.V., Knyazev, Yu.V., Velikanov, D.A., Vasiliev, A.D., Bezmaternykh, L.N., Platunov, M.S.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2013
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/118672
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Structure and magnetism of copper substituted cobalt ludwigite Co₃O₂BO₃ / N.B. Ivanova, N.V. Kazak, Yu.V. Knyazev, D.A. Velikanov, A.D. Vasiliev, L.N. Bezmaternykh, M.S. Platunov // Физика низких температур. — 2013. — Т. 39, № 8. — С. 913–918. — Бібліогр.: 15 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Summary:The single crystals Co₃O₂BO₃ with partial (4%) substitution of Co by Cu ions were synthesized by the flux technique. X-ray diffraction and magnetic properties investigations were carried out. The x-ray diffraction meas-urements have shown that Cu clearly prefers only one from four nonequivalent crystallographic positions with the smallest electric field gradient. The ferrimagnetic ordering near TN = 43 K and high magnetic hardness in this magnetic phase are similar to Co₃O₂BO₃. The small reduction of the effective magnetic moment was revealed under copper substitution.
ISSN:0132-6414