Paramagnetic defects related to photoluminescence in SiOx films

The correlation between the photoluminescence and paramagnetic defects is studied in SiOx films grown by vacuum thermal deposition and annealed at 750 ⁰C. The as-grown samples exhibit a wide structureless EPR line centered at g = 2.0040, which is explained by the presence of a variety of dangling bo...

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Published in:Semiconductor Physics Quantum Electronics & Optoelectronics
Date:2004
Main Authors: Rudko, G.Yu., Vorona, I.P., Indutnyy, I.Z., Ishchenko, S.S., Shepeliavyi, P.E., Yukhymchuk, V.O.
Format: Article
Language:English
Published: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2004
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/119207
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Paramagnetic defects related to photoluminescence in SiOx films / G.Yu. Rudko, I.P. Vorona, I.Z. Indutnyy, S.S. Ishchenko, P.E. Shepeliavyi, V.O. Yukhymchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2004. — Т. 7, № 4. — С. 400-403. — Бібліогр.: 9 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-119207
record_format dspace
spelling Rudko, G.Yu.
Vorona, I.P.
Indutnyy, I.Z.
Ishchenko, S.S.
Shepeliavyi, P.E.
Yukhymchuk, V.O.
2017-06-05T09:24:14Z
2017-06-05T09:24:14Z
2004
Paramagnetic defects related to photoluminescence in SiOx films / G.Yu. Rudko, I.P. Vorona, I.Z. Indutnyy, S.S. Ishchenko, P.E. Shepeliavyi, V.O. Yukhymchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2004. — Т. 7, № 4. — С. 400-403. — Бібліогр.: 9 назв. — англ.
1560-8034
PACS: 76.70.Hb, 78.55.Hx, 78.66.Sq
https://nasplib.isofts.kiev.ua/handle/123456789/119207
The correlation between the photoluminescence and paramagnetic defects is studied in SiOx films grown by vacuum thermal deposition and annealed at 750 ⁰C. The as-grown samples exhibit a wide structureless EPR line centered at g = 2.0040, which is explained by the presence of a variety of dangling bonds •Si = SiyO₃–y. The annealing at 750 ⁰C causes the formation of amorphous silicon inclusions in SiOx matrix, appearance of the photoluminescence peaked at ~ 1.8 eV and shift of the EPR line to the low field range. The latter implies the preferable annealing of the paramagnetic defects in the regions of the sample with higher concentration of oxygen. The optically detected magnetic resonance studies show that these defects are not responsible for the luminescence; they are the centers of nonradiative recombination, but the efficiency of photoluminescence quenching due to these defects is rather low.
The authors are grateful to Prof. W.M. Chen and Prof. I.A. Buyanova for the possibility to carry out the ODMR experiments. This study was funded by the Programs of the National Academy of Sciences of Ukraine “Optical and spectroscopic investigations of semiconductors and semiconductor structures” and “Magnetic resonance and optical study of defects in semiconductors and dielectrics”.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Paramagnetic defects related to photoluminescence in SiOx films
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Paramagnetic defects related to photoluminescence in SiOx films
spellingShingle Paramagnetic defects related to photoluminescence in SiOx films
Rudko, G.Yu.
Vorona, I.P.
Indutnyy, I.Z.
Ishchenko, S.S.
Shepeliavyi, P.E.
Yukhymchuk, V.O.
title_short Paramagnetic defects related to photoluminescence in SiOx films
title_full Paramagnetic defects related to photoluminescence in SiOx films
title_fullStr Paramagnetic defects related to photoluminescence in SiOx films
title_full_unstemmed Paramagnetic defects related to photoluminescence in SiOx films
title_sort paramagnetic defects related to photoluminescence in siox films
author Rudko, G.Yu.
Vorona, I.P.
Indutnyy, I.Z.
Ishchenko, S.S.
Shepeliavyi, P.E.
Yukhymchuk, V.O.
author_facet Rudko, G.Yu.
Vorona, I.P.
Indutnyy, I.Z.
Ishchenko, S.S.
Shepeliavyi, P.E.
Yukhymchuk, V.O.
publishDate 2004
language English
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
format Article
description The correlation between the photoluminescence and paramagnetic defects is studied in SiOx films grown by vacuum thermal deposition and annealed at 750 ⁰C. The as-grown samples exhibit a wide structureless EPR line centered at g = 2.0040, which is explained by the presence of a variety of dangling bonds •Si = SiyO₃–y. The annealing at 750 ⁰C causes the formation of amorphous silicon inclusions in SiOx matrix, appearance of the photoluminescence peaked at ~ 1.8 eV and shift of the EPR line to the low field range. The latter implies the preferable annealing of the paramagnetic defects in the regions of the sample with higher concentration of oxygen. The optically detected magnetic resonance studies show that these defects are not responsible for the luminescence; they are the centers of nonradiative recombination, but the efficiency of photoluminescence quenching due to these defects is rather low.
issn 1560-8034
url https://nasplib.isofts.kiev.ua/handle/123456789/119207
citation_txt Paramagnetic defects related to photoluminescence in SiOx films / G.Yu. Rudko, I.P. Vorona, I.Z. Indutnyy, S.S. Ishchenko, P.E. Shepeliavyi, V.O. Yukhymchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2004. — Т. 7, № 4. — С. 400-403. — Бібліогр.: 9 назв. — англ.
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AT ishchenkoss paramagneticdefectsrelatedtophotoluminescenceinsioxfilms
AT shepeliavyipe paramagneticdefectsrelatedtophotoluminescenceinsioxfilms
AT yukhymchukvo paramagneticdefectsrelatedtophotoluminescenceinsioxfilms
first_indexed 2025-12-07T19:53:03Z
last_indexed 2025-12-07T19:53:03Z
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