Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators

Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators

Results are presented on properties of new synthesized Gd-carboxylates with unsaturated bonds. Gd-containing polystyrene oligomer and plastic scintillators based thereon were obtained using these compounds. The chemical structure of the synthesized compounds was characterized by the IR spectroscopy....

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Datum:2015
Hauptverfasser: Velmozhnaya, E.S., Bedrik, A.I., Zhmurin, P.N., Safronov, D.S., Doroshenko, A.G.
Format: Artikel
Sprache:English
Veröffentlicht: НТК «Інститут монокристалів» НАН України 2015
Schriftenreihe:Functional Materials
Schlagworte:
Technology
Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/119367
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators / E.S. Velmozhnaya, A.I. Bedrik, P.N. Zhmurin, D.S. Safronov, A.G. Doroshenko // Functional Materials. — 2015. — Т. 22, № 2. — С. 274-279. — Бібліогр.: 15 назв. — англ.

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spelling nasplib_isofts_kiev_ua-123456789-1193672025-02-09T13:19:09Z Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators Velmozhnaya, E.S. Bedrik, A.I. Zhmurin, P.N. Safronov, D.S. Doroshenko, A.G. Technology Results are presented on properties of new synthesized Gd-carboxylates with unsaturated bonds. Gd-containing polystyrene oligomer and plastic scintillators based thereon were obtained using these compounds. The chemical structure of the synthesized compounds was characterized by the IR spectroscopy. Thermographic properties of new complexes were investigated. It is shown that thermal stability of the gadolinium complexes significantly increases with introduction of the unsaturated moiety into their structure and reaches at about 300 °C. The solubility of these structures remains practically unchanged with respect to complexes that do not contain unsaturated bonds. The light output of the obtained Gd-loaded material (plastic scintillators) is kept sufficiently high and reaches 78 % with respect to the unloaded sample. 2015 Article Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators / E.S. Velmozhnaya, A.I. Bedrik, P.N. Zhmurin, D.S. Safronov, A.G. Doroshenko // Functional Materials. — 2015. — Т. 22, № 2. — С. 274-279. — Бібліогр.: 15 назв. — англ. 1027-5495 DOI: http://dx.doi.org/10.15407/fm22.02.274 https://nasplib.isofts.kiev.ua/handle/123456789/119367 en Functional Materials application/pdf НТК «Інститут монокристалів» НАН України
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
language English
topic Technology
Technology
spellingShingle Technology
Technology
Velmozhnaya, E.S.
Bedrik, A.I.
Zhmurin, P.N.
Safronov, D.S.
Doroshenko, A.G.
Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators
Functional Materials
description Results are presented on properties of new synthesized Gd-carboxylates with unsaturated bonds. Gd-containing polystyrene oligomer and plastic scintillators based thereon were obtained using these compounds. The chemical structure of the synthesized compounds was characterized by the IR spectroscopy. Thermographic properties of new complexes were investigated. It is shown that thermal stability of the gadolinium complexes significantly increases with introduction of the unsaturated moiety into their structure and reaches at about 300 °C. The solubility of these structures remains practically unchanged with respect to complexes that do not contain unsaturated bonds. The light output of the obtained Gd-loaded material (plastic scintillators) is kept sufficiently high and reaches 78 % with respect to the unloaded sample.
format Article
author Velmozhnaya, E.S.
Bedrik, A.I.
Zhmurin, P.N.
Safronov, D.S.
Doroshenko, A.G.
author_facet Velmozhnaya, E.S.
Bedrik, A.I.
Zhmurin, P.N.
Safronov, D.S.
Doroshenko, A.G.
author_sort Velmozhnaya, E.S.
title Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators
title_short Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators
title_full Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators
title_fullStr Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators
title_full_unstemmed Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators
title_sort mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators
publisher НТК «Інститут монокристалів» НАН України
publishDate 2015
topic_facet Technology
url https://nasplib.isofts.kiev.ua/handle/123456789/119367
citation_txt Mixed-ligand complexes of gadolinium carboxylates containing unsaturated bonds in plastic scintillators / E.S. Velmozhnaya, A.I. Bedrik, P.N. Zhmurin, D.S. Safronov, A.G. Doroshenko // Functional Materials. — 2015. — Т. 22, № 2. — С. 274-279. — Бібліогр.: 15 назв. — англ.
series Functional Materials
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first_indexed 2025-11-26T02:05:56Z
last_indexed 2025-11-26T02:05:56Z
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