IR spectroscopy of KBr salt and crystals

The IR absorption spectra of the KBr salt pellets of different purity and crystals grown of them were investigated in the region of 400…4000 cm⁻¹. It was found that by the IR spectra of the KBr salt pellets suitable for growing optically pure crystals one can evaluate the KBr salt quality. Revealed...

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Veröffentlicht in:Semiconductor Physics Quantum Electronics & Optoelectronics
Datum:2001
Hauptverfasser: Goriletsky, V.I., Mitichkin, A.I., Belenko, L.E., Rebrova, T.P.
Format: Artikel
Sprache:English
Veröffentlicht: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2001
Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/119261
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:IR spectroscopy of KBr salt and crystals / V.I. Goriletsky, A.I. Mitichkin, L.E. Belenko, T.P. Rebrova // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2001. — Т. 4, № 2. — С. 139-141. — Бібліогр.: 7 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-119261
record_format dspace
spelling Goriletsky, V.I.
Mitichkin, A.I.
Belenko, L.E.
Rebrova, T.P.
2017-06-05T17:00:17Z
2017-06-05T17:00:17Z
2001
IR spectroscopy of KBr salt and crystals / V.I. Goriletsky, A.I. Mitichkin, L.E. Belenko, T.P. Rebrova // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2001. — Т. 4, № 2. — С. 139-141. — Бібліогр.: 7 назв. — англ.
1560-8034
PACS: 78.20.C, 82.80.C, 78.30
https://nasplib.isofts.kiev.ua/handle/123456789/119261
The IR absorption spectra of the KBr salt pellets of different purity and crystals grown of them were investigated in the region of 400…4000 cm⁻¹. It was found that by the IR spectra of the KBr salt pellets suitable for growing optically pure crystals one can evaluate the KBr salt quality. Revealed in the IR spectra are not only the impurity oxygen-containing molecular anions and the adsorption water but also, indirectly through them, the most dominating cations of sodium, barium and calcium. Determined was the concentration, beginning from which sodium ions are observed in the IR spectra of the KBr salt pellets. The coefficient of proportionality between the concentration of sulfates in the KBr salt and the absorption coefficient of SO₄²⁻ ions at the frequency of deformation vibration n₄ was found. The latter allows to estimate quantitatively the sulfates in the KBr salt.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
IR spectroscopy of KBr salt and crystals
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title IR spectroscopy of KBr salt and crystals
spellingShingle IR spectroscopy of KBr salt and crystals
Goriletsky, V.I.
Mitichkin, A.I.
Belenko, L.E.
Rebrova, T.P.
title_short IR spectroscopy of KBr salt and crystals
title_full IR spectroscopy of KBr salt and crystals
title_fullStr IR spectroscopy of KBr salt and crystals
title_full_unstemmed IR spectroscopy of KBr salt and crystals
title_sort ir spectroscopy of kbr salt and crystals
author Goriletsky, V.I.
Mitichkin, A.I.
Belenko, L.E.
Rebrova, T.P.
author_facet Goriletsky, V.I.
Mitichkin, A.I.
Belenko, L.E.
Rebrova, T.P.
publishDate 2001
language English
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
format Article
description The IR absorption spectra of the KBr salt pellets of different purity and crystals grown of them were investigated in the region of 400…4000 cm⁻¹. It was found that by the IR spectra of the KBr salt pellets suitable for growing optically pure crystals one can evaluate the KBr salt quality. Revealed in the IR spectra are not only the impurity oxygen-containing molecular anions and the adsorption water but also, indirectly through them, the most dominating cations of sodium, barium and calcium. Determined was the concentration, beginning from which sodium ions are observed in the IR spectra of the KBr salt pellets. The coefficient of proportionality between the concentration of sulfates in the KBr salt and the absorption coefficient of SO₄²⁻ ions at the frequency of deformation vibration n₄ was found. The latter allows to estimate quantitatively the sulfates in the KBr salt.
issn 1560-8034
url https://nasplib.isofts.kiev.ua/handle/123456789/119261
citation_txt IR spectroscopy of KBr salt and crystals / V.I. Goriletsky, A.I. Mitichkin, L.E. Belenko, T.P. Rebrova // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2001. — Т. 4, № 2. — С. 139-141. — Бібліогр.: 7 назв. — англ.
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