Partial polarization switching in ferroelectrics-semiconductors with charged defects

We propose the phenomenological description of ferroelectric disordering caused by charged defects in ferroelectric-semiconductors. The good agreement between the obtained experimental results for PZT films and theoretical calculations has been shown. We suppose that proportional to the averaged ch...

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Veröffentlicht in:Semiconductor Physics Quantum Electronics & Optoelectronics
Datum:2004
Hauptverfasser: Morozovska, A.N., Eliseev, E.A., Cattan, E., Remiens, D.
Format: Artikel
Sprache:English
Veröffentlicht: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2004
Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/119120
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Partial polarization switching in ferroelectrics-semiconductors with charged defects / A.N. Morozovska, E.A. Eliseev, E. Cattan, D. Remiens // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2004. — Т. 7, № 3. — С. 251-262. — Бібліогр.: 25 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-119120
record_format dspace
spelling Morozovska, A.N.
Eliseev, E.A.
Cattan, E.
Remiens, D.
2017-06-04T15:57:10Z
2017-06-04T15:57:10Z
2004
Partial polarization switching in ferroelectrics-semiconductors with charged defects / A.N. Morozovska, E.A. Eliseev, E. Cattan, D. Remiens // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2004. — Т. 7, № 3. — С. 251-262. — Бібліогр.: 25 назв. — англ.
1560-8034
PACS: 77.80.-e, 77.80.Dj, 61.43.-j
https://nasplib.isofts.kiev.ua/handle/123456789/119120
We propose the phenomenological description of ferroelectric disordering caused by charged defects in ferroelectric-semiconductors. The good agreement between the obtained experimental results for PZT films and theoretical calculations has been shown. We suppose that proportional to the averaged charge density of defects improper conductivity is sufficiently high to provide the screening of charge density random fluctuations drs in the absence of external field. When external electric field is applied, inner field fluctuations and induction fluctuations dD appear in the inhomogeneously polarized system “charged fluctuation + screening cloud”. We show that the macroscopic state of ferroelectric-semiconductor with random charged defects and sufficiently high improper conductivity can be described by three coupled equations for three order parameters. Averaged over sample volume induction determines the ferroelectric ordering in the system, its square fluctuation determines disordering caused by electric field fluctuations appeared around charged fluctuations drs, and reflects the correlations between the free carriers screening cloud and charged defects drs. For the first time, we derive the following system of three coupled equations: Also the obtained system of coupled equations qualitatively describes the peculiarities of polarization switching (footprint and minor hysteresis loops) in such ferroelectric materials with charged defects as PZT films with growth imperfections, PLZT ceramics and SBN single crystals doped with cerium.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Partial polarization switching in ferroelectrics-semiconductors with charged defects
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Partial polarization switching in ferroelectrics-semiconductors with charged defects
spellingShingle Partial polarization switching in ferroelectrics-semiconductors with charged defects
Morozovska, A.N.
Eliseev, E.A.
Cattan, E.
Remiens, D.
title_short Partial polarization switching in ferroelectrics-semiconductors with charged defects
title_full Partial polarization switching in ferroelectrics-semiconductors with charged defects
title_fullStr Partial polarization switching in ferroelectrics-semiconductors with charged defects
title_full_unstemmed Partial polarization switching in ferroelectrics-semiconductors with charged defects
title_sort partial polarization switching in ferroelectrics-semiconductors with charged defects
author Morozovska, A.N.
Eliseev, E.A.
Cattan, E.
Remiens, D.
author_facet Morozovska, A.N.
Eliseev, E.A.
Cattan, E.
Remiens, D.
publishDate 2004
language English
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
format Article
description We propose the phenomenological description of ferroelectric disordering caused by charged defects in ferroelectric-semiconductors. The good agreement between the obtained experimental results for PZT films and theoretical calculations has been shown. We suppose that proportional to the averaged charge density of defects improper conductivity is sufficiently high to provide the screening of charge density random fluctuations drs in the absence of external field. When external electric field is applied, inner field fluctuations and induction fluctuations dD appear in the inhomogeneously polarized system “charged fluctuation + screening cloud”. We show that the macroscopic state of ferroelectric-semiconductor with random charged defects and sufficiently high improper conductivity can be described by three coupled equations for three order parameters. Averaged over sample volume induction determines the ferroelectric ordering in the system, its square fluctuation determines disordering caused by electric field fluctuations appeared around charged fluctuations drs, and reflects the correlations between the free carriers screening cloud and charged defects drs. For the first time, we derive the following system of three coupled equations: Also the obtained system of coupled equations qualitatively describes the peculiarities of polarization switching (footprint and minor hysteresis loops) in such ferroelectric materials with charged defects as PZT films with growth imperfections, PLZT ceramics and SBN single crystals doped with cerium.
issn 1560-8034
url https://nasplib.isofts.kiev.ua/handle/123456789/119120
fulltext
citation_txt Partial polarization switching in ferroelectrics-semiconductors with charged defects / A.N. Morozovska, E.A. Eliseev, E. Cattan, D. Remiens // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2004. — Т. 7, № 3. — С. 251-262. — Бібліогр.: 25 назв. — англ.
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first_indexed 2025-11-25T20:49:20Z
last_indexed 2025-11-25T20:49:20Z
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